Controlled Growth of C-Oriented AlN Thin Films: Experimental Deposition and Characterization

Nowadays, the science of thin films has experienced an important development and specialization. Basic research in this field involves a controlled film deposition followed by characterization at atomic level. Experimental and theoretical understanding of thin film processes have contributed to the development of relevant technological fields such as microelectronics, catalysis and corrosion. The combination of materials properties has made it possible to process thin films for a variety of applications in the field of semiconductors. Inside that field, the nitrides III-IV semiconductor family has gained a great deal of interest because of their promising applications in several technology-related issues such as photonics, wear-resistant coatings, thin-film resistors and other functional applications (Moreira et al., 2011; Morkoc, 2008). Aluminium nitride (AlN) is an III-V compound. Its more stable crystalline structure is the hexagonal wurzite lattice (see figure 1). Hexagonal AlN has a high thermal conductivity (260 Wm-1K-1), a direct band gap (Eg=5.9-6.2 eV), high hardness (2 x 103 kgf mm-2), high fusion temperature (2400C) and a high acoustic velocity. AlN thin films can be used as gate dielectric for ultra large integrated devices (ULSI), or in GHz-band surface acoustic wave devices due to its strong piezoelectricity (Chaudhuri et al., 2007; Chiu et al., 2007; Jang et al., 2006; Kar et al., 2006; Olivares et al., 2007; Prinz et al., 2006). The performance of the AlN films as dielectric or acoustical/electronic material directly depends on their properties at microstructure (grain size, interface) and surface morphology (roughness). Thin films of AlN grown at a c-axis orientation (preferential growth perpendicular to the substrate) are the most interesting ones for applications, since they exhibit properties similar to monocrystalline AlN. A high degree of c-axis orientation together with surface smoothness are essential requierements for AlN films to be used for applications in surface acoustic wave devices (Jose et al., 2010; Moreira et al., 2011). On the other hand, the oxynitrides MeNxOy (Me=metal) have become very important materials for several technological applications. Among them, aluminium oxynitrides may have promissing applications in diferent technological fields. The addition of oxygen into a growing AlN thin film induces the production of ionic metal-oxygen bonds inside a matrix


Introduction
Nowadays, the science of thin films has experienced an important development and specialization.Basic research in this field involves a controlled film deposition followed by characterization at atomic level.Experimental and theoretical understanding of thin film processes have contributed to the development of relevant technological fields such as microelectronics, catalysis and corrosion.The combination of materials properties has made it possible to process thin films for a variety of applications in the field of semiconductors.Inside that field, the nitrides III-IV semiconductor family has gained a great deal of interest because of their promising applications in several technology-related issues such as photonics, wear-resistant coatings, thin-film resistors and other functional applications (Moreira et al., 2011;Morkoç, 2008).Aluminium nitride (AlN) is an III-V compound.Its more stable crystalline structure is the hexagonal würzite lattice (see figure 1).Hexagonal AlN has a high thermal conductivity (260 Wm -1 K -1 ), a direct band gap (E g =5.9-6.2 eV), high hardness (2 x 10 3 kgf mm -2 ), high fusion temperature (2400C) and a high acoustic velocity.AlN thin films can be used as gate dielectric for ultra large integrated devices (ULSI), or in GHz-band surface acoustic wave devices due to its strong piezoelectricity (Chaudhuri et al., 2007;Chiu et al., 2007;Jang et al., 2006;Kar et al., 2006;Olivares et al., 2007;Prinz et al., 2006).The performance of the AlN films as dielectric or acoustical/electronic material directly depends on their properties at microstructure (grain size, interface) and surface morphology (roughness).Thin films of AlN grown at a c-axis orientation (preferential growth perpendicular to the substrate) are the most interesting ones for applications, since they exhibit properties similar to monocrystalline AlN.A high degree of c-axis orientation together with surface smoothness are essential requierements for AlN films to be used for applications in surface acoustic wave devices (Jose et al., 2010;Moreira et al., 2011).On the other hand, the oxynitrides MeN x O y (Me=metal ) have become very important materials for several technological applications.Among them, aluminium oxynitrides may have promissing applications in diferent technological fields.The addition of oxygen into a growing AlN thin film induces the production of ionic metal-oxygen bonds inside a matrix Crystallographic orientation, lattice parameters, thickness and film quality were characterized through X-ray Diffraction (XRD) and UV-Visible spectroscopy (UV-Vis).Chemical indentification of phases and elemental concentration were characterized through X-ray photoelectron spectroscopy (XPS).From these results, an analysis of the interaction of oxygen into the AlN film is described.For a better understanding of this process, theoretical calculations of Density of States (DOS) are included too.The aim of this chapter is to provide from our experience a step wise scientific/technical guide to the reader interested in delving into the fascinating subject of thin film processing.

