ISIS Neutron and Muon Source Data Journal

This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.


Phase transitions in non-centrosymmetric Dion-Jacobson Phases

Abstract: Ferroelectric materials - those which exhibit a spontaneous and switchable electrical polarization - have a wide range of applications. However materials which exhibit ferroelectric behaviour are rare because in order to exhibit a spontaneous electrical polarization, materials must adopt a non-centrosymmetric crystal structure.We have been studying a series of layered perovskite phases which adopt non-centrosymmetric structures at room temperature. It is proposed that the non-centrosymmetric structures and resulting ferroelectric behaviour arise due to a novel ‘hybrid improper’ mechanism. In order to confirm this hypothesis we need to determine the structures adopted by these compounds at high temperature, because the nature of the phase transitions between ferroelectric and non-ferroelectric states is characteristic of the mechanism which leads to ferroelectric behaviour.

Public release date: 13 May 2021

Principal Investigator: Professor Michael Hayward
Experimenter: Miss Lun Jin
Local Contact: Dr Alexandra Gibbs
Experimenter: Mr Tong Zhu

DOI: 10.5286/ISIS.E.92919436

Parent DOI: 10.5286/ISIS.E.RB1810073

ISIS Experiment Number: RB1810073

Part Number: 1

Date of Experiment: 10 May 2018

Publisher: STFC ISIS Neutron and Muon Source

Data format: RAW/Nexus
Select the data format above to find out more about it.

Data Citation

The recommended format for citing this dataset in a research publication is as:
[author], [date], [title], [publisher], [doi]

For Example:
Professor Michael Hayward et al; (2018): Phase transitions in non-centrosymmetric Dion-Jacobson Phases, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.92919436



UKRI


Science and Technology Facilities Council Switchboard: 01793 442000