近年來,國際上發展一種稱為熱微影技術之奈米圖案成形技術。該技術利用曝光源直接在光阻層上選擇區域曝光,曝光區吸收熱能後,會產生由非晶相轉為晶相之相變化。由於曝光與未曝光區域結構之差異,造成顯影液具有不同的蝕刻對比度,經由顯影後可產生奈米級圖案。 在此研究中,採用Ge-Sb-Sn-O作為無機光阻材料。利用波長為405 nm之藍光雷射,搭配0.65的數值孔徑,來產生所需要的曝光源。它可製造出高度為80 nm和寬度為140 nm之奈米級圖案。所製作的圖案之最小寬度,遠小於光學繞射極限的312 nm。此種熱微影製程技術具有很多優點,例如加工便利、成本低和省時等。對於未來的工業應用,利用熱微影技術製造奈米級圖案,將是一大利器。
A thermal lithography technique was proposed for fabricating nanoscale patterns. Due to heat of illuminating laser, the phase of a resist material can be altered from amorphous to crystalline states. The contrast of dissolution rate between these two states can conduct a formation of nanopatterns through development. Using thermal lithography, a minimum pattern width of 140 nm with a height of 80 nm, far beyond the diffraction limit of 312 nm, for Ge-Sb-Sn-O inorganic resist can be obtained with a numerical aperture of 0.65 at the wavelength of 405 nm. Thermal lithography technique will be applied to the mastering process because it is convenient, low-cost and time-saving.