Kinematics and time-resolved evolution of the main thrust-sense shear zone in the Eo-Alpine orogenic wedge (the Vinschgau Shear Zone, Eastern Alps)

The Vinschgau Shear Zone (VSZ) is one of the largest and most significant shear zones developed in plastic conditions within the Austroalpine domain, juxtaposing the Ötztal and the Texel units to the Campo, Scharl and Sesvenna units during the building of the Eo-Alpine Orogen. The VSZ dominates the structural setting of a large portion of the central 15 Austroalpine Late Cretaceous thrust stack. In order to fully assess the evolution of the VSZ, a multi-faceted approach based on detailed multiscale structural and petrochronological analyses has been carried out across representative transects of the shear zone in the Vinschgau Valley. The research has been performed with a view to characterizing kinematics, PT conditions and timing of motion of the VSZ. Our fieldwork-based analyses suggest that the dip angle of mylonitic foliation increases from W to E with an E-W trending 20 stretching lineation which dips alternatively to the W and to the E, due to later folding related to the Cenozoic crustal shortening. The dominant top to the W shear sense of the mylonites recognized in the field and confirmed by microstructural analyses led to exhumation of the upper Austroalpine nappes in the hanging wall of the shear zone: the Texel unit with Late Cretaceous eclogites, the Schneeberg and Ötztal units both affected by Eo-Alpine amphibolite-facies metamorphism. Chemical and microstructural analyses suggest deformation temperatures of ca. 350-400 °C during 25 shearing. Timing of deformation along the VSZ has been constrained for the first time through 40 Ar/ 39 Ar dating of syn-shearing micas, which reveal a Late Cretaceous age of the VSZ mylonites with ages ranging between 80 and 97 Ma. A systematic younging age of deformation occurs towards the central part of the shear zone in the studied transects. Vorticity analysis shows a clear decrease in the simple shear component correlated to the younging of mica ages towards the core of the shear zone. This evolution is consistent with the growth of a shear zone where shear strain localizes into its central 30 part during deformation. The defined evolution of the VSZ sheds new light on how large-scale thrust-sense shear zones act and how much exhumation they can accommodate in the frame of an evolving orogenic wedge


Introduction
The Vinschgau Shear Zone (VSZ), extending along the homonymous valley (NE Italy; Fig. 1a-b), is one of the most important tectonic structures developed within the Austroalpine domain of the Alps (Fig. 1 and Fig. 2).Starting from the first systematic studies of the Alpine belt, this large shear zone, firstly defined as the "Schlinig Thrust", was interpreted as a top-to-W thrust plane (Spitz and Dyhrenfurth, 1914).Although several authors later rejected this interpretation (Heim, 1922;Staub, 1937), modern studies (Schmid and Haas, 1989;Froitzheim et al., 1994Froitzheim et al., , 1997) ) carried out since the end of the last century demonstrated the validity of the first assumptions.Recent structural analyses (Brunel, 1980;Ratschbacher, 1986, Ratschbacher et al., 1989;Schmid and Haas, 1989;Pomella et al., 2016) recognized indeed that the entire central Austroalpine nappe stack was affected by W-directed tectonic transport during the first stages of the Late Cretaceous Alpine deformations.Along the VSZ, the Austroalpine tectonometamorphic units with a dominant metamorphism of Alpine age overthrust Austroalpine units (Sesvenna and Campo-Ortler) that were only slightly affected by Alpine metamorphism (up to greenschist facies) and deformation during the Eo-alpine stage (Thöni, 1981), still largely preserving features acquired during the Variscan orogeny.The VSZ is almost continuously exposed for more than 50 km, mainly on the northern flank of the Vinschgau Valley (Fig. 1), reaching a maximum thickness of about 550 m close to Eyrs (Fig. 1 and Fig. 2).These features make the VSZ one of the largest ductile thrust-sense shear zone now exposed in the Alps, together with the Periadriatic Fault (Schmid et al., 1987;1989) and the Orobic Thrust in the Southern Alps (Zanchetta et al., 2011;D'Adda and Zanchetta, 2015).The Noric Thrust in the Eastern Alps (Ratschbacher, 1986) is another important ductile thrust, the first one studied by modern kinematic and structural methods.Due to its complete exposure and accessibility, the prominent VSZ represents an ideal natural laboratory for the study of cumulative shear strain distribution during the development of a large mature intrabasement shear zone and to evaluate the evolution in terms of shear strain localization, coaxiality, kinematic, and lifetime of activity (e.g.Xypolias, 2010;Xypolias and Koukouvelas, 2001;Law et al., 2013;Fossen and Cavalcante, 2017;Oriolo et al., 2016Oriolo et al., , 2018)).
Large scale thrust-or normal-sense shear zones developed within collisional setting display huge along-strike exposures as the ca.2500 km of the Main Central Thrust and South Tibetan Detachment in the Himalayan orogen (e.g.Caby et al., 1983;Searle et al., 2008), the ca.30 km of the Simplon Shear Zone (Mancktelow, 1985) and Brenner Fault (Rosenberg et al., 2018) in the Alps or the Great Slave Lake shear zone (Hamner et al., 1992) in northern Canada.Due to its peculiar exposure along strike, the VSZ shows different features from shallow depth conditions at its western portion and deeper conditions at the eastern end (Schmid and Haas, 1989), providing a complete crustal section of a large scale shear zone.This kind of exposure provides insights not only on the different deformation mechanisms and behaviours of the shear zone at different crustal levels, but also on its evolution through time.In this work, we applied a quantitative approach to reconstruct the evolution through space (depth) and time of the VSZ. 40Ar/ 39 Ar dating of syn-mylonitic micas sampled along several transects of the VSZ have been combined with microstructural and mineralogical analyses, aimed to define the PT condition of shearing.The analysis of the cumulative shear strain distribution and the kinematic vorticity of flow (e.g.Montemagni and Zanchetta, 2022;Petroccia et al., 2022) finally provide a full kinematic and time-resolved evolution of the VSZ, that could be taken as an example of how a regional-scale thrust-sense shear zone develops within a collisional orogen.

