静水压下锆锡钛酸铅铁电陶瓷相变和介电性能研究

蒋冬冬; 谷岩; 冯玉军; 杜金梅

doi:10.7498/aps.60.107703

摘要

研究了铌掺杂锆锡钛酸铅铁电陶瓷Pb0.99Nb0.02[(Zr0.90Sn0.10)0.96Ti0.04]0.98O3(PZST 90/10-4-2Nb)在静水压(0300 MPa)下的电荷释放量和介电性能. 对压力诱导的低温铁电三方(FR(LT))反铁电正交(AO)相变进行了研究. PZST 90/10-4-2Nb铁电陶瓷分为未极化、极化和压力去极化三种. 极化PZST 90/10-4-2Nb陶瓷FR(LT)AO相变过程中,电荷释放量为29.3 C/cm2,相变压力为140 MPa. 介电性能表明:极化PZST 90/10-4-2Nb陶瓷相变压力为136 MPa,而未极化陶瓷相变压力为104 MPa,压力去极化陶瓷未表现出明显的相变特征.

关键词:

静水压 /
铁电陶瓷 /
相变 /
介电

Abstract

Nb-doped lead zirconate stannate titanate ferroelectric ceramic with composition Pb0.99Nb0.02[(Zr0.90Sn0.10)0.96Ti0.04]0.98O3 (PZST 90/10-4-2Nb) is studied in a hydraulic pressure range of 0300 MPa by released charge and dielectric measurements. Pressure-induced low temperature phase transition from ferroelectric rhombohedral (FR(LT)) structure to antiferroelectric orthorhombic (AO) strueture is investigated. Unpoled, poled and pressure-depolarized PZST 90/10-4-2Nb ferroelectric ceramics are used. The released charge quantity is 29.3 C/cm2 and the threshold pressure is 140 MPa during the phase transformation from FR(LT) structure to AO strueture. Dielectric properties show that the threshold pressure of the phase transformation from FR(LT) structure to AO structure is 136 MPa for poled ceramic and 104 MPa for unpoled ceramic. Obvious characteristic of phase transformation is not observed in pressure-depolarized ceramic.

Keywords:

作者及机构信息

1.
中国工程物理研究院流体物理研究所冲击波物理与爆轰物理实验室,绵阳 621900;

2.
西安交通大学电子材料与器件研究所,西安 710049

基金项目: 中国工程物理研究院双百人才工程人选自选课题(批准号:2008R0107)、国家自然科学基金(批准号:10875095)和国家重点基础研究发展计划(批准号:2009CB623306)资助的课题.

Authors and contacts

1.
Laboratory for Shock Wave and Detonation Physics Research,Institute of Fluid Physics,China Academic of Engineering Physics,Mianyang 621900,China;

2.
Electronic Materials Research Laboratory, Xi'an Jiaotong University,Xi'an 710049, China

参考文献

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施引文献

[1]	Jaffe B, Cook W R, Jaffe H 1971 Piezoelectric Ceramics (New York: Academic Press) p135
[2]	Feng Y J, Yao X, Xu Z 2000 Acta Phys. Sin. 49 1606 (in Chinese) [冯玉军、姚熹、徐卓 2000 物理学报 49 1606]
[3]
[4]	Neilson F W 1957 Bull American Physics Soc. 2 302
[5]
[6]
[7]	Reynolds C E, Seay G E 1962 J. Appl. Phys. 33 2234
[8]	Halpin W J 1966 J. Appl. Phys. 37 153
[9]
[10]
[11]	Lysne P C, Percival C M 1975 J. Appl. Phys. 46 1519
[12]	Dick J J, Vorthman J E 1978 J. Appl. Phys. 49 2494
[13]
[14]	Setchell R E 2003 J. Appl. Phys. 94 573
[15]
[16]	Setchell R E 2005 J. Appl. Phys. 97 013507
[17]
[18]
[19]	Yang P, Tuttle B A, Moore R H, Voigt J A, Scofield T W 2003 Sandia Report 2003-3866
[20]
[21]	Samara G A 1966 Physical Review 151 378
[22]
[23]	Xu Z, Feng Y J, Zhen S G, Jin A, Wang F L, Yao X 2001 Acta Phys. Sin. 50 1787 (in Chinese) [徐卓、冯玉军、郑曙光、金安、王方林、姚熹 2001 物理学报 50 1787]
[24]
[25]	Zhang C H, Xu Z, Gao J J, Wang B K 2009 Acta Phys. Sin. 58 6500 (in Chinese) [张崇辉、徐卓、高俊杰、王斌科 2009 物理学报 58 6500]
[26]
[27]	Lee M Y, Montgomery S T, Hofer J H 2004 Sandia Report 2004-4954
[28]
[29]	Avdeev M, Jorgensen J D, Short S, Samara G A, Venturini E L 2006 Physical Review B 73 064105
[30]
[31]	Berlincourt D 1966 IEEE transactions on sonics and ultrasonics su-13 116
[32]	Fritz I J 1978 J. Appl. Phys. 49 4922
[33]
[34]	Zeuch D H, Montgomery S T, Holcomb D J 2000 J. Mater. Res. 15 689
[35]
[36]	Berlincourt D, Krueger H H A, Jaffe B 1964 J. Phys. Chem. Solids. 25 659
[37]

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