Deposition and growth of AlN films
The sputtering process consists in the production of ions within generated plasma, on which the ions are accelerated and directed to a target.Then, ions strike the target and material is ejected or sputtered to be deposited in the vicinity of a substrate.The plasma generation and sputtering process must be performed in a closed chamber environment, which must be maintained in vacuum.To generate the plasma gas particles (usually argon) are fed into the chamber.In DC sputtering, a negative potential U is applied to the target (cathode).At critical applied voltage, the initially insulating gas turns to electrical conducting medium.Then, the positively charged Ar + ions are accelerated toward the cathode.During ionization, the cascade reaction goes as follows: e -+ Ar  2e -+ Ar + where the two additional (secondary) electrons strike two more neutral ions that cause the further gas ionization.The gas pressure "P" and the electrode distance "d" determine the breakdown voltage "V B" to set the cascade reaction, which is expressed in terms of a product of pressure and inter electrode spacing: where A and B are constants.This result is known as Paschen´s Law (Ohring, 2002).
In order to increase the ionization rate by emitted secondary electrons, a ring magnet (magnetron) below the target can be used.Hence, the electrons are trapped and circulate over the surface target, depicting a cycloid.Thus, the higher sputter yield takes place on the target area below this region.An erosion zone (trace) is "carved" on the target surface with the shape of the magnetic field.
Equipment description: Films under investigation were obtained by DC reactive magnetron sputtering in a laboratory deposition system.The high vacuum system is composed of a pirex chamber connected to a mechanic and turbomolecular pump.Inside the chamber the magnetron is placed and connected to a DC external power supply.In front of the magnetron stands the substrate holder with a heater and thermocouple integrated.The distance target-substrate is about 5 cm and target diameter 1".The power supply allows to control the voltage input (Volts) and an external panel display readings of current (Amperes) and sputtering power (Watts) (see Figure 2).Deposition procedure: A disc of Al (2.54 cm diameter, 0.317 cm thick, 99.99% purity) was used as a target.Films were deposited on silica and glass substrates that were ultrasonically cleaned in an acetone bath.For deposition, the sputtering chamber was pumped down to a base pressure below 1x10 -5 Torr.When the chamber reached the operative base pressure, the Al target was cleaned in situ with Ar + ion bombardment for 20 minutes at a working pressure of 10 mTorr (20 sccm gas flow).A shutter is placed between the target and the substrate throughout the cleaning process.From set 2, three samples correspond to AlN (10 min of deposition time, labeled S5, S6 and S7) and one to AlNO (10 min of deposition time, labeled S8).All samples were deposited using an Ar flow of 20 sccm, an N 2 flow of 1 sccm and an O 2 flow of 1 sccm .In all samples (excluding the ones grown at room temperature.),the temperature was supplied during film deposition.
Tables 1 (a) (set 1) and 1 (b) (set 2) summarize the experimental conditions of deposition.Calculated optical thickness by formula 4 is included in the far right column.

Structural characterization
XRD measurements were obtained using a Philips X'Pert diffractometter equipped with a copper anode K radiation,  =1.54 Å. High resolution theta/2Theta scans (Bragg-Brentano geometry) were taken at a step size of 0.005.Transmission spectra were obtained with a UV-Visible double beam Perkin Elmer 350 spectrophotometer.From set 1, it can be observed that the intensity of (002) diffraction peak is the highest in S2.In this case, the temperature of 100 0 C increased the crystalline ordering of film.In S3 and S4 the intensity of (002) diffraction and grain size are very similar for both samples, which shows that applied temperature on S4 had not effect in improving its crystal ordering.
From set 2, it can be observed that the intensity of (002) diffraction peak is the highest in S5.
Generally, temperature gives atoms an extra mobility, allowing them to reach the lowest thermodynamically favored lattice positions hence, the crystal size becomes larger and the crystallinity of the film improves.However, the temperature applied to S6 and Ss makes no effect to improve their crystallinity.In this case, a substrate temperature higher than 100C can trigger a re-sputtering of the atoms that arrive at the substrate´s surface level and crystallinity of films experiences a downturn.
