All Issue

2021 Vol.53, Issue 6 Preview Page
Effect of Temperature of Tetraethylammonium Hydroxide/Urea/Cellulose Solution on Surface Tension and Cellulose Bead Size

TEAH/요소/셀룰로오스 용액의 온도가 표면장력 및 셀룰로오스 비즈 입자 크기에 미치는 영향

Hee-Jin An1
,
Heon E. Park2‡
,
Byoung-Uk Cho3†
안희진 1
,
박희언 2‡
,
조병욱 3†
1Department of Paper Science & Engineering, College of Forest and Environmental Science, Kangwon National University
2Department of Chemical and Process Engineering, College of Engineering, University of Canterbury, New Zealand
3Department of Paper Science & Engineering, College of Forest and Environmental Science, Kangwon National University
1강원대학교 산림환경과학대학 제지공학과, 학생
2캔터베리대학교, 화학공학과, 교수
3강원대학교 산림환경과학대학 제지공학과, 교수
†Corresponding author: E-Mail: bucho@kangwon.ac.kr (Address: Department of Paper Science & Engineering, Kangwon National University, Chunchon, Republic of Korea)
‡Co-corresponding Author: E-Mail: heon.park@canterbury.ac.nz (Address: Department of Chemical and Process Engineering, College of Engineering, University of Canterbury, Christchurch, New Zealand)
30 December 2021. pp. 69-76
PDF XML Citation
Abstract

Effects of temperature of the tetraethylammonium hydroxide (TEAH)/urea/cellulose solution on viscosity, surface tension, and size of cellulose beads were investigated. Hardwood bleached kraft pulp (HwBKP) was used as a cellulose sauce and the dropping method was utilized to fabricate cellulose beads. Temperature of cellulose solution was varied from 30℃ to 50℃. When the temperature of cellulose solution was increased, the viscosity decreased while the surface tension increased. In addition, increasing the temperature of cellulose solution resulted in the increased size of cellulose beads possibly due to the increased surface tension.

Keywords
Cellulose beads
dropping
solution temperature
particle size
viscosity
surface tension
References

Literature Cited

1

An, D. and Kim, J., Proposing policy for prevention of marine pollution from microplastics, Journal of Environmental Policy and Admistration 26(3):77-102 (2018).

10.15301/jepa.2018.26.3.77
2

Jambeck, J. R., Andrady, A., Geyer, R., Narayan, R., Perryman, M., Siegler, T., Wilcox, C., and Lavender Law, K., Plastic waste inputs from land into the ocean, Science 347:768-771 (2015).

10.1126/science.1260352
3

GESAMP, Sources, fate and effects of microplastics in the marine environment: A global assessment, Kershaw, P.J. (ed.), IMO/FAO/UNESCO-IOC/UNIDO/WMO/IAEA/UN/UNEP/UNDP Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection, Reports and Studies GESAMP No. 90, p.96 (2015).

4

Kathryn, M., Santillo, D., and Johnston, P., Plastics in seafood – full technical review of the occurrence, fate and effects of microplastics in fish and shellfish, Greenpeace Research Laboratories Technical Report (Review) 07-2016 (2016).

5

Kim, K. W., Current status of plastic pollution and the scientific policy to solve the problem, KAST Research Report 123, The Korean Academy of Science and Technology (2018).

6

Moon, S. M., Jeon, S. H., Eom, T., and Shim, B. S., Recent research trends in eco-friendly materials for solving environmental microplastic problems, Prospectives of Industrial Chemistry 22(2):25-43 (2019).

7

Kwon, G.-J. and Kim, N.-H., Trend and technology development of bioenergy from woody biomass, Journal of Forest and Environmental Science 25(2):131-138 (2009).

8

Klemm, D., Heublein, B., Fink, H.-P., and Bohn, A., Cellulose: Fascinating biopolymer and sustainable raw material, Angewandte Chemie International Edition 44:3358-3393 (2005).

10.1002/anie.200460587
9

Gericke, M., Trygg, J., and Fardim, P., Functional cellulose beads: Preparation, characterization, and applications, Chemical Reviews 113:4812-4836 (2013).

10.1021/cr300242j
10

Kim, Y., An, H.-J., and Cho, B.-U., Production of cellulose beads with TEAH-urea solvent and dropping technique–Effect of inner diameter of syringe needle, Journal of Korea TAPPI 52(6):149-156 (2020).

10.7584/JKTAPPI.2020.12.52.6.149
11

Kim, Y., An, H.-J., and Cho, B.-U., Production of cellulose beads with TEAH-urea solvent and dropping technique–Effect of concentration of cellulose solution, Journal of Korea TAPPI 53(1):83-89 (2021).

