The Application of Cretaceous Clay Minerals of Mjez El Beb (North-Western Tunisia) in Ceramic Industry

The Cretaceous clays of north-western Tunisia have been studied for their use in the traditional ceramic industry (bricks, tiles and pottery). Mineralogical, chemical, thermal analyses, technological proprieties and grain size distribution were carried out on clay samples collected from Jebel El Moura (BM section) and kef Lasfar-Oued El Jebs (MK section) in the locality of Mjez el Beb. The results showed that these clay minerals are represented mainly by kaolinite associated with illite and smectite. Quartz, calcite, feldspars and hematite were also detected as accessory minerals in the whole rock. The amount silica is convenient for the manufacture of ceramic products. So the prepared mixtures were made without admixture of any variety of silicate. The technology tests revealed that the modelled products had small shrinkage during drying and firing, and a high bending strength. For this reason, the clay mixtures were made without admixture of quartz or any other component. As a result, Mjez el Beb clays have high qualities necessary for the manufacture of tiles and ceramic bricks. Figure 1: Generalized geological map of the Jebel Mourra area (Extracted from the geological map of Mejez El Bab No. 27 at 1/50,000 scale). Journal of Earth Science & Climatic Change J o u r n a l o f E art hS cience &Cmatic C h a n g e Research Article ISSN: 2157-7617 Citation: Faten HBZ, Dalel S, Najet SS, Mohsen H (2015) The Application of Cretaceous Clay Minerals of Mjez El Beb (North-Western Tunisia) in Ceramic Industry. J Earth Sci Clim Change. 6: 308. doi:10.4172/2157-7617.1000308

Chemical compositions of powdered and pressed clays samples were determined by subjecting them to an electron microprobe equipped with an X-ray dispersive spectrometer (Bruker S4 Pioneer). Samples preparation was realized according to the conventional techniques proposed by Meseguer et al. [13]. The particle-size distribution was obtained by laser granulometry using a MALVERN instrument. Thermal Gravimetric Analysis (TGA) and Differential Thermal Analysis (DTA) were performed with a SETRAM type 124 TG/DTA instrument using aluminium as inert reference material. Temperature was increased from room temperature to 1100°C at the regular increment of 10°C/min in air atmosphere. The expansion and firing shrinkage were measured using the dilatometer Adamel Lhomargy Type DM 15. The powders were heated from room temperature above 1200°C with 10°C/min. The liquid limit (LL), plastic limit (PL) and plastic index (IP), (IP=LL−PL) were determined for each sample in accordance with the French Standard NF P 94-051. The Bigot curve drawn with an Adamel barelattograph is used to characterize the drying process. The ceramic properties, namely moisture content dry shrinkage and dry bending strength were performed on fired products. The linear firing shrinkage, the bending strength and the water absorption for ceramic faience, were obtained from modelling numerous flat pieces (with normative dimensions: 100 mm×50 mm×10 mm). After compacting of 60 g moistened materials (7wt.% moisture content) under 250 bars, the prepared pieces were oven-dried at 105°C until constant weight then fired at 950°C and at 1000°C during 1h. The water absorption for ceramic faience was determined by immersing a specimen of brick in water boiling until constant mass. The water absorption by dipping (Abs) is expressed as a percentage of the dry weight and is calculated by the following relationship: Abs = 100 x (mh -ms)/ms. mh, constant wet mass of the specimen after immersion; ms, constant dry mass of the specimen wiped with an absorbing any water surface rag. The bending strength was measured with a three point flexural method according to the norm [14]. The linear firing shrinkage, the bending strength and the water absorption were carried out for ceramic bricks pieces heated in dates to the Early Cretaceous witnessed by the following fauna species: Lenticulina Ouacheniss, Epistomina (Brotzena) djaffaensis [10,11], Globuligerina hoterivica [10][11][12], Hedbergella tuschepsensis, Leupoldina pustulans, Biglobigernella barri. The lithological series of Kef Lasfar-Oued Jebs (MK section) includes five clay combs varying from beige, greenish to grey in colour, and with a thickness ranging from 150 to 480 m ( Figure 2b). Faunistic species namely: Thalmanninella appenninca ballernaensis were found in these tender levels, which let us to attribute these series from Albian to Senonian age. These argillaceous combs contain metre-scale alternations of beige pelagic limestone units.