From set 1 and set 2, S2 and S5, respectively, were the ones that presented the best crystalline properties.A temperature r a n g i n g f r o m R T t o 1 0 0 C turned out to be the critical experimental factor to get a highly oriented crystalline growth.(Borges et al., 2010;Brien & Pigeat, 2007).Therefore, the existence of Al 2 O 3 or even spinel AlNO phases in samples cannot be discarded, but maybe in such a small proportions as to be detected by XRD.S1, S2 and S5 show a higher crystalline quality than S3, S4 and S8.For these last samples, the extra O 2 introduced to the chamber promotes the oxidation of the target-surface (target poisoning).In extreme cases when the target is heavily poisoned, oxidation can cause an arcing of the magnetron system.Formation of aluminium oxide on the target can act as an electrostatic shell, which in turn can affect the sputtering yield and the kinetic energy of species which impinge on substrate with a reduction of the sputtering rate: The lesser energy of species reacting on substrate, the lesser crystallinity of films.Also, the oxygen can enter in to the AlN lattice through a mechanism involving a vacancy creation process by substituting a nitrogen atom in the weakest Al-N bond aligned parallel to 0001 direction.During the process, the mechanism of ingress of oxygen into the lattice is by diffussion (Brien & Pigeat, 2007;Brien & Pigeat, 2008;Jose et al., 2010).On the other hand, the ionic radius of oxygen (r O =0.140 nm) is almost ten times higher than that of nitrogen (r N =0.01-0.02nm) (Callister, 2006).Thus, the oxygen causes an expansion of the crystal lattice through point defects.As the oxygen content increases, the density of point defects increases and the stacking of hexagonal AlN arrangement is disturbed .It has been reported that the Al and O atoms form octahedral atomic configurations that eventually become planar defects.These defects usually lie in the basal 001 planes (Brien & Pigeat, 2008;Jose et al., 2010).
As was mentioned, during the deposition of thin films, the oxygen competes with the nitrogen to form an oxidized Al-compound.The resulting films are then composed of separated phases of AlN and Al x O y domains.The presence of Al x O y domains provokes a disruption in the preferential growth of the film.For example, in S4, the applied temperature of 120 0 C can promote an even more efficient diffusive ingress of oxygen into the AlN lattice and such temperature was not a factor contributing to improve crystallinity.In S3 and S8, oxygen by itself was the factor that provoked a film´s low crystalline growth.By using the Bragg angle ( b ) as variable that satisfies the Bragg equation: and the formula applied for hexagonal systems: the length of the lattice parameters "a" and "c" can then be obtained from the experimental data.
As films crystallized in a hexagonal würzite structure, XRD patterns were processed with a software program in order to obtain the lattice parameters "a" and "c".The AlN würzite structure from the JCPDS database (PDF file 00- 025-1133, c= 4.97 Å, a=3.11 Å) was taken as a reference (Powder Diffraction File, 1998).For the fitting, input parameters of (h k l) planes with their corresponding theta-angle are given.By using the Bragg formula and the equation of distance between planes (for a hexagonal lattice), the lattice parameters are then calculated by using a multiple correlation analysis with a least squares minimization.The 2 angles were set fixed while lattice parameters were allowed to fit.Calculated lattice parameters "a" and "c" and grain size "L" by formula (4) are included in Table 2.
The average grain size "L" is obtained through the Debye-Scherrer formula (Patterson, 1939): where K is a dimensionless constant that may range from 0.89 to 1.30 depending on the specific geometry of the scattering object.
For a perfect two dimenssional lattice, when every point on the lattice produces a spherical wave, the numerical calculations give a value of K=0.89.A cubic three dimensional crystal is best described by K=0.94 (Patterson, 1939).
The measure of the peak width, the full width at half maximum (FWHM) for a given  b is denoted by B (for a gaussian type curve).
From table 2, it can be observed that the calculated lattice parameters differ slightly from the ones reported from the JCPDS database, mainly the "c" value, particularly for S3, S4 and S8.
Introduction of oxygen into the AlN matrix along the {001} planes also modifies the lattice parameters.As expected, the "c" value is the most affected.
The quality of samples can also be evaluated from UV-Visible spectroscopy (Guo et al., 2006).By analysing the measured T vs  spectra at normal incidence, the absorption coefficient () and the film thickness can be obtained.
