This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Local structure of polymers in confined geometries in surface dominated samples
Abstract: This proposal is focused on developing an understanding of how surfaces affect the local structure of synthetic polymers. There is considerable evidence for a strong variation in the local structure in nanocomposites. However, there has been no real attempt to quantify the structural effects. We have recently carried some experiments on GEM to exploit the particular advantages of neutron scattering to probe these effects; they were very successful. These novel experiments were based on deuterated atactic polystyrene with a high loading of silica and boehmite nanoparticles which results in all the material having a major exposure to a local surface. These experiments revealed significant variations in the local structure and we wish to explore this approach further with a wider range of samples with different molecular weights, nanoparticle size and composition.
Public release date: 28 May 2012
Principal Investigator: Professor Geoffrey Mitchell
Experimenter: Dr Fred Davis
Experimenter: Mr Robert Olley
Experimenter: Dr Saeed Mohan
DOI: 10.5286/ISIS.E.24068026
ISIS Experiment Number: RB910514
Part Number: 1 - SANDALS
Date of Experiment: 25 May 2009
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
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publication is as:
[author], [date], [title], [publisher],
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Professor Geoffrey Mitchell et al; (2009): Local structure of polymers in confined geometries in surface dominated samples, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.24068026