Geological setting
The study area (Fig. 1 and Fig. 2) is located along the Vinschgau Valley (NE Italy) entirely extending within the central Austroalpine domain, comprised between the Northern Calcareous Alps to the north and the Periadriatic Fault to the south (Fig. 1).Here, the Austroalpine domain consists of tectono-metamorphic units that have been identified based on paragenesis, deformation history, metamorphism and relative ages.These units are the Pejo and Laas units (belonging to the Campo-Ortler nappe system), and the Ötztal-Stubai Complex, the Matsch unit, and, finally, the Texel and the Schneeberg units, belonging to the Koralpe-Wölz high-pressure nappe system (Schmid et al., 2004;Handy et al., 2010;Pomella et al., 2016;Klug and Froitzheim, 2022).The E-W striking VSZ separates the Pejo and Laas units to the south, the footwall of the VSZ characterized by greenschist facies Alpine metamorphism, from the Ötztal, Matsch, Texel and Schneeberg units forming the hanging wall, characterized by amphibolite to eclogite facies Alpine metamorphism (Fig. 2).Therefore, the VSZ together with the Passeier Fault, the Jaufen Fault and the Defereggen-Antholz-Vals Fault (PSF, JF and DAV in Fig. 1) has been considered to form the Southern limit of Alpine Metamorphism (SAM, Hoinkes et al., 1999), a large faults system defining the southern border of the high-grade Alpine metamorphism in the Austroalpine domain of the Eastern Alps.The VSZ has been described as a ductile-to-brittle fault formed by a thick zone of mylonites and phyllonites exposed mainly along the left hydrographic side of the Vinschgau Valley (Fig. 2; Schmid and Haas, 1989;Conti, 1994;Froitzheim et al., 1997;Thöni, 1999;Sölva et al., 2005;Pomella et al., 2016;Koltai et al., 2018;Klug and Froitzheim, 2022).Schmid and Haas (1989) defined the main structure as a thick intrabasement shear zone dominated by intracrystalline plastic processes, showing different thermal conditions ranging from 300 °C to the west up to 500 °C to the east.The VSZ forms a wide system of shear zones, branching out eastward across the folded boundaries between the Ordovician Partschinser Granodiorite (also named Tschigot orthogneiss, Zantedeschi, 1991) and the host paragneiss of the Texel unit.The VSZ shows a gently N-dipping foliation (20°-30°) and a constantly E-W trending lineation, with kinematic indicators at the mesoscopic and microstructural scale that point to a top-to-N/NW sense of shear (Schmid and Haas, 1989).
Four tectonic units mainly consisting of polyphase metamorphic crystalline basement rocks, which have been deeply involved in the Alpine deformation and metamorphism, form the hanging wall of the shear zone.They consist of the western termination of the Texel and Schneeberg units, and of the Ötztal unit, one of the largest nappes of the Late Cretaceous Austroalpine thrust stack, which is overthrust by the Matsch unit, forming a folded klippe atop of the VSZ mylonites.
The age pattern of the Alpine metamorphic peak of the tectonometamorphic units in the hanging wall of the VSZ displays almost coeval ages in the Texel and the Schneeberg units.Partially amphibolitized eclogite boudins, preserved within the micaschists and paragneisses of the Texel unit, point to metamorphic peak conditions during the Alpine orogenesis of 540-630 °C and 1.2-1.4GPa (Habler et al., 2006), with even higher temperature and pressure suggested for other eclogite occurrences (Poli, 1991;Zanchetta et al., 2012;Zanchetta et al., 2013).Peak metamorphic conditions close to the amphibolite/eclogite facies boundary have been suggested for the Schneeberg unit, with peak temperature of 550-600 °C, at pressure of 0.8-1.0Gpa (Konzett and Hoinkes, 1996;Krenn et al., 2011).Geochronological data point to a Late Cretaceous age for both the Texel eclogites (U-Pb zircon ages of 84 ± 5 Ma; Habler et al., 2006;Zanchetta et al., 2013) and the upper amphibolite facies metamorphism of the Scheneeberg unit, for which ages ranging between 85-86 Ma ( 40 Ar/ 39 Ar age on paragonitic white mica in amphibolites, Konzett and Hoinkes, 1996) and 90.9 ± 4.1 Ma (Sm-Nd on garnet cores in metapelites, Sölva et al., 2005) have been obtained.
The age and the peak metamorphic conditions experienced by the Ötztal unit during the Alpine metamorphism are far less constrained.Mid to Late Cretaceous K-Ar mica ages (100-110 Ma) have been obtained by Thöni (1980) from the basement in the hanging wall of the VSZ and a whole rock Rb-Sr age of 83 ± 1 Ma resulted from a metapegmatite of the Matsch unit (Fig. 2) at the western end of the VSZ (Thöni, 1986).An Alpine age of upper greenschist facies metamorphism in the Matsch unit has been also argued by Habler et al. (2009), on the base of Early to Middle Permian intrusions age of pegmatites, later deformed and metamorphosed, and the growth of chloritoid after pre-Alpine staurolite.The Alpine metamorphism in the Ötztal unit reached 530-550 °C in the southeastern part (Purtscheller and Rammlmair, 1982;Hoinkes et al. 1999), with temperatures that progressively decrease toward NW.Pressure estimates are substantially lacking.On the base of newly formed mineralogical assemblages in pre-Alpine andesitic and andesitic/basaltic dikes intruding the Ötztal basement, Purtscheller and Rammlmair (1982) supposed a maximum pressure of about 0.5-0.6Gpa, confirmed by recent data (Zanchetta et al., 2013).Additional PT estimates have been proposed by Gregnanin and Valle (1995) for the Ötztal metasedimentary cover (550 °C and 1.0 Gpa), and by Tropper and Reichis (2009) for the SW part of the Ötztal basement (560 °C and 0.88 Gpa) close to the Schneeberg unit.The westernmost portion of the VSZ is crosscut by the Glurns Fault (GF in Fig. 2), along which the Ötztal basement is in contact with the Sesvenna unit, mainly consisting of orthogneiss with a Variscan medium-grade metamorphic imprint and its Permian-Mesozoic sedimentary cover (Froitzheim et al., 1994;1997).