If the thickness of the film is uniform, interference effects between substrate and film (because of multiple reflexions from the substrate/film interface) give rise to oscillations.
The number of oscillations is related to the film thickness.The appearence of these oscillations on analized films indicates uniform thickness.If the thickness "t" were not uniform or slightly tappered, all interference effects would be destroyed and the T vs  spectrum would look like a smooth curve (Swanepoel, 1983).
Oscillations are useful to calculate the thickness of films using the formula (Swanepoel, 1983;Zong et al., 2006): (5 Where t is the thickness of film, n the refractive index,  1 and  2 are the wavelength of two adjacent peaks.Calculated optical thickness of samples using the above mentioned formula, are included in Tables 1(a) and (b).
Regarding the absorbance (), a T vs  curve can be divided (grossly) into four regions.In the transparent region =0 and the transmitance is a function of n and t through multiple reflexions.In the region of weak absorption  is small and the transmission starts to reduce.
In the region of medium absorption the transmission experiences the effect of absoption even more.In the region of strong absorption the transmission decreases abruptly.This last region is also named the absorption edge.
Near the absorption edge, the absorption coefficient can expressed as: where h is the photon energy, E g the optical band gap and  is the parameter measuring the type of band gap (direct or indirect) (Guerra et al., 2011;Zong et al., 2006).Thus, the optical band gap is determined by applying the Tauc model and the Davis and Mott model in the high absorbance region.For AlN films, the transmittance data provide the best linear curve in the band edge region, taking n=1/2, implying that the transition is direct in nature (for indirect transition n=2).Band gap is obtained by plotting (h) 2 vs h by extrapolating the linear part of the absorption edge to find the intercept with the energy axis.By using UV-Vis measurements for AlNO films on glass sustrates, authors of ref. (Jang et al., 2008) found band gap values between 6.63 to 6.95 eV, depending the Ar:O ratio.
From our measurements, figure 4 displays the optical spectra (T vs  curve) graphs.The oscillations detected in the curves attest the high quality in homogeneity of deposited films.
All the samples have oscillation regardless their degree of crystallinity.An important feature to note is that curves present differences in the "sharpness", at the onset of the strong absorption zone.These differences are attributed to deposition conditions, where final density of films, presence of deffects and thickness, modify the shape of the curve at the band edge.
A FESEM micrograph cross-section of S2 is displayed on figure 5. From figure, it is possible to identify a well defined substrate/film interface and a section of film with homogeneous thickness.Together with micrographs, in-situ EDAX analyses were conducted in two specific regions of the film.An elemental analysis by EDAX allows to distinguish the differences in elemental concentration depending on the analized zone.In the film zone , an elemental concentration of Al (54.7 %) and N (45.2 %) was detected, as expected for AlN film.Conversely, in the substrate zone, elemental concentration of Si and O with traces of Ca, Na, Mg was detected, as expected for glass.At this stage, we can establish that during the sputtering process, the oxygen diffuses in to the growing AlN films.Then, the oxygen attaches to available Al, forming Al x O y phases.Dominions of these phases, contained in the whole film, can induce defects.These defects are piled up along the c-axis.From X-ray diffractograms, a low and narrow intensity at the (0002) reflection indicates low crystallographic ordering.By calculating lattice parameters "a" and "c" and evaluating how far their obtained values deviate from the JCPDF standard (mainly the "c" distance), also provides evidence about the degree of crystalline disorder.In films, a low crystallographic ordering does not imply a disruption in the homogeneity, as was already detected by UV-Visible measurements.A more detailed analysis concerning the identification and nature of the phases contained in films were performed with a spectroscopic technique.

Chemical characterization
The process of oxidation is a micro chemical event that was not completely detected by XRD.Because of that, XPS analyses were performed in order to detect and identify oxidized phases.XPS measurements were obtained with a Perkin-Elmer PHI 560/ESCA-SAM system, equipped with a double-pass cylindrical mirror analyzer, and a base pressure of 110 -9 Torr.
