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Isobaric Vapor–Liquid Equilibrium Data of Binary Mixtures of [Water + 2,3-butanediol] and [Water + 1,4-butanediol] at 40, 50, 60, 66.7, 80, and 101 kPa

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Abstract

Isobaric vapor–liquid equilibrium (VLE) data for two binary systems, water + 2,3-butanediol (2,3-BDO) and water + 1,4-butanediol (1,4-BDO), were gathered using a customized Othmer still VLE apparatus at various pressures (40, 50, 60, 66.7, 80, and 101 kPa). In addition, the NRTL and UNIQUAC activity coefficient models were applied to correlate the data obtained experimentally, and the parameters for these binary models were derived. The average absolute deviation of temperature (AADT), AAD of vapor-phase composition (AADy), and root-mean-square deviation values were employed to assess the agreement between the experimental results and the values calculated using the two modeling methods. The total AADy values for the water + 2,3-butanediol system were calculated to be 6.4 × 10–3 (NRTL) and 2.2 × 10–3 (UNIQUAC), and for the water + 1,4-butanediol system, the values were 2.7 × 10–3 (NRTL) and 2.5 × 10–3 (UNIQUAC). The reliability of the models was confirmed by the close match between the calculated and experimental data. The Van Ness-Byer-Gibbs test was conducted to evaluate the validity and thermodynamic consistency of the experimental results. The calculated values for \(\Delta P\) and \(\Delta y\) in all systems were below 1.0, satisfying the thermodynamic consistency requirements. The information gained from this study on the vapor–liquid equilibrium behavior of the water + 2,3-butanediol and water + 1,4-butanediol systems is crucial for optimizing and designing their separation processes.

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Acknowledgements

This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF-2016R1D1A1B01013707). This work was supported by Korea Institute of Energy Technology Evaluation and Planning(KETEP) grant funded by the Korea government(MOTIE) (20214000000500, Training program of CCUS for the green growth).

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  1. Joon-Hyuk Yim

    Present address: Doosan Corporation Electro-Materials, 112 Suji-ro, Yongin-si, 16858, Gyeonggi-do, Korea

Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Sogang University, C.P.O. Box 1142, Seoul, 100-611, South Korea

    Won-Wook Seo, Joon-Hyuk Yim & Jong Sung Lim

  2. Department of Chemical and Biological Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul, 136-701, South Korea

    Jeong Won Kang

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Seo, WW., Yim, JH., Kang, J.W. et al. Isobaric Vapor–Liquid Equilibrium Data of Binary Mixtures of [Water + 2,3-butanediol] and [Water + 1,4-butanediol] at 40, 50, 60, 66.7, 80, and 101 kPa. Korean J. Chem. Eng. 41, 1457–1466 (2024). https://doi.org/10.1007/s11814-024-00039-y

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