Abstract
To obtain the VO2 film/CVD diamond-coated tools, the deposition process of CVD diamond coating on the VO2 film surface is investigated in this paper. Firstly, the effect of carbonization treatment on VO2 film is studied. Then, the deposition process of CVD diamond coating on the VO2 film is studied. Finally, it is studied that the change law of the VO2 film/CVD diamond coating system stresses under thermal loading. Results indicate that the CVD diamond coating can be grown on the VO2 film after carbonization and diamond seed crystal treatment. The V6C5 is the most stable material after the carbonization of the VO2 film, and it is used to connect diamond coating and VO2 film. The VO2 film/CVD diamond coating system stress undergoes a sudden change under thermal loading. After the sudden change of stress, the VO2 film/CVD diamond coating system stress is only half of the CVD diamond coating stress. The adhesion of CVD diamond coating is more than 100 N. This study can provide a new idea for the deposition of CVD diamond-coated cutting tools with high bonding performance.
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The raw/processed data required to reproduce these findings cannot be shared at this time as the data also form part of an ongoing study of a PhD thesis work.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (Grant No. 51975287) and Funding for the Outstanding Doctoral Dissertation in NUAA (Grant No. BCXJ22-08). Thanks to the Analysis and Testing Center of the Nanjing University of Aeronautics and Astronautics for the laser confocal, Raman spectroscopy, spherical aberration transmission electron microscopy, XPS, and SEM detection.
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XD involved in investigation, methodology, validation, data curation, and writing—original draft preparation. SY involved in conceptualization, methodology, investigation, and software. LX involved in writing—review and editing and conceptualization. WL involved in project administration, supervision, review and editing, resources, funding acquisition, and supervision.
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Du, X., Yi, S., Xu, L. et al. Deposition of a CVD diamond coating on a carbonized VO2 film. J Mater Sci 59, 3504–3515 (2024). https://doi.org/10.1007/s10853-024-09412-y
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DOI: https://doi.org/10.1007/s10853-024-09412-y