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Germatranes and their quasi and hypo analogs with highly electronegative substituent at the Ge atom

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Abstract

Synthesis of germatranes XGe(OCH2CH2)3N (1), quasigermatranes X2Ge(OCH2CH2)2NR (R = H, Me) (2), and hypogermatranes X3Ge(OCH2CH2)NH2 (3) containing highly electronegative substituents at the Ge atom was described. An exchange reaction of the corresponding hydroxygermatranes with ammonium salts was used for their preparation. The synthesized compounds 1–3 were studied by IR spectroscopy.

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 2 nab. Adm. Makarova, 199034, Saint Petersburg, Russian Federation

    M. G. Voronkov, G. S. Samokhin, D. V. Vrazhnov & T. A. Kochina

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. A. Korlyukov

Authors
  1. M. G. Voronkov
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  2. A. A. Korlyukov
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  3. G. S. Samokhin
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  4. D. V. Vrazhnov
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  5. T. A. Kochina
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Corresponding author

Correspondence to M. G. Voronkov.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 0987–0993, May, 2012.

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Voronkov, M.G., Korlyukov, A.A., Samokhin, G.S. et al. Germatranes and their quasi and hypo analogs with highly electronegative substituent at the Ge atom. Russ Chem Bull 61, 992–998 (2012). https://doi.org/10.1007/s11172-012-0128-0

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  • DOI: https://doi.org/10.1007/s11172-012-0128-0

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