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:: Volume 9, Issue 4 (8-2022) ::
jehe 2022, 9(4): 417-430 Back to browse issues page
Investigating of the performance of persulfate activation process by magnetic activated carbon in the decomposition of benzotriazole in aqueous solution
Mehdi Amidnia , Mahboubeh Cheraghi * , Afshin Takdestan , Babak Kakavandi , Reza Jalilzadeh yengejeh
Department of Environmental Engineering, Islamic Azad University, Ahvaz Branch, Iran
Abstract:   (680 Views)
Background and Objective: Recently, significant efforts have been performed for the removal of various emerging pollutants (EPs) from water sources. Among these EPs, benzotriazole has been widely identified in aquatic environments, which has harmful health and environmental effects, so it is necessary to apply various methods to remove it. Up to date, the use of advanced oxidation processes (AOPs) as an efficient method for the degradation and mineralization of EPs pollutants from aqueous solutions has attracted so much attention. Therefore, in this research, the performance of the persulfate activation process using magnetic nanocatalyst iron oxide-activated carbon prepared from coconut shell for the removal of benzotriazole from aqueous solution, and also the effect of different parameters have been investigated.
Materials and Method: This research is an experimental-laboratory study. The effect of various variables such as solution pH (2-10), catalyst dose (0.1-0.5 g/L), persulfate concentration (1-5 mM), and initial concentration of benzotriazole (10-50 mg/L) was investigated. The final concentration of benzotriazole was measured using a spectrometer. Also, the characteristics of the synthesized catalyst were investigated using numerous analyzes such as BET, FESEM, XRD, EDX and VSM, and
Results: The results showed that the highest efficiency of the process for the removal of benzotriazole was attained at pH: 6, initial concentration: 10 mg/L, catalyst dosage: 0.5 g/L, persulfate concentration: 3 mM, and more than 80% of benzotriazole was removed. On the other hand, the results of catalyst characterization showed that the catalyst was perfectly synthesized and could be reused in five consecutive cycles.
Conclusion: Based on the results of this research, this catalyst had a high performance for the removal of organic pollutants from aqueous solution.

 
Keywords: Advanced oxidation, Benzotriazole, Persulfate, Coconut shell, Sulfate radical
Full-Text [PDF 1185 kb]   (526 Downloads)    
Type of Study: Research | Subject: Special
Received: 2022/10/10 | Accepted: 2022/12/11 | Published: 2023/06/20
References
1. 1.Ghanbari F, Khatebasreh M, Mahdavianpour M, Lin K-YA. Oxidative removal of benzotriazole using peroxymo-nosulfate/ozone/ultrasound: Synergy, optimization, degr-adation intermediates and utilizing for real wastewater. Chemosphere 2020;244: 125326. [DOI:10.1016/j.chemosphere.2019.125326] [PMID]
2. Deng J, Li X, Wei X, et al. Sulfamic acid modified hydrochar derived from sawdust for removal of benzotriazole and Cu (II) from aqueous solution: Adsorp-tion behavior and mechanism. Bioresource Technology 2019;290: 121765. [DOI:10.1016/j.biortech.2019.121765] [PMID]
3. Ma J, Ding Y, Chi L, et al. Degradation of benzotriazole by sulfate radical-based advanced oxidation process. Environmental technology 2021;42(2): 238-47. [DOI:10.1080/09593330.2019.1625959] [PMID]
4. Bahnmüller S, Loi CH, Linge KL, et al. Degradation rates of benzotriazoles and benzothiazoles under UV-C irradiation and the advanced oxidation process UV/ H2O2. Water research 2015;74: 143-54. [DOI:10.1016/j.watres.2014.12.039] [PMID]
5. Xu J, Li L, Guo C, et al. Removal of benzotriazole from solution by BiOBr photocatalysis under simulated solar irradiation. Chemical Engineering Journal 2013;221: 230-7. [DOI:10.1016/j.cej.2013.01.081]
6. Ahmadi M, Rahmani K, Rahmani A, Rahmani H. Removal of benzotriazole by Photo-Fenton like process using nano zero-valent iron: response surface methodology with a Box-Behnken design. Polish Journal of Chemical Technology 2017;19(1): 104--12. [DOI:10.1515/pjct-2017-0015]
7. Wang S, Pei S, Zhang J, et al. Flow-through electrochemical removal of benzotriazole by electroactive ceramic membrane. Water Research 2022;218: 118454. [DOI:10.1016/j.watres.2022.118454] [PMID]
8. Roshani B, Leitner NKV. Effect of persulfate on the oxidation of benzotriazole and humic acid by e-beam irradiation. Journal of Hazardous Materials 2011;190(1-3): 403-8. [DOI:10.1016/j.jhazmat.2011.03.059] [PMID]
9. Jaafarzadeh N, Kakavandi B, Takdastan A, et al. Powder activated carbon/Fe 3 O 4 hybrid composite as a highly efficient heterogeneous catalyst for Fenton oxidation of tetracycline: degradation mechanism and kinetic. RSC Advances 2015;5(103): 84718-28. [DOI:10.1039/C5RA17953J]
10. Jonidi Jafari A, Kakavandi B, Jaafarzadeh N, et al. Fenton-like catalytic oxidation of tetracycline by AC@Fe3O4 as a heterogeneous persulfate activator: Adsorption and degradation studies. Journal of Industrial and Engineering Chemistry 2017;45: 323-33. [DOI:10.1016/j.jiec.2016.09.044]
11. Jorfi S, Kakavandi B, Motlagh HR, et al. A novel combination of oxidative degradation for benzotriazole removal using TiO2 loaded on FeIIFe2IIIO4@ C as an efficient activator of peroxymonosulfate. Applied Catalysis B: Environmental 2017;219: 216-30. [DOI:10.1016/j.apcatb.2017.07.035]
12. Oh W-D, Lua S-K, Dong Z, Lim T-T. A novel three-dimensional spherical CuBi 2 O 4 consisting of nano-column arrays with persulfate and peroxymonosulfate activation functionalities for 1 H-benzotriazole removal. Nanoscale 2015;7(17): 8149-58. [DOI:10.1039/C5NR01428J] [PMID]
13. Hasanbeiki A, Hasanbeiki O. Evaluation The Performa-nce of 4-Chlorophenol Removal from Contaminated Waters Using a Monopolar Electrochemical Cell. Journal of Jiroft University of Medical Sciences 2015;1(1): 37-48.