Structural analysis 3.1. General description and methods
The entire VSZ has been individuated and followed in the field from Naturns (E) to Glurns (W) (Fig. 2).The maximum thickness is reached close to its western ends, at Eyrs, where it is estimated to be of about 600 m.To the east of Naturns (Fig. 2) the VSZ widens and branches out in several shear zones that wrap around the rigid body of the Partschinser orthogneiss of the Texel unit, as already noticed by Schmid and Haas (1989), which has given a Rb-Sr radiometric age of about 450 Ma for Partschinser orthogneiss (Zantedeschi, 1991).Here, in the Meran area, the VSZ is crosscut by most recent shear zones and faults (Bargossi et al., 2010).
Detailed field structural analyses and sampling of the VSZ were performed along three selected transects (Fig. 2) in the localities, from E to W: Juval, Schlanders and Eyrs.The three studied geological sections were chosen through field surveys and structural analyses.They are considered to be representative of the entire VSZ at different depths of exposure (shallowest conditions at Eyrs and deepest at Juval) and offer also the possibility to study and sampling the shear zone in continuity, due to the good bedrock exposure.Each transect (Fig. 2) has been mapped at a 1:2,000 scale, identifying the distribution of protomylonites, mylonites and ultramylonites following the classification by Simpson and De Paor (1993).
Sampling sites were accurately selected on the base of their representativity along the transects and the possibility they offered to perform microstructural and geochronological analyses.

The Juval transect
The easternmost transect is completely within the Texel unit.The cross section extends SE-NW, from the bottom of the Vinschgau valley to the Juval Castle.Here the road is entirely excavated in the bedrock, offering a continuous exposure of the entire shear zone.The bedrock mainly consists of granitoid orthogneiss (Partschinser orthogneiss) showing different mylonitization degrees.This transect almost corresponds to the westernmost termination of the Texel unit (Fig. 2).Besides the Partschinser orthogneiss, the Texel unit here consists of garnet, staurolite and kyanite bearing paragneiss that are also affected by mylonitization.They chiefly occur in the upper and central part of the transect, alternating with the orthogneiss.Some amphibolite boudins (Fig. 3d) are also exposed within the paragneiss along the road that takes to the Juval Castle.Paragneisses display a decrease in grain size with respect to the ones outside the VSZ, especially in the central part of the transect, where they can be classified as protomylonites.Analysis of the shear strain distribution highlights a symmetric increase, from rims to core, with ultramylonites and mylonites (Fig. 3) concentrated in the central part of the shear zone, whereas protomylonitic textures mainly occur both close to the structurally higher and lower margins.The mylonitic foliation is defined by the SPO (Shape Preferred Orientation, Passchier and Trouw, 2005) of biotite.The mylonitic lineation visible in outcrops mainly consists of elongated quartz aggregates and aligned biotite crystals (see section 3.2 for details).Foliation dips towards NNW, with mylonitic lineations that are nearly horizontal trending ENE-WSW (Fig. 2b).Moving toward the core of the shear zone, the clast-matrix ratio decreases, as does the size of K-feldspar porphyroclasts (Fig. 3).Ultramylonites appear as dark-grey bands within mylonites, a few centimetres up to 3-4 metres in thickness (Fig. 3c).Quartz ribbons, a few millimetres in thickness and up to several decimetres in extension, frequently occur (Fig. 3e).Porphyroclasts are scarce within the ultramylonites, with a mean size not exceeding a few millimetres, whereas they commonly display a mean size of 20-30 mm outside the shear zone.Kinematic indicators represented by σ and δ clasts (Fig. 3b), antithetic bookshelves in K-feldspar porphyroclasts and SCC' fabric, invariably point to a top-to-W/WNW sense of shear.

The Schlanders transect
The Schlanders transect is located about 20 km to the W of the Juval section (Fig. 2).This section of the VSZ is entirely within the Ötztal polymetamorphic basement, here chiefly consisting of granitoid orthogneiss and minor two-mica paragneiss.
The upper portion of the structural transect extends outside the VSZ, where orthogneiss still preserve their metamorphic regional foliation of Variscan age (Schmid and Haas, 1989;Hoinkes et al., 1999;Thöni, 1999) gently dipping to the E.
The cumulative shear strain distribution visible along this transect is symmetric, as was the case in the Juval section.Shear strain increases from the margins toward the core of the shear zone, with a decreasing grain size of both matrix and K-feldspar porphyroclasts.On the base of the matrix/clast ratio (Simpson and De Paor, 1993), the orthogneiss is protomylonitic.Only towards the core of the shear zone mylonitic bands occur, ranging in thickness from 10 to 50 centimetres.Ultramylonites, which are frequent along the Juval transect, here occur only as 2-10 centimetres thick bands, with a dark-grey colour and an intense grain-size reduction (Fig. 3f).The mylonitic foliation dips to NNW with a variable dip angle (Fig. 2b).Dip variations result from the occurrence of late stage S-facing folds with E-W trending fold axes that refold the mylonitic foliation.The lineation associated to top-to-W shearing is nearly sub-horizontal or gently dipping to W (Fig. 2b), identified in the field by elongate quartz aggregates and white micas.

