Issue 18, 2000

Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]·6H2O

Abstract

Two complexes, [{Co(phen)2}2V6O17]n 1 and [{Cu(phen)2}4- V10O29]·6H2O 2, have been hydrothermally synthesized; X-ray crystallography shows that 1 consists of one-dimensional stepped chains built up from covalently linked {V6O17}n4n chains and [Co(phen)2]2+ fragments while 2 is composed of a discrete V10O298 cluster covalently attached to four [Cu(phen)2]2+ fragments.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 2000, 1817-1818

Hydrothermal synthesis and crystal structures of two bimetallic chain-like and cluster complexes [{Co(phen)2}2V6O17]n and [{Cu(phen)2}4V10O29]·6H2O

X. Zhang, M. Tong and X. Chen, Chem. Commun., 2000, 1817 DOI: 10.1039/B005880G

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