14. Oturan MA, Sirés I, Oturan N, et al. Sonoelectro-Fenton process: a novel hybrid technique for the destruction of organic pollutants in water. Journal of Electroanalytical Chemistry 2008;624(1-2): 329-32. [DOI:10.1016/j.jelechem.2008.08.005]
15. Giannakis S, Lin K-YA, Ghanbari F. A review of the recent advances on the treatment of industrial wastew-aters by Sulfate Radical-based Advanced Oxidation Processes (SR-AOPs). Chemical Engineering Journal 2021;406: 127083. [DOI:10.1016/j.cej.2020.127083]
16. Yao C, Zhang Y, Du M, et al. Insights into the mechanism of non-radical activation of persulfate via activated carbon for the degradation of p-chloroaniline. Chemical Engineering Journal 2019;362: 262-8. [DOI:10.1016/j.cej.2019.01.040]
17. Aljeboree AM, Alshirifi AN, Alkaim AF. Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arabian journal of chemistry 2017;10: S3381-S93. [DOI:10.1016/j.arabjc.2014.01.020]
18. Kakavandi B, Esrafili A, Mohseni-Bandpi A, et al. Magnetic Fe3O4@ C nanoparticles as adsorbents for removal of amoxicillin from aqueous solution. Water science and technology 2014;69(1): 147-55. [DOI:10.2166/wst.2013.568] [PMID]
19. Rahmani A, Asgari G, Leili M, Aazami Gilan R. Degradation of methylene blue dye using fenton/ pho-tofenton-peracetic acid (UV/Fe3+-CH3COOH− H2O2) processes from aqueous solutions. Journal of Mazandaran University of Medical Sciences 2017;27 (153:95-111).
20. V. Chandra JP, Y. Chun, J.W. Lee, I.C. Hwang, K.S. Kim. Water-dispersible magnetite-reduced graphene oxide composites for arsenic removal. Acs Nano 2010;4. [DOI:10.1021/nn1008897] [PMID]
21. Z. Li ZC, J. Fang, C. Shang. Bromate formation in bromide-containing water by the cobalt-mediated activation of peroxymonosulfate: Roles of sulfate radicals and Co(III). Acs National Meeting & Exposition 2014.
22. Liu Y, Guo W, Guo H, et al. Cu (II)-doped V2O5 mediated persulfate activation for heterogeneous catalytic degradation of benzotriazole in aqueous solution. Separ-ation and Purification Technology 2020;230: 115848. [DOI:10.1016/j.seppur.2019.115848]
23. Ma Q, Zhang X, Guo R, et al. Persulfate activation by magnetic γ-Fe2O3/Mn3O4 nanocomposites for degrad-ation of organic pollutants. Separation and Purification Technology 2019;210: 335-42. [DOI:10.1016/j.seppur.2018.06.060]
24. Oh W-D, Lua S-K, Dong Z, Lim T-T. Performance of magnetic activated carbon composite as peroxymonos-ulfate activator and regenerable adsorbent via sulfate radical-mediated oxidation processes. Journal of hazard-ous materials 2015;284: 1-9. [DOI:10.1016/j.jhazmat.2014.10.042] [PMID]
25. Li X, Liu Z, Zhu Y, et al. Facile synthesis and synergistic mechanism of CoFe2O4@ three-dimensional graphene aerogels towards peroxymonosulfate activation for highly efficient degradation of recalcitrant organic pollutants. Science of The Total Environment 2020;749: 141466. [DOI:10.1016/j.scitotenv.2020.141466] [PMID]
26. Li X, Jia Y, Zhou M, et al. High-efficiency degradation of organic pollutants with Fe, N co-doped biochar catalysts via persulfate activation. Journal of Hazardous Materials 2020;397: 122764. [DOI:10.1016/j.jhazmat.2020.122764] [PMID]
27. Guan K, Zhou P, Zhang J, Zhu L. Catalytic degradation of Acid Orange 7 in water by persulfate activated with CuFe2O4@ RSDBC. Materials Research Express 2020;7(1): 016529. [DOI:10.1088/2053-1591/ab6253]
28. Li X, Zhang D, Liu Z, et al. Enhanced catalytic oxidation of benzotriazole via peroxymonosulfate activated by CoFe2O4 supported onto nitrogen-doped three-dimensi-onal graphene aerogels. Chemical Engineering Journal 2020;400: 125897. [DOI:10.1016/j.cej.2020.125897]
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Amidnia M, Cheraghi M, Takdestan A, Kakavandi B, Jalilzadeh yengejeh R. Investigating of the performance of persulfate activation process by magnetic activated carbon in the decomposition of benzotriazole in aqueous solution. jehe 2022; 9 (4) :417-430
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Volume 9, Issue 4 (8-2022) Back to browse issues page
مجله مهندسی بهداشت محیط Journal of Environmental Health Enginering
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