The Eyrs transect
The Eyrs transect covers the W part of the exposed VSZ, close to the Schlinig Normal Fault and Glurns Fault (Fig. 1 and 2) that crosscut the shear zone.The exposed part of the VSZ is here entirely developed again within the Ötztal polymetamorphic basement, chiefly made of granitoid orthogneiss.Protomylonites and mylonites are preserved only along the upper margin of the shear zone, whereas the remaining part, from 1300 down to 900 m.a.s.l.(meters above sea level), consists almost entirely of light grey to whitish phyllonites (Fig. 3g).The phyllonites' protolith is hardly identifiable in the field, but the widespread occurrence (see section 3.2) of K-feldspar suggests that mylonites and ultramylonites developed on pre-existing granitoid orthogneisses.Phyllonites are also exposed on the right side of the Vinschgau Valley (Fig. 2), NW of Prad am Stilfserjoch.This part of the VSZ was probably the best known to past authors, and its fault rocks were previously known as the "Eyrs phyllites".The occurrence of dispersed carbonates (Fig. 3h) within the phyllonites led some authors to suppose the occurrence of Permian-Triassic carbonate sediments entrapped within the VSZ (Schmid and Haas, 1989).
Mylonitic foliation dips NNW with a variable dip angle due to the occurrence of S-facing folds as described in the Schlanders transect (Fig. 2b).The mylonitic lineation, here mainly identified by iso-oriented sericite crystal on the foliation planes, if far less evident than in other sectors of the VSZ, but a WNW-ESE trend (Fig. 2b) is generally recognizable.The SPO of chlorite, white mica and quartz defines the mylonitic foliation.Extremely fine-grained quartz bands, a few millimetres thick, commonly occur (Fig. 3h).The light colour of the phyllonites turns frequently into a brownish aspect (Fig. 3h).This is due to the occurrence of dispersed fine-grained carbonates (mainly calcite and Fedolomite, Fig. 3h) that likely originated from secondary fluids circulating along the shear zone.Secondary carbonates have been also found within orthogneiss-derived mylonites of the Juval transect.

Microstructural analyses and kinematic vorticity of flow
Field structural analyses served as a base for sampling of the different structural facies recognized along the studied VSZ transects.Samples were collected (Supplementary Table 1) all along the three transects at regular distances in order to obtain a complete representation of the whole exposed shear zone.Granitoid orthogneiss, the main protolith of the mylonites of the VSZ, does not represent the best opportunity for PT estimates.The scarce changes in the equilibrium mineral assemblage and the variation in the mineral chemistry of representative phases (white mica, biotite, K-feldspar and plagioclase) at greenschist and amphibolite facies conditions make difficult a precise estimate of pressure conditions and a qualitative, relative pressure determination can be estimated based on the Si content of white mica.Maximum temperature of mylonites could instead be determined by the stability of chlorite vs. biotite along the mylonitic foliation and the dominant quartz recrystallization mechanism (Stipp et al., 2002).
In the Juval transect poorly deformed orthogneiss and proto-and mylonitic orthogneiss consist of plagioclase, quartz, Kfeldspar, white mica, biotite and chlorite.Rutile, apatite, titanite and zircon occur as accessory phases.The regional foliation is made by the SPO of Bt1 + Wm1 (Zantedeschi, 1991;Bargossi et al., 2010).Rare relicts of pre-mylonitic Bt have been reported on the easternmost termination of the Partschinser orthogneiss body, outside the VSZ (Bargossi et al., 2010).The mylonitic foliation is defined by the SPO of Wm1 + Bt1, with white mica more abundant than biotite.Chlorite has been only rarely observed, mainly as an initial destabilization of biotite along rims of the Bt2 grains.Bt2 and Wm2 overprinting the main foliation are observed in some samples (Fig. 4b).In the poorly deformed orthogneiss, quartz is recrystallized mainly via bulging (BLG, Passchier & Trouw, 2005) recrystallization mechanism (Fig. 4a).Within proto-and mylonitic orthogneiss the dominant mechanism is subgrain rotation (SGR, Passchier and Trouw, 2005; Fig. 4b) recrystallization.A well-developed SCC' fabric (Fig. 5), together with various groups of mica fish (group 1 to 5 of Passchier and Trouw, 2005; group 5 in Fig. 4c) and asymmetric Kfeldspar porphyroclasts (Fig. 4d) point to a top-to-W shear sense, as already observed in the field.In the Schlanders transect, chlorite substitutes biotite along the mylonitic foliation, pointing to lower temperatures during shearing than in the Juval section.The syn-mylonitic foliation is defined here by the SPO of MsIII + Chl.The complete mineralogy of mylonites consists of plagioclase, quartz, K-feldspar, white mica, chlorite and rare relicts of biotite.Apatite, rutile and zircon are usually present as accessory phases.Mylonites along the Schlanders transect are often seen to grade into phyllonites, with a strong decrease in grain size and a progressive increase of white mica with respect to chlorite.
Within phyllonites, K-feldspar has been preserved only as relicts of 1-3 mm in size, with white mica becoming the major mineral phase.The occurrence of fine-grained white mica domains characterize most of the phyllonites, often affected by a weak crenulation (Fig. 4e) in response of E-W trending S-facing folds, as previously described.Together with the increase of white mica abundance, also carbonates increase.They occur as calcite and Fe-calcite crystals, reaching about 5% in volume of the whole rock.Quartz in mylonites display textures compatible with SGR recrystallization, whereas BLG is the only recrystallization mechanism observed in phyllonites.
In the Eyrs transect, the westernmost and, following Schmid and Haas (1989), the shallowest transect of the VSZ, phyllonites completely substitute mylonites.The whole of the shear zone consists of light-grey to whitish extremely finegrained phyllonites.Phyllosilicate domains reach up to 60% of the rock volume, with white mica as the major mineral phase.The abundance of calcite increases, reaching up to 10% in several outcrops.Calcite and Fe-calcite crystal show type 1 and type 2 deformation twinning (Ferrill et al., 2004;Fig. 4f).Quartz recrystallizes via BLG, no relicts of SGR and GBM textures have been observed in samples from the Eyrs transect.SCC' fabric, foliation fish, mica fish (group 3 and 4) and K-feldspar porphyroclasts occur as kinematic indicators, pointing to a top-to-W sense of shear.