To clean the surface, Ar + sputtering was performed with 4 keV energy ions and 0.36 A/cm 2 current beam, yielding to about 3 nm/min sputtering rate.All XPS spectra were obtained after Ar + sputtering for 15 min.The use of relatively low current density in the ion beam and low sputtering rate reduces modifications in the stoichiometry of the AlN surface.For the XPS analyses, samples were excited with 1486.6 eV energy Al K X-rays.XPS spectra were obtained under two different conditions: (i) a survey spectrum mode of 0-600 eV, and (ii) a multiplex repetitive scan mode.No signal smoothing was attempted and a scanning step of 1 eV/step and 0.2 eV/step with an interval of 50 ms was utilized for survey and multiplex modes, respectively.The spectrometer was calibrated using the Cu 2p 3/2 (932.4 eV) and Cu 3p 3/2 (74.9 eV) lines.Al films deposited on the glass and silica substrates were used as additional references for Binding energy.In both kind of films, the BE of metallic (Al 0 ) Al2ptransition gave a value of 72.4 eV respectively.On these films, the C1s-transition gave values of 285.6 eV and 285.8 eV for glass and silica substrates, respectively.These values were set for BE of C1s.The relative atomic concentration of samples was calculated from the peak area of each element (Al2p, O1s, N1s) and their corresponding relative sensitivity factor values (RSF).These RSF were obtained from software system analysis (Moulder, 1992).Gaussian curve types were used for data fitting.Figure 6 displays the XPS spectra of films.The elemental attomic concentration (atomic percent) calculated from the O1s, N1s and Al2p transitions is also included in the figure.
Figure 6a shows the Al2p high-resolution photoelectron spectrum of S1.The binding energies (BE) from the acquired Al2p photoelectron transition are presented in table 3. The survey spectra show the presence of oxygen in all films, regardless of the fact that some samples were grown without oxygen during deposition.From the XPS analysis, S2 and S5, our films with the best crystalline properties, a concentration of oxygen of 26.3% and 21.6% atomic percent respectively, was measured.The highest measured concentration of oxygen was of about 36.6%, corresponding to S8.This occurrence of oxidation was not directly detected by the XRD analysis, since these oxidized phases can be spread in a low amount throughout the film.The nature of these phases can be inferred from the deconvoluted components of the Al2p transition.In Figure 6a, the Al2p core level spectrum is presented.This spectrum is composed of contributions of metallic Al (BE=72.4eV), nitridic Al in AlN (BE=74.7 eV) and oxidic Al in Al 2 O 3 (BE=75.6eV).Despite the differences in experimental conditions, aluminium reacted with the nitrogen and the oxygen in different proportions.Even in S2, the thin film with the best crystalline properties, a proportion of about 30.6 % of aluminum reacted with oxygen to form an aluminium oxide compound.In S7, the relative contribution of Al in nitridic and oxidic state is almost similar, of 42.2% and 49.5%, respectively.A tendency, not absolute but in general, indicates that the higher the proportion of Al in oxidic state, the more amorphous the film.4).
Table 4. Binding energy of (eV) of metallic aluminium (Al O ), aluminium in nitridic (Al-N) and oxidic (Al-O) state obtained from literature In films, only small traces of metallic aluminium were detected in S1 at 72.4 eV.For S4 and S8, BE of Al in nitride gave a value of 74.4 eV, just below the of 74.7 eV, detected for the rest of the samples.This value of 74.4 eV can be attributed to a substoichiometric AlN x phase (Robinson et al., 1984;Stanca, 2004).On the other hand, the BE for aluminium in oxydic state varies from 75.1 eV to 75.7 eV.The lowest values of BE of about 75.1 eV and 75.2 eV, corresponding to S3 and S4, respectively, could be attributed to a substoichiometric Al x O y phase, although in our own experience, the reaction of aluminium with oxygen tends to form the stable -Al 2 0 3 phase, which possesses somewhat higher value in BE.These finding agree with those reported in other works, where low oxidation states such as Al +1 , Al +2 can be found at a BE lower than the one of Al +3 (Huttel et al., 1993;Stanca, 2004).Oxidation states lower than +3 confer an amorphous character to the aluminium oxide (Gutierrez et al., 1997).

