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Synthesis and crystal structures of two three-dimensional vanadium polyoxoanion-bridged macrocyclic metal complexes

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Abstract

The reactions of transition metal macrocyclic complexes [ML](ClO4)2 (L = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane, M = Ni, Cu) with NH4VO3 under hydrothermal conditions gave two coordination polymers, namely [NiL]2[V6O17] and [CuL]2[V6O17]. Single-crystal X-ray diffraction analyses indicated that the central Ni(II)/Cu(II) atom displays a distorted six-coordinate octahedral coordination geometry by coordination with four nitrogen atoms of L, and two oxygen atoms of [VO4] tetrahedrons. Compounds [NiL]2[V6O17] and [CuL]2[V6O17] show three-dimensional structures, which are constructed through the connections of dodecanuclear [V12O32]4− rings with [NiL]2+ in [NiL]2[V6O17], and [V8O22] 4n−n chains with [CuL]2+ in [CuL]2[V6O17], respectively, generating one-dimensional channels.

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Acknowledgments

This work was financially supported by the Science and Technology Planning Project of Hunan Province (2012FJ3050, 2012NK3067), the Construct Program of the Key Discipline in Hunan Province (2011-76), and the Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province (2012-318).

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Authors and Affiliations

  1. Department of Biology and Chemistry, Hunan University of Science and Engineering, Yongzhou, 425100, Hunan, China

    Guang-Chuan Ou, Xian-You Yuan & Zhi-Zhang Li

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  1. Guang-Chuan Ou
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  2. Xian-You Yuan
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  3. Zhi-Zhang Li
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Correspondence to Guang-Chuan Ou.

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Ou, GC., Yuan, XY. & Li, ZZ. Synthesis and crystal structures of two three-dimensional vanadium polyoxoanion-bridged macrocyclic metal complexes. Transition Met Chem 37, 705–711 (2012). https://doi.org/10.1007/s11243-012-9641-0

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  • DOI: https://doi.org/10.1007/s11243-012-9641-0

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