This is a page describing data taken during an experiment at the ISIS Neutron and Muon Source. Information about the ISIS Neutron and Muon Source can be found at https://www.isis.stfc.ac.uk.
Enhanced oxygen hyperstoichiometry in Y doped La9.33+xGe6O26+3x/2
Abstract: Apatite-type lanthanide silicates/germanates have been attracting considerable interest as a new class of oxide ion conductors. The presence of interstitial oxide ions is vitally important for the high oxide ion conductivities of these phases, although the location of these interstitial sites has attracted some controversy. The accurate location of the interstitial oxide ions is non-trivial as their presence causes significant localised structural distortions. Therefore there is a need for further detailed studies in this area. Recently we have shown that Y doping in La9.33+xGe6O26+3x/2 increases the maximum interstitial oxygen content by over 50%, thus allowing greater ease of their location, and in this experiment a detailed structural study of these phases will be performed with a view to accurately locating these interstitial sites.
Public release date: 21 October 2010
Experimenter: Dr Julia Percival
Experimenter: Dr Peter Slater
DOI: 10.5286/ISIS.E.24003271
ISIS Experiment Number: RB720166
Part Number: 1 - POLARIS
Date of Experiment: 19 October 2007
Publisher: STFC ISIS Neutron and Muon Source
Data format: RAW/Nexus
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Data Citation
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Dr Julia Percival et al; (2007): Enhanced oxygen hyperstoichiometry in Y doped La9.33+xGe6O26+3x/2, STFC ISIS Neutron and Muon Source, https://doi.org/10.5286/ISIS.E.24003271