Abstract
La1−xNbO4:xDy3+ phosphors were synthesized through sol–gel route. XRD analysis confirms pure fergusonite monoclinic structure of La1−xNbO4:xDy3+ phosphor. The FTIR and Raman spectra show the vibrational modes present in La1−xNbO4:xDy3+ phosphor. The surface morphology and internal microstructure of the prepared phosphor were analysed by scanning electron microscopy and transmission electron microscopy and its microstructure is useful for better luminescence efficiency. UV–VIS-NIR spectrum of La1−xNbO4:xDy3+ phosphor was analysed on the basis of Judd–Ofelt theory and the J–O intensity parameters (Ωλ) were calculated. The radiative properties such as radiative transition probability, branching ratio, stimulated emission cross-section and optical gain were investigated using J–O intensity parameters. Energy transfer process between host and Dy3+ ions was studied at host excitation of 251 nm and tunable color emission from blue to near white was obtained with increasing concentration of Dy3+ ion. Excitation into 4f levels of Dy3+ ions at 351 nm show cool white light emission and the corresponding decay time, color coordinates and color correlation temperature were calculated. The results indicate that the prepared phosphor produce white light emission from a single phase host and can be used for near ultraviolet pumped white light emitting diode (NUV WLED) applications.
Similar content being viewed by others
References
S. Ye, F. Xiao, Y.X. Pan, Y.Y. Ma, Q.Y. Zhang, Mater. Sci. Eng. 71, 1–34 (2010)
W.M. Yen, S. Shionoya, H. Yamamoto, Phosphor Handbook, 2nd edn. (CRC Press, Boca Raton, 2007)
K. Takahashi, A. Yoshikawa, A. Sandhu, Wide bandgap semiconductors, fundamental properties and modern photonic and electronic devices, (Springer, Berlin, 2007)
C. Guo, L. Luan, Y. Xu, F. Gao, L. Liang, J. Electrochem. Soc. 155(11), J310–J314 (2008)
M. Shang, C. Li, J. Lin, Chem. Soc. Rev. 43, 1372–1386 (2014)
G. Zhu, Z. Ci, Q. Wang, Y. Shi, Y. Wang, Opt. Mater. Express. 3,1810–1819 (2013)
W. Ran, Q. Wang, Y. Zhou, S. Ding, J. Shi, J.H. Jeong, Mater. Res. Bull. 64, 146–150 (2015)
H. Liu, L. Liao, Q. Guo, D. Yang, L. Mei, J. Lumin. 181, 407–410 (2017)
C. Li, J. Dai, J. Huang, D. Deng, H. Yu, L. Wang, Y. Ma, Y. Hua, S. Xu, Ceram. Int. 42, 6891–6898 (2016)
J. Zhao, C. Guo, X. Su, H.M. Noh, J.H. Jeong, J. Am. Ceram. Soc. 97, 1878–1882 (2014)
C. Guo, X. Ding, L. Luan, Y. Xu, Sens. Actuators 143, 712–715 (2010)
M. Yang, X. Zhao, Y. Ji, F. Liu, W. Liu, J. Sun, X. Liu, New J. Chem. 38, 4249–4257 (2014)
A. Dwivedi, A.K. Singh, S.B. Rai, Dalton Trans. 43, 15906–15914 (2014)
L. Qin, D.L. Wei, Y. Huang, C. Qin, P. Cai, S.I. Kim, H.J. Seo, Mater. Chem. Phys. 147, 1195–1203 (2014)
S.K. Lee, H. Chang, C.H. Han, H.J. Kim, H.G. Jang, H.D. Park, J. Solid. State. Chem. 156, 267–273 (2001)
J. Hou, P. Chen, G. Zhang, W. Jiang, F. Huang, Z. Ma, J. Lumin. 146, 97–101 (2014)
P. Sun, P. Dai, J. Yang, C. Zhao, X. Zhang, Ceram. Int. 41, 3009–3016 (2015)
H. Fjeld, K. Toyoura, R. Haugsrud, Phys. Chem. 12, 10313–10319 (2010)
S. Tsunekawa, H. Takei, J. Phys. Soc. Jpn. 40, 1523–1524 (1976)
M. Arai, Y.X. Wang, S. Kohiki, M. Matsuo, H. Shimooka, T. Shishido, M. Oku, Jpn. J. Appl. Phys. 44, 6596–6599 (2005)
A. Magraso, M.L. Fontaine, J. Power Sources 196, 10183–10190 (2011)
L. Jian, C.M. Wayman, J. Am. Ceram. Soc. 80, 803–806 (1997)
A.H. Buth, G. Blasse, Phys. Stat. Sol. 64, 669–676 (1981)
C. Balamurugan, D.W. Lee, A. Subramania, App. Surf. Sci. 283, 58–64 (2013)
C. Li, R.D. Bayliss, S.J. Skinner, Solid state Ion. 262, 530–535 (2014)
K. Li, Y. Zhang, X. Li, M. Shang, H. Lian, J. Lin, Phys. Chem. 17, 4283–4292 (2015)
H. Junli, Z. Liya, L. Zhaoping, G. Fuzhong, H. Jianpeng, W. Rongfang, J. Rare Earths 28, 356–360 (2010)
S.A. Naidu, S. Boudin, U.V. Varadaraju, B. Raveau, J. Mater. Chem. 22, 1088–1093 (2012)
G. Blasse, J. Solid state chem. 7, 169–171 (1973)