315
To define the type of flow within the VSZ, kinematic vorticity analyses were performed on five samples (JVL-16, JVL-12, JVL-11, JVL-6, JVL-14) collected along the Juval transect oriented perpendicular to the shear zone boundaries.The vorticity analysis were carried out on Juval samples, as they are suitable for vorticity estimates.Unfortunately, Schlanders and Eyrs mylonites are unsuitable for the application of any of the methods of vorticity estimates due to the lack of fabrics which allow applying vorticity estimate methods (e.g.shear bands fabric, porphyroclasts or oblique foliation in quartz).
The analyses were performed on thin sections cut perpendicular to foliation and parallel to lineation (i.e. the XZ plane of the finite strain ellipsoid) using the C' shear band method (Kurz and Northrup, 2008), considering the mean value of the orientation of the synthetic shear bands following the interpretation of Gillam et al. (2013).Polar histograms used to derive the angle (2ν) between the apophyses A1 and A2 are reported in Figure 5.
The C' shear band method reveals Wm ranging from 0.64 up to 0.87, corresponding to a variation in simple shear component of 46 -68%, with the kinematic vorticity decreasing towards the core of the shear zone.

Mineral chemistry
Electron microprobe analyses (EMPA) were carried out using a JEOL 8200 Super Probe EMP at the Dipartimento di Scienze della Terra "A.Desio", Università degli Studi di Milano.Quantitative chemical analyses were performed on carbon-coated petrographic thin sections.Data acquisition was performed using an accelerating voltage of 15 kV, a beam current of 5 nA with a spot size of 1 µm.Natural silicates and oxides were used as standards.White mica and biotite analyses were recalculated as atoms per formula unit (apfu) based on 11 oxygens.Quantitative chemical analyses were performed on a non-mylonitic orthogneiss sample (JVL-15), on mylonitic orthogneiss samples (JVL-1, JVL-7, JVL-13, SCH-4) and on a phyllonite sample (ERY-11), with a total of about 100 points.Chemical analyses are reported in Figure 6 and Supplementary Table 2.Both first and second generation of micas were analysed: the microstructurally older white mica and biotite generation forming the main mylonitic foliation (hereafter Wm1 and Bt1) and the following, static, white mica and biotite generation overprinting the preceding one (hereafter Wm2 and Bt2).

Biotite
Analyses were performed on biotite from five samples, since it was absent from sample SCH-4.In the sample  the XMg ratio ranges between 0.54 and 0.56 (Fig. 6c-d), whereas XMg of the other samples shows a cluster at lower values (0.34-0.46).As in the case of white mica analyses, no significant chemical variations have been observed between the two biotite generations (Bt1 and Bt2).
Step heating experiments were conducted following the analytical protocols of Montemagni and Villa (2021).
This approach evaluates and integrates the information deriving from the age spectra, the correlation diagram (i.e.Ca/K vs. age) and the differential release plot (i.e.T vs. differential release).The obtained ages are therefore isochemical ages: the step used for the age calculation are those with lowest and homogeneous Ca/K ratios which correspond to 39 Ar highest release and % of 39 Ar.All 40 Ar/ 39 Ar data are reported in Supplementary Table 3.

The Juval transect
The age spectrum, the correlation diagram (Ca/K vs age) and the Differential Release Plots (DRP) for white mica display similar features (Fig. 7).The 39 Ar degassing peaks in the DRP (occurring at temperature ranging in the ca.1080 -1300 K interval) correspond to the flat part of the spectrum and the lowest Ca/K values, as imposed by white mica stoichiometry, which should be Ca-free.The heating steps showing high Ca/K and high Cl/K ratios (derived from the measured 37 Ar/ 39 Ar and 38 Ar/ 39 Ar), monitor the degassing of Ca-rich alteration phases and have been disregarded in the age calculation.At higher temperatures pertaining to white mica or biotite degassing, the Ca/K and Cl/K reach a minimum.

