Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano- and microscopic vesicles

Data underlying the figures in the publication “Fully amorphous atactic and isotactic block copolymers and their self-assembly into nano- and microscopic vesicles”, published in Polym. Chem., 2021, 12, 5377-5389.

https://pubs.rsc.org/en/content/articlelanding/2021/PY/D1PY00952D

Table of contents:

1. Figure 1: Zip archive containing the experimental data (NMR spectra) for the kinetics of the PBO syntheses (Figure 1c) and the PBO-b-PEEGE syntheses (Figure 1d).

2. Figure 2: Zip archive containing the experimental data for Figure 2. Structural characterisation of the (S)-BCP (S)-PBO₂₇-b-(S)-PG₁₄ by ¹H-NMR spectroscopy in methanol-d₄.

3. Figure 3: Zip archive containing the experimental data for Figure 3. Chiral characterisation of the atactic and isotactic BCPs.

4. Figure 4: Zip archive containing the experimental data for Figure 4. TEM and Cryo-TEM characterisation of the SUVs formed by (a) (R/S)-PBO₂₆-b-(R/S)-PG₁₄, (b) (R)-PBO₂₆-b-(R)-PG₁₄ and (c) (S)-PBO₂₇-b-(S)-PG₁₄.

5. Figure 5: Zip archive containing the CLSM images for Figure 5.

6. Figure 6: Zip archive containing the images for Figure 6. Snapshots of the enzyme reaction within the cavity of (R/S)-BCP GUVs (b) with and (c) without reconstituted membrane protein OmpF, recorded by CLSM at different time points

7. Figure 7: Excel file containing the experimental data for Figure 7. Fluorescence intensity development of (a) (R/S)-BCP and (b) PDMS₂₅-b-PMOXA₁₀ GUVs resulting from the reaction of resorufin β-D-galactopyranoside (RGP) with β-galactosidase (β-Gal) to yield fluorescent resorufin.

8. Table 1: Zip archive containing the experimental data for Table 1.

9. Table 2: Zip archive containing the experimental data for Table 2.