Materials and Methods
More than 50 Kg of raw materials were collected from this Mjez el Beb clay deposits. Eighteen samples were taken from kef Lasfar-Oued El Jebs section and fourteen specimens were sampled from jebel El Mourra section. One representative mixture for the whole lower Cretaceous clays (BM section) and another one (MK section) of the Upper Cretaceous clay have been considered to define the potential use of these raw materials in the ceramic industry. Therefore, BM and MK clays were used in the ceramic earthen ware, while BM and MK samples were mixed to make up the bricks. The bulk material was initially dried at 60°C for 24 h, and then was gently crushed. Mineralogical analysis was carried out by X-ray diffraction (XRD) using a PANalytical X'Pert Pro diffractometer, operating at 40 kV and 40 mA; and equipped with a Cu Kα radiation (1.5418 Å). The relative abundances of non-clay species was estimated using the heights ratio of the main reflections whereas, clay minerals proportions were determined by measuring the superficies of the "001" reflections. Infrared spectra were obtained using a JASCO FT-IR-420 spectrophotometer. The pressed-discs, we prepared using 1 mg of the selected samples which was diluted with 200 mg KBr. Discs were heated on the oven overnight at 150°C to minimize the water absorption on KBr and the clay powder. Transmittance spectra were recorded in the MIR region 4000 to 400 cm -1 . The cation exchange capacity was measured with standard acetate ammonium procedure.

Results and Interpretations
Mineralogy characterization Particle size: The grading curves of (BM) and (MK) mixtures have a bimodal distribution: a dominant particle-size population having diameters ranging between approximately 30 μm and 25 μm; a second population with diameters lower than 4 μm ( Table 1 and Figure 3). The D50 and D90 particle-size represent the median diameters which range between 8.97 µm and 39.47 µm for BM, and 15.77 µm and 48.02 µm for MK. This later is related to the presence of the kaolinite. The fraction below 2 μm corresponds to 40.38% and 38.7% of the whole sample for MK and BM respectively. These values are suitable for the ceramic manufacture.

X-ray Diffraction:
The results summarized in Table 2 show the predominance of kaolinite (48% for BM and 41% for MK), and smectite (46% for BM and 38% for MK) and low to moderate content of illite (20% for MK and 6% for BM). The mineralogical analysis of the non-clay minerals indicates the presence of quartz (51% in the MK samples and 35% in the BM samples), calcite and the feldspars which the content not exceeds the 6%, and, the hematite which is only detected in the MK sample (2%).

Infrared spectroscopy:
The IR absorption curves of both clay samples BM and MK are roughly similar, as seen in (Figures 4 and 5). It shows the presence of OH-stretching bands at the vicinity of 3600-3700 cm -1 domain and the Si-O stretching bands near 1000 cm -1 [15][16][17][18][19]. Bands at 3698 cm -1 , and 3620 cm -1 are attributed to the structural OH respectively of kaolinite [15,16,20,21]. The broad OH-stretching band ranging from 3623 and 3926 cm -1 coupled with relatively weak absorption bands near 825 and 750 cm -1 are characteristic of illite. The latter bands arise from Al-Mg-OH deformation. The shoulder at 913 cm -1 is attributed to the Al-OH-Al bending vibration and characterise the dioctahedral phyllosilicates [22]. The peak at 885 cm -1 is assigned to the Fe-Al-OH vibration that identified usually in the illite and smectitic minerals [23] resulting from Fe 3+ for Al substitution in the octahedral sheet. The shoulder arising from the Si-O-Al vibration is showed at 536 cm -1 . The presence of water is verified by the band large at 3400 cm -1 . Peaks at 1727, 1402, 875 and 712 cm -1 correspond to the presence of calcite. The quartz was identified in the two samples by the bands at

Chemical characterization
Major elements and trace elements analyses: Table 3 (Table 4).