The Schlanders transect
The 39 Ar release patterns of the three white mica samples SCH-1, SCH-4 and SCH-5 (Fig. 8) are different from those of Juval.All three Schlanders samples show a bimodal 39 Ar peak pattern: one release around 940 K, typical of chlorite (see Montemagni and Villa, 2021), and one around 1050 -1150 K, typical of white mica.In SCH-4 and SCH-5 the white mica release peak corresponds to the lowest Ca/K ratios, i.e. the flat part of the spectra.In SCH-1 the white mica release peak is not very evident but the three steps between 1080 and 1200 K correspond to low and homogenous Ca/K ratios, coherent with the Ar release in SCH-4 and SCH-5.The age of mylonitic foliation has been constrained at 95.35 ± 1.50 Ma (SCH-1; Fig. 8a), 89.37 ± 0.24 Ma (SCH-4; Fig. 8d) and 97.86 ± 0.24 Ma (SCH-5; Fig. 8g).

The Eyrs transect
The phyllonites (ERY-3 and ERY-8) contain dispersed carbonates, evidence of massive fluid circulation (Fig. 3h).Moreover, due to the lower strain rate and/or lower temperature, the micas did not fully recrystallize during the Cretaceous faulting and give meaningless mixed ages with substantial Ar inheritance and white mica ages are geologically meaningless (Fig. 9 a-d).The age of mylonitic foliation has been constrained to be 92.58 ± 1.56 Ma (ERY-11; Fig. 9g).

Kinematic and chronological evolution of the VSZ
Although the Vinschgau Shear Zone (VSZ) is one of the largest thrust-sense shear zone exposed in the Alps, no age constraints existed on the shearing activity of this huge intra-Austroalpine thrust, with its Late Cretaceous age only inferred on the base of indirect evidence (Schmid and Haas, 1989) and a single Rb-Sr whole rock age of a deformed pegmatite (Thöni, 1986).Our 40 Ar/ 39 Ar data are the first attempt to constrain the time interval of activity of the VSZ, combining geochronological results obtained across the shear zone and along its dip direction.
The evolution of shear zones has been deeply investigated in terms of spatial variation especially concerning their length and thickness (Hull, 1988;Mitra, 1992;Means, 1995;Vitale andMazzoli, 2008, 2010;Fossen, 2010;Fossen and Cavalcante, 2017).This effort was aimed at defining the parameters that may influence the evolution of one type of shear zone with respect to another one.If the growth in length of a shear zone is essentially due to linkage of different branches forming a composite system of shear zones (Fossen and Cavalcante, 2017), the growth in thickness may be influenced by different mechanisms.Four ideal models of shear zone evolution have been proposed and discriminated based on shear strain gradient, kinematic vorticity and plane or triaxial strain (Vitale and Mazzoli, 2008;Fossen and Cavalcante, 2017).
Processes of strain hardening or strain softening promote the thickening and the thinning of the shear zone, respectively type-1 or type-2 models.In the type-1 model, the deformation concentrates in the margins of the shear zone, leaving inactive the inner portion.On the contrary, in the type-2 model the deformation shifts and concentrates in the inner portion of the shear zone as strain accumulates, leaving the margins inactive.In addition, type-3 model is related to a strain weakening process, even if its active thickness remains constant with time.Type-4 model expands in thickness but, unlike type-1, all the thickness remains active through time.According to the several models proposed for shear zone evolution (Fossen and Cavalcante, 2017 with references), the VSZ followed a type-2 evolutionary model, with increasing cumulative shear strain from margins to the core of the shear zone (Fig. 10).This pattern of shear strain distribution is demonstrated for the VSZ by the occurrence of ultramylonites at the core of the Juval transect (Fig. 10), whereas protomylonites derived from the Partschinser orthogneiss are preserved only at the margins.The kinematic vorticity of flow follows the same symmetric distribution, with Wm that increases from the rims to the core (ca.0.64 at margins and ca.0.87 at the core, Fig. 10).The patterns displayed by the shear strain points to a strain-softening behavior of the shear zone (e.g.Vitale and Mazzoli, 2008).At the microscale, the processes that may cause strain softening are: (i) recrystallization during shearing, especially when associated with subgrain rotation recrystallization mechanism (Passchier and Trouw, 2005), which leads to formation of new grains with lower dislocation density that results in a deformation at lower differential stress; (ii) shear bands fabric formation (Fig. 5), as shear bands imply local grain-size reduction, a mechanism which is invoked in low-to-medium mylonitization to promote strain weakening (Fossen and Cavalcante, 2017 and references therein).Lattice preferred orientation (Fig. 4) may also weaken the rheology as recrystallized or newly formed minerals, mainly micas and quartz, have intracrystalline slip planes aligned in the shear direction, resulting in favorable motion of dislocations with continuous dynamic recrystallization also at low differential stress (Passchier and Trouw, 2005 with references).The VSZ deepens from W to E, as suggested by previous workers (Schmid and Haas, 1989) and confirmed by the present data, with white mica-chlorite phyllonites overprinting white mica-biotite mylonites in the western part of the shear zone.
Broadly, the 40 Ar/ 39 Ar ages rejuvenate from W to E, opposite to the transport direction and consequent exhumation of the Austroalpine units in the hanging wall.This age pattern points for younger ages of shearing in the E (i.e.Juval area) where deeper portions were still being deformed (Fig. 11), while in the W the shear zone was already at shallow crustal depths.
Beyond the deformational path of the VSZ, which clearly follows a strain softening type-2 shear zone evolution model, the novelty of our work is the integration of microstructural and kinematic analyses with age profiling of the shear zone along its transport direction, along depth, and across strike (Fig. 11).The obtained age pattern allows the reconstruction of a time-resolved evolution of the shear zone during its progressive activity and exhumation.
The 40 Ar/ 39 Ar ages recorded by micas in the Schlanders and Juval transects reveal a clear younging trend from the margin to the inner zone of the shear zone (Figs. 7,8 and 11).This trend of younging mica ages is paralleled by increasing cumulative shear strain and decreasing simple shear component (Fig. 11).The correlation between ages and deformation suggests a progressive migration of deformation towards the inner portion of the VSZ, with the margin becoming inactive (as testified by older mylonite ages ≥ 97 Ma), while deformation concentrates in the middle of the shear zone where micas show younger ages down to 80 Ma.

