Abstract
The [CuL](ClO4)2 complex, L=1,4,7,10-tetrakis- (2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane, was prepared in EtOH and characterized. The crystal structure of the complex was determined by single-crystal X-ray analysis. The coordination geometry about the copper ion can be described as a strongly distorted octahedron, with CuN distances ranging from 2.01(1)–2.82(1)AÅ.
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References
V. Alexander, Chem. Rev., 95, 273 (1995).
G. De M. Norante, M. D. Vaira, F. Mani, S. Mazzi and P. Stoppioni, Inorg. Chem., 29, 2822 (1990).
C-M. Che, W-T. Tang and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 2879 (1988).
N. W. Alcock, K. P. Balakrishman and P. Moore, J. Chem. Soc., Dalton Trans., 1743 (1986).
M. D. Vaira, F. Mani, N. Nardi, P. Stoppioni and A. Vacca, J. Chem. Soc., Dalton Trans., 2679 (1996).
J. E. Richman and T. J. Atkinz, J. Am. Chem. Soc., 96, 2268 (1974).
X-H. Bu, X-C. Cao, W. Chen, R-H. Zhang and T. Clifford, submitted for publication.
K. Miyoshi, H. Tanaka, E. Kimura, S. Tsuboyama, S. Murata, H. Shimizu and K. Ishizu, Inorg. Chem. Acta, 78, 23 (1983).
B. A. Goodman and J. B. Raynor, Adv. Inorg. Chem. Radiochem., 13, 135 (1970).
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Bu, XH., Cao, XC., Zhang, WQ. et al. A new tetraazamacrocycle functionalized with pendant pyridyl groups: synthesis and crystal structure of a copper(II) complex of 1,4,7,10-tetrakis(2-pyridylmethyl)-1,4,7,10-tetraazacyclododecane (L), [CuL]·(ClO4)2. Transition Metal Chemistry 22, 513–515 (1997). https://doi.org/10.1023/A:1018527716715
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DOI: https://doi.org/10.1023/A:1018527716715