Most of the municipal solid waste incinerator(MSWI) fly ash are solidified followed by landfilling currently, based on the tendency of resource recirculation, it should be studied to recover for high value products. MSWI fly ash has been studied successfully to blend with waste glass and kaolinite, as the feedstock of humidity adjustment ceramic material sintering. While MSWI boiler ash used to be blended with waste glass and palygorskite during the study of humidity-controlling ceramic sintering, and found that addition of palygorskite can increase the moisture absorption capacity of the product. Fly ash (reaction product of semi-dry APCD) was sampled from a MSWI in central Taiwan. In the first stage experiment, the fly ash samples were pretreated by washing with liquid/solid ratio 5, followed by wet ball milling with liquid/solid ratio 9, in order to remove soluble salts and stabilize the heavy metals; then blended with waste cullet powder and kaolinite in different ratio to press in a mold, followed by sintered at different temperature in the furnace. In the second stage, washed ash samples were milled with proper amount of activated palygorskite to enhance the effect of heavy metals stabilization; In the molding step, kaolinite was replaced by palygorskite to enhance the characteristics of humidity-controlling ceramic. The results showed six conditions of the ceramic were in line with the level three of humidity-controlling standard and the bending strength standard of tile in CNS. The best humidity desorption rate (79.4%) sample reveled the best bending strength 22.3 MPa at sintering temperature 900℃, with the combination of waste glass：stabilized ash：kaolinite =6 : 1 : 3. Nevertheless, the best humidity adsorption capacity (162.3 g/m2) reveled at sintering temperature 950℃ with waste glass：stabilized ash：palygorskite =6 : 2：2. Total Cr leaching in the TCLP tests were far below the hazardous waste standard for all of the 6 samples, while other heavy metals were all below the detection limit. SEM analysis showed that the higher temperature melted the particles to from smooth surface of the ceramic, which induced better humidity desorption rate; on the contrary, the sample with better moisture absorption is porously and the surface is rough. XRD analysis revealed that after wet milling process and sintered at high temperature, new stable crystals such as Diopside (CaMg(SiO3)2), Quartz (SiO2) and Al0.67Fe0.33(PO4) appeared.