The VSZ in an evolving orogenic wedge
The evolution of the Eo-Alpine orogenic wedge of the Eastern Alps is generally related to the closure of the Meliata Ocean, located in an intra-Austroalpine position (e.g.Schmid et al., 2004), or separating the former Austroalpine and Southalpine domain (e.g.Neubauer et al., 2000).Other interpretations consider instead the possibility that the entire Austroalpine orogenic wedge formed in the Late Cretaceous in a pre-collisional setting (Zanchetta et al., 2012(Zanchetta et al., , 2015)).
Irrespective of the geodynamic scenario of the Eo-Alpine orogen in the Eastern Alps, the VSZ acted as a crustal-scale shear zone promoting nappe stacking and exhumation within an orogenic wedge chiefly made of continent-derived tectonic units.The ages of shearing along the VSZ indicate that the shear zone was already active at 97 Ma (Fig. 7, Fig. 8 and Fig. 11), at least 7-8 Ma before the pressure peak recorded by the Texel eclogites and the amphibolitic peak in the Schneeberg unit.The ages of the VSZ in the Schlanders transects overlap with published/available ages related to the peak of Alpine metamorphism in the Ötztal basement, suggesting that thrusting within the Austroalpine domain started where units in the hanging wall of the VSZ had already reached (Ötztal) or were close to the metamorphic peak (Texel and Schneeberg units).These ages overlap between shearing and metamorphic peak is explained by a rapid exhumation of these HP rocks via thrusting in the Eo-alpine orogenic wedge.Handy et al. ( 2010) argued that the Eo-alpine orogen, in the time span 118-84 Ma, was subjected to intracontinental subduction and basement nappe stacking, whose evidence is the E-W trending belt of Late Cretaceous, HP rocks of the Koralpe-Wölz nappe complex (Schmid et al., 2004;Thöni et al., 2008), to which the Texel and Schneeberg units belong.The exhumation of these HP rocks was both westward and northward (Handy et al., 2010).The W/SW-directed Late Cretaceous thrusting (Eisbacher and Brandner, 1996;Ratschbacher, 1986;Schmid and Haas, 1989;Viola et al., 2003;Handy et al., 2010) and consequent nappe stacking under pressure-dominated, amphibolite to greenschist facies conditions, is unusual, if compared to major N/NW-directed direction of transport for other sector of Alps.This scenario has been explained through a complex microplate configuration at 94 Ma, which necessarily invokes the eastward faster accommodation of the Iberia microplate with respect to the Adria microplate, also moving eastward with respect to Europa, but at lower rates (Handy et al., 2010).The age of the pressure metamorphic peak within HP units has been reported between 95 and 89 Ma (Thöni, 2002;Habler et al., 2006;Miller et al., 2005;Thöni et al., 2008;Janák et al., 2009;Zanchetta et al., 2013), with partially overlapping ages related to their rapid exhumation (e.g.Fügenschuh et al., 1997;Sölva et al., 2005).
As the Texel and the Ötztal units are now in tectonic contact at the eastern termination of the VSZ, at least 20 km of vertical exhumation of the Texel unit should have been accommodated along the VSZ, considering the difference in peak metamorphic pressure recorded by the two units (Fig. 11a): 1.2-1.4GPa for the Texel unit (Habler et al., 2006) and 0.5-0.6GPa for the Ötztal basement (Purtscheller and Rammlmair, 1982).Considering a lithostatic pressure gradient of 0.03 GPa/km and a consequent difference in terms of pressure of 0.6 GPa between the Ötztal and the Texel unit, such vertical displacement corresponds to a minimum of about 40 km along the shear zone, taking into account a dip of about 30°, which is typical of thrust-sense shear zone active through crustal depths controlling the exhumation of high-grade units in their hanging wall (e.g.Jamieson et al., 2004).The amount of E-W shortening within the Austroalpine basement nappes has been estimated to be ≥100-150 km (Manatschal and Bernoulli, 1999;Schmid et al., 2020).
The VSZ yields ages in the range of 80 Ma (the youngest age at the inner portion of Juval transect) and 97 Ma (the oldest age in the Schlander area) almost coeval with the peak metamorphic age in the Ötztal and Texel units at ca. 85-90 Ma (Zanchetta et al., 2013, Fig. 11).Hence, we argue that the VSZ has been active at least for 17 Ma, promoting the rapid exhumation of the Texel eclogite in the Late Cretaceous.Syn-shearing exhumation of the Texel and Schneeberg units continued at least up to 76 Ma, as testified by the age of greenschist facies mylonites along shear zones within these two units (Sölva et al., 2005).This scenario was depicted also by Handy et al. (2010), who suggested a rapid exhumation of the Koralpe-Wölz units during the Cenomanian -Santonian (ca.94-84 Ma) when the Gosau Group (syn-to post-orogenic clastic sediments sometimes deposited in intra-orogenic extensional basins) sealed thrusts in the Austroalpine basement and in the Northern Calcareous Alps.Exhumation models for crystalline rocks have been extensively proposed, modeled and tested for the Himalayan orogen, where the exhumation of the metamorphic core of the belt was matter of debate in the literature (e.g.Montomoli et al., 2015;Carosi et al., 2018;Montemagni, 2020).Regardless the specific model, the scientific community agrees that exhumation in the Himalayas has been driven by two opposite shear zone bounding the crystalline core: a normal-sense at its top and a thrust-sense shear zone at its bottom, respectively (e.g.Godin et al., 2006;Montomoli et al., 2013 for reviews).Based on structural and geochronological data, a similar model was also proposed for the type locality eclogites in the Saualpe region (Wiesinger et al., 2006).A recent study (Schulz and Krause, 2021) documented the younger age in amphibolite-grade footwall units underlying the eclogite-bearing unit.
In this perspective, we argue that the VSZ played a key role in the exhumation of HP rocks in the Eastern Alps, and we can speculate that the units containing HP rocks have been exhumed by a (non-necessarily coeval) shearing of a thrustsense shear zone at the base and a normal-sense shear zone at the top of the orogenic wedge, i.e. above the Ötztal-Stubai complex.Considering the jump in the metamorphic grade and age of metamorphism between the underlying Eo-Alpine Ötztal-Stubai complex (garnet amphibolites facies) and the quartz-phyllites (ca.350 °C of peak temperature, Lünsdorf et al., 2012) with a pre-Permian metamorphic age (Rockenschaub et al., 2003) of the Steinach Nappe, the shear zone at the base of this nappe could be a valuable candidate for the normal-sense shear zone that together with the VSZ controlled the exhumation of the Ötztal-Texel-Schneeberg high-pressure complex.
Beside the geodynamic interpretation, the presented data indicate that the VSZ had a long-lasting evolution of at least 17 Myrs.The minimum accommodated displacement of ca.40 km implies a displacement rate of 2-2.5 mm/yr that is significantly higher than values reported in Vitale and Mazzoli (2008) that are of 0.10 mm/yr for thinning shear zone (type-2).The accommodated displacement of the VSZ is coherent with slip rate values of ca. 10 mm/yr reported by Stübner et al. (2013) for an intrabasement normal sense shear zone in the Pamir plateau.The exhumation continued rapidly as suggested by thermochronological data in the eastern Ötztal-Stubai complex unit where cooling below 60 °C at 60 Ma has been reported (Fügenschuh et al., 1997).