Theoretical calculations
Experimental results provided evidence that oxygen can induce important modifications in the structural properties of sputtered-deposited AlN f i l m s .I n t h i s w a y , t h e o r e t i c a l calculations were performed to get a better understanding of how the position of the oxygen into the AlN matrix can modify the electronic properties of the film system.The bulk structure of hexagonal AlN was illustrated in Figure 1.Additionally, hexagonal AlN can be visualized as a matrix of distorted tetrahedrons.In a tetrahedron, each Al atom is surrounded by four N atoms.The four bonds can be categorized into two types.The first type is formed by three equivalent Al-Nx, (x=1,2,3) bonds, on which the N atoms are located in the same plane normal to the 0001 direction.The second type is the Al-N 0 bond, on which the Al and N atoms are aligned parallel to the 0001 direction (see figure 7).This last bond is the most ionic and has a lower binding energy than the other three (Chaudhuri et al., 2007;Chiu et al., 2007;Zhang et al, 2005).When an AlN film is oxidized, the oxygen atom can substitute the nitrogen atom in the weakest Al-N0 bond while the displaced nitrogen atom can occupy an interstitial site in the lattice (Chaudhuri et al., 2007).For würzite AlN, there are four atoms per hexagonal unit cell where the positions of the atoms for Al and N are: Al(0,0,0), (2/3,1/3,1/2); N(0,0,u), (2/3,1/3, u+1/2), where "u" is a dimensionless internal parameter that represents the distance between the Al-plane and its nearest neighbor N-plane, in the unit of "c", according to the JCPDS database (Powder diffraction file, 1998).
The calculations were perfomed using the tight-binding method (Whangbo & Hoffmann, 1978) within the extended Hückel framework (Hoffmann, 1963) using the computer package YAeHMOP (Landrum, 1900).The extended Hückel method is a semiempirical approach that solves the Schrödinger equation for a system of electrons based on the variational theorem (Galván, 1998).In this approach, explicit correlation is not considered except for the intrinsic contributions included in the parameter set.For a best match with the available experimental information, experimental lattice parameters were used instead of optimized values.Calculations considered a total of 16 valence electrons corresponding to 4 atoms within the unit cell for AlN.Band structures were calculated using 51 k-points sampling the first Brillouin zone (FBZ).
Reciprocal space integration was performed by k-point sampling (see figure 8).From band structure, the electronic band gap (E g ) was obtained.Theoretical band-gap calculations are summarized in Table 5.Values are given in electron volts (eV).
Table 5. Calculated energy gaps for pure AlN (würzite) and with oxygen in different atomic site positions.
For AlN hexagonal, a direct band gap of  7.2 eV at M was calculated (see Figure 9).When oxygen was taken into account in the calculations, the band gap value undergoes a remarkable change: 1.3 eV for AlN with intercalated oxygen (2) and 0.8 eV for AlN with oxygen substitution (3).In terms of electronic behavior, the system transformed from insulating (7.2 eV) to semiconductor (1.3 eV), and then from semiconductor (1.3 eV) to semimetal (0.82 eV).This change in the electronic properties is explained by the differences between the ionic radius of Nitrogen (r N ) and Oxygen (r O ).The ionic radius of the materials involved was: r N =0.01-0.02nm, r O =0.140 nm (Callister, 2006).Comparing these values, it can be noted that r O is almost ten times higher than r N .This fact would imply that when the oxygen atom takes the place of the nitrogen atom (by substitution o intercalation of O), the crystalline lattice expands because of the larger size of oxygen.Any change in the distance among atoms and the extra valence electron of the oxygen will alter the electronic interaction and in consequence, the band gap value In calculation (4), the atoms of Al and N are kept in their würzite atomic positions while the oxygen atom is placed on top of the AlN lattice.In this case, the calculated band gap (6.31 eV) is closer in value to pure AlN (7.2 eV) than the calculated ones for interstitial (1.3 eV) and substitution (0.82 eV).In this case, theoretical results predicts that when the oxygen is not inside the Bravais lattice, the band gap will be close in value to the one of hexagonal AlN; conversely, the more the oxygen interacts with the AlN lattice, the more changes in electronical properties are expected; However, in energetic terms, competition between N and O atoms to get attached to the Al to form separated phases of AlN and Al x O y is the most probable configuration, as far as experimental results suggests.Theoretical calculations of band structure for würzite AlN have been performed using several approaches; For comparison purposes, some of them are briefly described in Table 6.From our results, the calculated band gap for AlN was 7.2 eV: slightly different to the reported experimental-value of  6.2 eV.About this issue, is important to take into account that in our calculations spin-orbit effects were not considered.Therefore, some differences arise, especially when an energy-band analysis is performed.Some bands could be shifted up or down in energy due to these contributions.However, it must be stressed out that our proposed method is simple, computationally efficient and the electronic structures obtained can be optimized to closely match the experimental and/or ab-initio results.More specific details about DOS graphs and PDOS calculations can be found in reference (García-Méndez et al., 2009), of our authorship.

