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A CeIII–CuII Supramolecular Architecture Based on a Trinuclear [Ce(H2O)6(CuL)2] Unit: Synthesis, Crystal Structure and Magnetic Properties

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Abstract

A novel 3d–4f heterometallic coordination complex [Ce(H2O)6 (CuL)2]·NO2·7H2O (1) (H3L = glycylglycine, N-[1-(2-hydroxy, phenyl)-propylidene]) was synthesized and characterized by IR, elemental analysis, TGA and single crystal X-ray diffraction. An octameric water cluster consisting of a planar tetrameric water ring and four dangling water molecules were observed in 1. Variable-temperature magnetic data shows antiferromagnetic behavior for 1.

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Acknowledgments

This work was financial support by National Natural Science Foundation of China (No. 20901067), Qianjiang Talent Project (No. 2011R10076), Natural Science Foundation of Zhejiang Province China (No. Y4080342), and SRF for ROCS, SEM.

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Authors and Affiliations

  1. Department of Chemistry, Zhejiang Sci-Tech University, Hangzhou, 310018, Zhejiang, People’s Republic of China

    Bianling Yan, Xiaojun Zhou, Yuanyuan Li, Fei Yin, Yang Zou, Yinzhi Jiang & Xing Wang

  2. College of Biological, Chemical Sciences and Engineering, Jiaxing University, Jiaxing, 314001, Zhejiang, People’s Republic of China

    Jingli Xie

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  1. Bianling Yan
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  2. Xiaojun Zhou
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  3. Yuanyuan Li
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  6. Yinzhi Jiang
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Correspondence to Yang Zou or Jingli Xie.

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Yan, B., Zhou, X., Li, Y. et al. A CeIII–CuII Supramolecular Architecture Based on a Trinuclear [Ce(H2O)6(CuL)2] Unit: Synthesis, Crystal Structure and Magnetic Properties. J Inorg Organomet Polym 23, 1534–1539 (2013). https://doi.org/10.1007/s10904-013-9955-1

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