10.7584/JKTAPPI.2021.02.53.1.83
12

Mandato, S., Rondet, E., Delaplace, G., Barkouti, A., Galet, L., Accart, P., Ruiz, T., and Cuq, B., Liquid’s atomization with two different nozzles: Modeling of effect of some processing and formulation conditions by dimensional analysis, Powder Technology 224:323-330 (2012).

10.1016/j.powtec.2012.03.014
13

Sirvio, J. A. and Heiskanen, J. P., Room temperature dissolution and chemical modification of cellulose in aqueous tetraethylammonium hydroxide-carbamide solutions, Cellulose 27:1933-1950 (2020).

10.1007/s10570-019-02907-x
14

Hamdaoui, L. E., Bouchti, M. E., and Moussaouiti, M. E., Comparison of rheological properties of kraft and microcrystalline cellulose dissolved in lithium chloride/N,N-dimethylacetamide, Polymer Bulletin 75(2):1-11 (2018).

10.1007/s00289-017-2066-3
15

Hamdaoui, L. E., Bouchti, M. E., Moussaouiti, M. E., and Gmouh, S., Comparison of rheological properties of kraft and microcrystalline cellulose dissolved in 1-butyl-3-methylimidazolium chloride, Moroccan Journal of Chemistry 6(2):237-244 (2018).

16

Kamide, K., Saito, M., and Kowsaka, K., Temperature dependence of limiting viscosity number and radius of gyration for cellulose dissolved in aqueous 8% sodium hydroxide solution, Polymer Journal 19(10):1173-1181 (1987).

10.1295/polymj.19.1173
17

Chen, X., Zhang, Y., Cheng, L., and Wang, H., Rheology of concentrated cellulose solutions in 1-butyl-3-methylimidazolium chloride, Journal of Polymers and the Environment 17(4):273-279 (2009).

10.1007/s10924-009-0149-4
18

Kartikawati, N. A., Safdar, R., Lal, B., Mutalib, M. I. B. A., and Shariff, A. M., Measurement and correlation of the physical properties of aqueous solutions of ammonium based ionic liquids, Journal of Molecular Liquids 253:250-258 (2018).

10.1016/j.molliq.2018.01.040
19

Park, H. E., Dealy, J., and Münstedt, H., Influence of long-chain branching on time-pressure and time-temperature shift factors for polystyrene and polyethylene, Rheologica Acta 46:153–159 (2006).

10.1007/s00397-006-0116-0
20

Sánchez, L. G., Espel, J. R., Onink, F., Meindersma, G. W., Haan, A. B., Density, viscosity, and surface tension of synthesis grade imidazolium, pyridinium, and pyrrolidinium based roomtemperature ionic liquids, Journal of Chemical & Engineering Data 54(10):2803-2912 (2009).

10.1021/je800710p
21

Carvalho, P. J., Neves, C.M.S. S., and Coutinho, J. A., Surface tension of bis(trifluoromethylsulfonyl)imide anion-based ionic liquids, Journal of Chemical & Engineering Data 55(9):3807-3812 (2010).

10.1021/je100253m
22

Xiong, B., Zhao, P., Hu, K., Zhang, L., and Cheng, G., Dissolution of cellulose in aqeous NaOH/ure solution: Role of urea, Cellulose 21:1183-1192 (2014).

10.1007/s10570-014-0221-7
23

Hu, R. Y. Z., Wang, A. T. A., and Hartnett, J. P., Surface tension measurement of aqueous polymer solutions, Experimental Thermal and Fluid Science 4(6):723-729 (1991).

10.1016/0894-1777(91)90079-7
24

Schuermann, J., Huber, T., LeCore, D., Mortha, G., Sellier, M., Duchemin, B., and Staiger, M. P., Surface tension of cencentrated cellulose solutions in 1-ethyl-3-methylimidazolium acetate, Cellulose 23:1043-1050 (2016).

10.1007/s10570-015-0850-5
25

Davanliu, A., Lee, J. D., Basu, S., and Kumar, R., Effect of viscosity and surfae tension on breakup and coalescence of bicomponent sprays, Chemical Engineering Science 131:243-255 (2015).

10.1016/j.ces.2015.03.057
Information
  • Publisher :Korea Technical Association of The Pulp and Paper Industry
  • Publisher(Ko) :한국펄프종이공학회
  • Journal Title :Journal of Korea TAPPI
  • Journal Title(Ko) :펄프종이기술
  • Volume : 53
  • No :6
  • Pages :69-76
  • Received Date : 2021-12-04
  • Revised Date : 2021-12-22
  • Accepted Date : 2021-12-23
  • DOI :https://doi.org/10.7584/JKTAPPI.2021.12.53.6.69
Journal Informaiton Journal of Korea TAPPI Journal of Korea TAPPI
Online Submission
  • scopus
  • NRF
  • KOFST
  • crossref crossmark
  • crossref cited-by
  • crosscheck
  • orcid
Journal Informaiton Journal Informaiton - close