Cation exchange capacity and specific surface:
The values of cation exchange capacity (CEC) of clays BM and MK are 52 méq/100 g for BM and 47 méq/100 g for MK respectively. The low values are due to the abundance of kaolinite and to the presence of non-clay minerals. The specific surface area (BET) of the studied clays is low: 77.77 m 2 /g for BM and 59.81 m 2 /g for MK. These values confirm that the studied clays are a mixture (semi-kaolin-semi-illito-smectic).

Thermal behaviours
Thermal Analysis: The DTA-TGA curves of the prepared mixtures ( Figures 6 and 7) show: (i) a significant endothermic peak at around 100°C, resulting from the removal of adsorbed and interlayer water of the clay minerals [24]. It represents a 2.209% (for BM) and 2.741% (for MK), weight loss of water moisture and hygroscopic water; (ii) an endothermic peak around 300°C is assigned to the combustion of organic material; (iii) an endothermic peak at 540°C attributed to the dehydroxylation of kaolinite; (iv) an endothermic peaks between 606°C and 726°C with a weight loss of 0.719% corresponds to the dehydroxylation of smectite ; (v) an exothermic peak at around 950°C corresponds to the reorganization of the structure of metakaolin in Mullite.

Dilatometry:
The Thermo-dilatometric curve of MK mixture shows a slight dilation at 88.1°C followed by a low shrinkage (4.01%) observed at 144.8°C (Figure 8). Beyond this temperature, the curve becomes linear, which corresponds to an important dilatation. The firing temperature is around 1165°C with a total shrinkage of 4.53%. For BM mixture, the first dilatation is observed at 88°C followed by 2.82% of shrinkage occurred at 175.7°C and, confirming the departure of residual water (Figure 9). The hook observed between 500 and 700°C is linked to the presence of illite. The inflexion point at 707°C is originated from the quartz conversion. The final firing temperature corresponding to 4.70% of shrinkage occurred at 1164°C.

Plasticity:
The results of the plasticity tests are given by the Atterberg limits (Table 5 and Figure 10). The values of the LL are about 49.74% for BM and 51.11% for MK. The PL values are 33.33% and 34.50% for BM and MK respectively, which are in agreement with the range of plasticity used for ceramic product manufacture defined in the literature (30-60%). The plasticity index PI was calculated based on the arithmetic difference of the plasticity limit and liquid limit. Both clays present relatively medium values of plasticity (7%< PI >15%).

Bigot Curves:
The Bigot curves of the clay mixtures (BM and MK) after drying shows that the proportions of moisture water, interlayer water and colloidal water are 24.66%, 17.61% and 7.05% respectively ( Figure 11). The total shrinkage after drying is 5.51%. This value results from the substantial amount of sand in the clay samples.

Industrial Tests
Concerning, the tiles manufacture, the results of technological tests in semi-industrial scales show a small drying shrinkage at around 1% for BM and 0.7 for MK (Table 6). Furthermore, the firing shrinkage is less than 2% for the two mixtures and depends to the firing temperature. The values of water absorption are greater than 10% for both mixtures, which is conforms to the French standard N.F.EN. 15 [25] (Table  7). Regarding the resistance to the inflection, which is the parameter defining the class of ceramic faience products according to the French standard N.F. EN 100 [26], we recorded at 1000°C 11.62 N/mm 2 for MK mixture and 8.56 N/mm 2 for BM mixture. Therefore, the results      (Table 7).