M. Nazarov, Y.J. Kim, E.Y. Lee, K.I. Min, M.S. Jeong, S.W. Lee, D.Y. Noh, J. Appl. Phys. 107, 103104 (2010)
H. Jiwei, C. Qiao, G. Chan, D. Rucheng, Z. Jianwu, W. Zhongping, Z. Zengming, D. Zejun, J. Rare Earths 32, 787–791 (2014)
M.P.F. Graca, M.V. Peixoto, N. Ferreira, J. Rodrigues, C. Nico, F.M. Costa, T. Monterio, J. Mater. Chem. C 1, 2913–2919 (2013)
R.Y. Yang, H.L. Lai, J. Lumin. 145, 49–54 (2014)
D.W. Kim, D.K. Kwon, S.H. Yoon, K.S. Hong, J. Am. Ceram. soc. 89, 3861–3864 (2006)
L. Jian, C.M. Huang, G. Xu, C.M. Wayman, Mater. Lett. 21, 105–110 (1994)
H.W. Lee, J.H. Park, S. Nahm, D.W. Kim, J.G. Park, Mater. Res. Bull. 45, 21–24 (2010)
J. Liao, D. Zhou, B. Yang, R. Liu, Q. Zhang, Opt. Mater. 35, 274–279 (2012)
R. Naik, S.C. Prashantha, H. Nagabhushana, S.C. Sharma, H.P. Nagaswarupa, K.S. Anantharaju, B.M. Nagabhushana, H.B. Premkumar, K.M. Girish, Spectrochim. Acta A 140, 516–523 (2015)
B.R. Judd, Phys. Rev. 127, 750 (1962)
G.S. Ofelt, J. Chem. Phys. 37, 511 (1962)
S. Dutta, S. Som, S.K. Sharma, RSC Adv. 5, 7380 (2015)
G. Dominiak-Dzik, W. Ryba-Romanowski, M.N. Palatnikov, N.V. Sidorov, V.T. Kalinnikov, J. Mol. Struct. 704, 139–144 (2004)
O. Ravi, C. Madhukar Reddy, B. Sudhakar Reddy, B. Deva Prasad Raju, Opt. Commun. 321, 263–268 (2014)
K. VenkataRao, S. Babu, G. Venkataiah, Y.C. Ratnakaram, J. Mol. Struct. 1094, 274–280 (2015)
G. Blasse, J. Chem. Phys. 45, 2356–2360 (1966)
Y.J. Hsiao, T.H. Fang, Y.S. Chang, Y.H. Chang, C.H. Liu, L.W. Ji, W.Y. Jywe, J. Lumin. 126, 866–870 (2007)
Y.J. Hsiao, T.H. Fang, L.W. Ji, S.S. Chi. Open Surf. Sci. J. 1, 30–33 (2009)
X. Xiao, B. Yan, J. Mater. Res. 23, 679–687 (2008)
E.Y. Lee, M. Nazarov, Y.J. Kim, J. Elect. Chem. Soc. 157, J102–J105 (2010)
M. Vijayakumar, K. Mahesvaran, D.K. Patel, S. Arunkumar, K. Marimuthu, Opt. Mater. 37, 695–705 (2014)
P.B. Devaraja, D.N. Avadhani, H. Nagabhushana, S.C. Prashantha, S.C. Sharma, B.M. Nagabhushana, H.P. Nagaswarupa, B. Daruka Prasad, Mater. Charact. 97, 27–36 (2014)
L. Jing, X. Liu, Y. Li, Y. Wang, J. Lumin. 162, 185–190 (2015)
G. Blasse, J. Solid State Chem. 62, 207–211 (1986)
P. Babu, K.H. Jang, E.S. Kim, L. Shi, H.J. Seo, J. Korean Phys. Soc. 54,1488–1491 (2009)
R.T. Karunakaran, K. Marimuthu, S.S. Babu, S. Arumugam, J. Lumin. 130, 1067–1072 (2010)
C.S. McCamy, Color Res. Appl., 17,142–144 (1992)
T. Erdem, S. Nizamoglu, X.W. Sun, H.V. Demir, Opt. Express 18, 340–347 (2010)
R. Shrivastava, J. Kaur, M. Dash, Superlattices Microstruct. 82, 262–268 (2015)
R.J. Xie, Y. Q. Li, N. Hirosaki, H. Yamamoto, Nitride phosphors and solid-state lighting, (CRC Press, Boca Raton, 2011)
Y.Q. Li, N. Hirosaki, R.J. Xie, T. Takeda, M. Mitomo, Chem. Mater. 20, 6704–6714 (2008)
N. Guo, Y. Jia, W. Lu, W. Lv, Q. Zhao, M. Jiao, B. Shao, H. You. Dalton Trans. 42, 5649–5564 (2013)
L. Wang, H. Zhang, X.J. Wang, B. Dierre, T. Suehiro, T. Takeda, N. Hirosaki, R.J. Xie, Phys. Chem. Chem. Phys. 17, 15797–15804 (2015)
G. Zhu, Z. Ci, S. Xin, Y. Wen, Y. Wang, Mater. Lett. 91, 304–306 (2013)
Acknowledgements
The authors are grateful for financial assistance from UGC (Govt. of India) and DST (Govt. of India) through SAP-DRS and DST-PURSE programs, respectively. The authors are thankful to Prof. M. K Jayaraj, Cusat, Cochin and Prof. C. K Jayasankar, Sri Venkateswara University, for micro Raman and fluorescence decay analysis respectively. The authors Remya Mohan P, Viji Vidyadharan and Sreeja E are also thankful to UGC for providing UGC-BSR Research fellowship.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Remya Mohan, P., Vidyadharan, V., Sreeja, E. et al. Judd–Ofelt analysis, structural and spectroscopic properties of sol–gel derived LaNbO4:Dy3+ phosphors. J Mater Sci: Mater Electron 28, 10250–10261 (2017). https://doi.org/10.1007/s10854-017-6792-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10854-017-6792-y