Besides our government has pushed the new agricultural exercise aggressively in 2006, there are already a lot of agricultural units using innovative organization, for instance, research and extension station, research institute, production and marketing class. They have broken through the predicament of the agriculture of Taiwan, and created new profit and value, brought new opportunity for Taiwan agricultural development. This implies that native agricultural units can maintain their competitive power, making profit, and creating new business model through forming some innovative value net when facing some powerful competitive stress. Also through building the value net and value chain, they can adjust the commodity’s value and circulate the higher value to the final customer. Thus, this research use the case study method in order to discuss the fact that how does the structure of the value net achieve to value creation with Taiwan’s agricultural. This research will discuss what the value creation models of Taiwan’s agricultural are through systemic filtration. Also this research will generalize the relationship between the structure of value net and value creation from the angle of value net analysis. The results of this research focus on the core concept, the structure of the value net, and will discuss the relationship between the structure of the value net and value creation. In conclusion, newness and function value are formed with the activities that the agricultural material and products are preceded R&D and reprocessed. Security value is formed with the whole security maintenance activities that the process of the agricultural products from producing to marketing. Emotion value, knowledge, and synergy value are formed with the activities of offering diversiform experience service, selling all kinds of agricultural products, and sharing all kinds of agricultural cultivation and administration experience. Convenience value is formed with the reprocessing activities of the agricultural products which cuisine process have been simplified.