Conclusions
The VSZ is one of the prominent intra-basement thrust-sense shear zone developed in the Alps, promoting the exhumation of HP rocks within the Eo-Alpine orogenic wedge.
Our approach fully constrains its kinematic and temporal evolution: (i) Cumulative shear strain and kinematic vorticity values reveal an evolution compatible with a type-2 thinning shear zone.
(ii) 40 Ar/ 39 Ar geochronology defines the shearing activity to be comprised between 97 and 80 Ma, resulting in a long-lasting deformation history. (iii) The novelty of our work is the combination of microstructural and kinematic analyses with age profiling of the shear zone both along its transport direction and across strike.
Author contribution.SZ, AZ and CM designed the study, CM and MR carried it out.The paper was prepared by CM and SZ and revised by AZwith the contribution of all co-authors.All authors participated in fieldwork and in the various scientific discussions.
Competing interests.None of the authors has any competing interests.

Figure 3 :
Figure 3: Field photographs of Juval, Schlanders and Eyrs outcrops.(a) Proto-mylonitic Partschinser Orthogneiss with a mylonite band, recognizable from the darker colour, reduced grain size and rare presence of K-feldspar porphyroclasts (SW

Figure 4 :
Figure 4: Representative photomicrographs from the VSZ, crossed polars.(a) Quartz recrystallized via bulging recrystallization mechanism (red arrows) in poorly deformed Partschinser orthogneiss.The white arrow points at Bt2; (b) Quartz recrystallized via subgrain rotation recrystallization mechanism (red arrows) and static white mica (Wm2, white arrow) growing on the main foliation (Wm1) at high angle; close up on (c) group 5 mica fish according to the classification of Passchier and Trouw (2005) and (d) asymmetric K-feldspar porphyroclasts.(e) A well-developed crenulation cleavage in phyllonite, and (f) deformation twinning in calcite.
Figure 5: Vorticity estimates through SC' (a-e) and relative SC' fabric (f-l).Polar histograms used to derive the angle θ and to calculate kinematic vorticity with the SC′ method (Kurz and Northrup, 2008) for samples JVL-16 (a),

Figure 8 :
Figure 8: 40 Ar/ 39 Ar age spectra, Ca/K vs. age diagrams and Differential Release Plots for Schlanders samples SCH-1 (a-c), SCH-4 (d-f) and SCH-5 (g-i).The dotted circles in the T vs. differential release plots (c, f, i) indicate the degassing steps selected for the age calculation.

Figure 9 :
Figure 9: 40 Ar/ 39 Ar age spectra, Ca/K vs. age diagrams and Differential Release Plots for Eyrs samples ERY-3 (a-c), ERY-8 (d-f) and ERY-11 (g-i).The dotted circles in the T vs. differential release plots (c, f, i) indicate the degassing steps selected for the age calculation. 480

Figure 10 :
Figure 10: schematic cross section of Juval transect

Figure 11 :
Figure 11: Evolution of the Vinschgau Shear Zone in the orogenic Eo-alpine wedge during the Late Cretaceous.Activation of the VSZ (a) in the time span 97-90 Ma affecting the Ötzal unit, (b) in 87-85 Ma the VSZ affected also the Texel unit and (c) during the late stage of shearing exhumed the Texel and Schneeberg units to Ötzal PT conditions.In (a) the PT conditions for Ötzal, Texel and Schneeberg units are reported.The dashed lines represent the thickness and length of the shear zone through time.The evolution of the VSZ in the studied transects in term of ages, cumulative shear strain and kinematic vorticity is also shown.