Abstract
A group of (0.65Bi0.5Na0.5–0.35Bi0.2Sr0.7)(Ti1−x,Zrx)O3 (BNBS-(Ti1−x,Zrx)) lead-free energy storage ceramic sheets are prepared by a conventional solid-state sintering method. We find that B-site doping of ZrO2 may minimize the grain size while not change the perovskite structure of BNBS-(Ti1−x,Zrx). As such, BNBS-(Ti1−x,Zrx) possesses the uniform grains and clear grain boundaries, resulting in a high dielectric permittivity (εr) of about 2080 and a low dielectric loss (tanδ) of 0.05 at 100 Hz. Due to the lattice distortion caused by Zr4+ entering the TiO6 octahedral lattice, Tm of BNBS-(Ti1−x,Zrx) decreases with the increase of ZrO2 doping content. Attractively, BNBS-(Ti1−x,Zrx) exhibits relatively slender polarization-electric field (P-E) loops at a high electric field of 100 kV/cm, and BNBS-(Ti0.97,Zr0.03) achieves considerable recycle discharging energy density (Wrec) of 1.47 J/cm3 and high efficiency (η) of 86.94%. Thus, as a block ceramic synthesized by convenient process, this result is superior to most of similar BNT-based materials, and may provide a reference for pulse power capacitors.
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Acknowledgements
This work was supported in part by National Natural Science Foundation of China (NSFC 51773168 and 92066204), NSFC of Shaanxi province (2023-JC-YB- 287), and by the Shaanxi project of Education Department (21JY031).
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NA mainly contributes to the conception, carrying out measurements, manuscript composition. WX mainly is predominated to the conception experimental design and funding surporting. TL contributes to the funding supporting and manuscript composition. CC contributes to the manuscript composition. JL contributes to carrying out measurements equally. MZ contributes to carrying out measurements and manuscript composition.
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Ai, N., Xia, W., Lu, T. et al. B-site doping of ZrO2 to improve the dielectric and energy storge performances of a BNBS-(Ti1−x,Zrx) ceramic. J Mater Sci: Mater Electron 35, 38 (2024). https://doi.org/10.1007/s10854-023-11806-8
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DOI: https://doi.org/10.1007/s10854-023-11806-8