Discussion
In order to assess the potentiality of Mjej el Beb clays in the ceramic industry, their mineralogy, chemistry composition, thermal behaviours and technological properties were determined. The results showed the predominance of the fine fraction composed basically with kaolinite, smectite and illite which are confirmed by the infrared spectroscopy. The confectioned items made of these clays have a red to dark colour arising from the high concentration of iron oxides content. This later, lead to a good fluxing properties and affect the mechanical strength of the ceramic products [27,28]. In addition, Fe 2 O 3 with alkaline elements favour the formation of vitreous phase and lead to the densification of these fine materials and therefore could affect their fluxing and the firing temperatures [29]. The weight loss on ignition occurring after sintering lead to the development of the porosity, and has an effect on the resistance to the inflection during the thermally treatment. Beside, this clays are enriched in some trace elements such as Zn Sr, Cr, Th, Cs, Nb, V, Zr and Y. Zn Sr, Cr, Th which could be mobilized by the mineralizing fluids of the Kef Lasfer mine. These elements have an important role in the improvement of the mechanical resistance of the ceramic products. Previous studies showed that the Cs, Nb and V enhance the melting point as well as the mechanical strength. Whereas, the Zr present as oxide (zirconia), or silicate (zircon) could improve the ceramic materials quality. Biside, Y could be used as a sintering additive [30]. During the thermal treatment, various reactions occur principally dehydration, dehydroxylation and structural reorganization and neoformation phases.

Structural transformations
During firing treatment, clay minerals are transformed into new minerals dehydrated. At 850°C, kaolinite is transformed into amorphous phase: metakaolinite (Al 2 Si 2 O 7 ) by the removal of the hydroxyl groups of the silicate lattice according to the following reaction: Al 2 Si 2 O 5 (OH) 4 → Al 2 Si 2 O 7 + 2H 2 O.
Between 850°C and 950°C, the CaCO 3 decomposes to CaO accompanied by disengagement of CO 2 outside the structure of fired bodies; this phenomenon creates a porous structure [29]. The CaO reacts with the metakaolinite at increasing temperature, leading to the  Table 7: Technological properties of the prepared ceramic bricks.  formation of the gehlenite which evolves to anorthite [31,32]  In general, we cannot exclude the formation of anorthite from the metakaolinite according to the reaction:   Above 900°C, a segregated spinel-type phase (γ-Al 2 O 3 ) recrystallizes [33], and evolves to mullite when the temperature increase above1000°C. The industrial tests carried out on the fired products reveal a low withdrawal, which is linked to the removal of the water. This latter is responsible of the tightening of the particles and the decrease of the liquid surface and capillarity tension. Concerning the mechanical resistance to the inflection, the medium value observed is related to the medium plasticity of the Cretaceous clays. Previous studies showed that the flexural strength could be linked to the presence of silica minerals [34]. It was also shown, that the mechanical resistance to the inflexion increases with vitrification. Indeed, when vitrification is completed, the pores join together to from large pores causing the macroscopic deformation on the ceramic materials [35][36][37][38][39][40].

Conclusion
In conclusion, the mineralogical and geochemical characterizations of the Cretaceous clay of Mjez El Beb revealed a good quality of raw material composed mainly of kaolinite and illite and enriched with Al 2 O 3 , and SiO 2 . These oxides have a decisive influence on the refractoriness and strength of the final product. Besides that, the Fe 2 O 3 , alkali and alkaline earth elements, present in the clays, lead to the rapid vitrification and fusion during firing. In addition, the high proportions of finer particles favour the vitrification due to the good compaction during moulding, which positively influences on the resistance of fired materials. During firing, several mineralogical transformations of the  minerals initially present in clay powder occur [41][42][43]. The new phases represented mainly by metakaolinite, gehlenite, anorthite, spinel-type phase (γ-Al 2 O 3 ) and mullite enhance the process of sintering of ceramic matrix. Therefore, the mineralogical and chemical compositions allowed us to choose the suitable semi industrial manufacturing applications [44][45][46]. For this, we recommend to use BM and MK clay-mixture in the ceramic earthen ware, and to mix BM and MK for the bricks fabrication. The quality of the ceramic product could be verified by examining the firing shrinkage, the firing line narrowing, the ignition loss, the porosity, the plasticity and the flexural strength.