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  • 學位論文

連續式濺鍍製作氧化鋅摻雜鋁薄膜

Aluminum doped zinc oxide films prepared by in-line sputter tool

指導教授 : 張慎周

摘要


本實驗研究採用連續式濺鍍製作氧化鋅掺雜鋁薄膜(AZO),連續式濺鍍方式是產業界普遍使用在大面積、高產量的薄膜生產方式。 利用AZO靶材採用連續性濺鍍在玻璃基板沉積AZO薄膜時,藉由改變基板加熱溫度與製程氣體,在純氬氣及加熱板4500C時的基板溫度所製作的AZO薄膜,可達到平均穿透率91%(波長400-1100nm),電阻率6.22×10-4Ω-cm。同樣地氬氣混合5%氫氣及加熱板4500C時的基板溫度所製作的AZO薄膜,可達到平均穿透率92%(波長400-1100nm),電阻率4.81×10-4Ω-cm。濺鍍中加入氫氣可以增加薄膜導電率。在薄膜鍍完一天內就量測薄膜電性,則氬氣混合5%氫氣比純氬氣所製作的AZO薄膜載子濃度高2.2倍,但是混合氫氣所製作的AZO薄膜電性不穩定,氬氣混合氫氣所製作的薄膜存放30天後再多量一次載子濃度結果濃度降低,純氬氣製作的薄膜則沒有濃度降低的現象。 本實驗可提供如薄膜太陽能電池產業,在製作AZO透明導電層的生產條件選擇參考。

並列摘要


This work studies aluminum doped zinc oxide (AZO) films prepared by in line sputtering. In line sputtering is a popular thin film producing method for large area and high throughput production in industry application. Different substrate heating temperatures and process gas during sputtering were applied to produce AZO films on glass with in line sputtering AZO target. Average optical transmittance 91% between 400 and 1100 nm wavelength region and electrical resistivity 6.22×10-4Ω-cm of AZO films can be obtained with pure argon process gas and 450C substrate heating temperature. Average optical transmittance 92% between 400 and 1100 nm wavelength region and electrical resistivity 4.81×10-4Ω-cm of AZO films can be also produced from argon mixed with 5% hydrogen process gas and 450C substrate heating temperature. Adding hydrogen during sputtering can increase film’s electrical conductivity. The carrier concentration for AZO films prepared from argon mixed with 5% hydrogen process gas is higher than that prepared from pure argon gas about 2.2 times when the electrical property was measured within one day after films production. The electrical property for AZO films produced from hydrogen mixture gas is unstable. The carrier concentration decreases more than one time for films produced from argon/hydrogen mixture after storing 30 days. The films produced from pure argon gas do not have this decreasing behavior. This work contributes to industry like thin film solar cell in selecting process recipe for producing AZO films as transparent electrodes.

參考文獻


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被引用紀錄


吳光榮(2010)。直線式連續濺鍍製作氧化鋅共摻雜鎵鋁薄膜〔碩士論文,崑山科技大學〕。華藝線上圖書館。https://www.airitilibrary.com/Article/Detail?DocID=U0025-2007201010343200

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