Conclusions
In this chapter, the basis of DC reactive magnetron sputtering as well as experimental results concerning the growth of AlN thin films has been reviewed.For instance, films under investigation were polycrystalline and exhibit an oriented growth along the 0002 direction.XRD measurements showed that films are composed mainly by crystals of hexagonal AlN.From XPS measurements, traces of aluminium oxides phases were detected.Films deposited without flux of oxygen presented the best crystalline properties, although phases of aluminum oxide were detected on them too.In this case, even in high vacuum, ppm levels of residual oxygen can subside and react with the growing film.Oxygen induces on films structural disorder that tends to disturb the preferential growth at the c-axis.
In other works of reactive magnetron sputtering, authors of ref. (Brien & Pigeat, 2008) found that for contamination of oxygen atoms (from 5% to 30 % atomic), AlN films can still grow in würzite structure at room temperature, with no formation of crystalline AlNO or Al 2 O 3 phases, just only traces of amorphous AlO x phases, that leave no signature in diffraction recordings, which is consistent with our results, where a dominant AlN phase in the whole film was detected.On the other hand, authors of ref. (Jose et al., 2010) reports that even in high vacuum, ppm levels of oxygen can stand and promote formation of alumina-like phases at the surface of AlN films, where these phases of alumina could only be detected and quantified by XPS and conversely, X-ray technique was unable to detect.In other report, authors of ref. (Borges et al., 2010), stablished three regions: Metallic (zone M), transition (zone T) and compound (zone C), where chemical composition of AlNO films varies depending the reactive gas mixture in partial pressure of N 2 +O 2 at a fixed Ar gas partial pressure.Then, they found that when film pass from zone M to zone C, films grow from crystalline-like to amorphous-type ones, and the lattice parameters increase as more oxygen and nitrogen is incorporated into the films, which also represents the tendency we report in our results.Thus, the versatility of the reactive DC magnetron sputtering that enables the growth of functional and homogeneous coatings in this case AlN films has been highlighted.To produce suitable films, however, it is necessary to identify the most favourable deposition parameters that maximize the sputtering yield, in order to get the optimal deposition rate: the sputter current that determines the rate of deposition process, the applied voltage that determines the maximum energy at which sputtered particles escape from target, the pressure into the chamber that determines the mean free path for the sputtered material, together with the target-substrate distance that both determines the number of collisions of particles on their way to the substrate, the gas mixture that determines the stoichiometry, the substrate temperature, all together influence the crystallinity, homogeneity and porosity of deposited films.As the physics behind the sputtering process and plasma formation is not simple, and many basic and technological aspects of the sputtering process and AlN film growth must be explored (anisotropic films, preferential growth, band gap changes), further investigation in this area is being conducted.

Fig. 2 .
Fig. 2. Schematic diagram of the equipment utilized for film fabrication.
Figure 3 (a) and (b) display the XRD patterns of the films deposited on glass (set 1) and silica (set 2) substrates, respectively.The diffraction pattern of films displayed in figure 3 match with the standard AlN würzite spectrum (JCPDS card 00-025-1133, a=3.11Å, c=4.97 Å) (Powder Diffraction file, 1998).The highest intensity of the (002) reflection at 2θ35.9 0 indicates an oriented growth along the caxis perpendicular to substrate.

Fig. 6 .
Fig. 6.XPS survey spectra of dc sputtered films.In this figure, the O1s, N1s and Al2p corelevel principal peaks can be observed.
The Target was systematically cleaned to remove any contamination before each deposition.Sputtering discharge gases of Ar, N 2 and O 2 (99.99 % purity) were admitted separately and regulated by individual mass flow controllers.A constant gas mixture of Ar and N 2 was used in the sputtering discharge to grow AlN films; a gas mixture of Ar, N 2 and O 2 was used to grow AlNO films.A set of eight films were prepared: four samples on glass substrates (set 1) and four samples on silica substrates (set 2).From set 1, two samples correspond to AlN (15 min of deposition time, labeled S1 and S2) and two to AlNO (10 min of deposition time, labeled S3 and S4).

Table 1b .
Deposition parameters for DC sputtered films grown on silica substrates (set 2).

Table 6 .
AlN energy band gap values obtained from theoretical calculations.