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Synthesis and acid-base and complex-forming properties of 1,4,7,10-tetrakis(dihydroxyphosphorylmethyl)-1,4,7,10-tetraazacyclododecane

  • Organic Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

A new complexone, 1,4,7,10-tetrakis(dihydroxyphosphorylmethyl)-1,4,7,10-tetraazacyclododecane, has been synthesized and its acid-base and complex-forming properties have been studied. It shows a very high complexing capability and marked selectivity for cations of large ionic radius (Cd2+, Hg2+, Pb2+, La3+).

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Literature cited

  1. M. I. Kabachnik, T. Ya. Medved', Yu. M. Polikarpov, B. K. Shcherbakov, F. I. Bel'skii, E. I. Matrosov, and M. P. Pasechnik, Izv. Akad. Nauk SSSR, Ser. Khim., 835 (1984).

  2. I. E. Richman and I. G. Atkins, J. Am. Chem. Soc.,6, 2268 (1974).

    Google Scholar 

  3. R. C. Weast, Handbook of Chemistry and Physics, 55th edn., CRC Press (1974–1975), p. F198.

  4. M. Kodama and E. Kimura, J. Chem. Soc. Dalton Trans., 116 (1976).

  5. H. Stetter, W. Frank, and R. Mertens, Tetrahedron,37, 767 (1981).

    Google Scholar 

  6. A. E. Martell and R. M. Smith, Critical Stability Constants, Vol. 1, Amino Acids, Plenum Press, New York, London (1974).

    Google Scholar 

  7. H. Koyama and T. Ioschino, Bull. Chem. Soc. Jpn.,45, 481 (1972).

    Google Scholar 

  8. D. H. Peacock and U. C. Dutta, J. Chem. Soc., 1303 (1934).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 844–849, April, 1984.

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Kabachnik, I.M., Medved', T.Y., Bel'skii, F.I. et al. Synthesis and acid-base and complex-forming properties of 1,4,7,10-tetrakis(dihydroxyphosphorylmethyl)-1,4,7,10-tetraazacyclododecane. Russ Chem Bull 33, 777–782 (1984). https://doi.org/10.1007/BF00947832

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  • DOI: https://doi.org/10.1007/BF00947832

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