The evolution of the čanište epidote-bearing pegmatite , Republic of Macedonia : evidence from mineralogical and geochemical features

1 Institute of Mineralogy and Petrology, Department of Geology, Faculty of Science, University of Zagreb, Horvatovac 95, HR-10000 Zagreb, Croatia; (sabina.strmic@inet.hr) 2 Faculty of Mining, Geology and Polytechnic, Goce Delčev University, Krste Misirkov bb, P.O. Box 201, MK-2000 Štip, Republic of Macedonia 3 Research Division, Canadian Museum of Nature, P.O. Box 3443, Station D, Ottawa, Ontario K1P 6P4, Canada 4 Department of Applied Geosciences and Geophysics, Mineralogy and Petrology Group, University of Leoben, Peter-Tunner-Strasse 5, A-8700 Leoben, Austria


INTrODUCTION
The Čanište pegmatite is situated approximately 150 km south of Skopje, Republic Macedonia, on the western slopes of the Selečka Mts. which represent a part of the Eastern Pelagonian tectono-stratigraphic unit of the Dinaride-Hellenides (Fig. 1).The Pelagonian Massif exposes Precambrian crystalline basement made of ortho-and paragneisses, micaschists and amphibolites and comprises numerous pegmatites, which differ according to their size, mineralogical fea- tures, internal structures and the degree of fractionation (e.g.IVANOV et al., 1966;ZEBEC & RADANOVIĆ-GUŽVICA, 1992;JOVANOVSKI et al., 2003).
This pegmatite attracts attention due its peculiar Ca-enriched mineral assemblage with the unique occurrence of up to 2 metre long epidote crystals (BERMANEC et al., 2001).Epidote is not a common pegmatitic mineral and it has been recorded only within several epidote-bearing pegmatites elsewhere (e.g.FRANZ & SMELIK, 1995;JANECZEK, 2007, LIEBSCHER et al., 2007;COTA et al., 2010, SWAN-SON & VEAL, 2010).Furthermore, the Čanište pegmatite exhibits a zonal mineral distribution that allows a detailed investigation of fluid inclusions within minerals from the different stages of the pegmatite crystallization.Although the zonal pegmatites are common, and fluid inclusions rep-resent relicts of fluids involved in the crystallization processes, only a few publications present the fluid inclusion data systematically collected across the distinct pegmatite zones (e.g.LONDON, 1986LONDON, , 1990;;THOMAS & SPOONER, 1988, 1992;FUERTES-FUENTE et al. 2000;BEURLEN et al., 2001;SIRBESCU et al., 2008).
The pegmatites are related to the late stage of magmatic crystallization.While the importance of volatiles and incompatible elements in enriched melts is generally accepted, there are still numerous open questions about the mechanism of their deposition.The majority of authors consider that water-saturated magmas are responsible for the principal mineralogical characteristics of pegmatites (e.g.JAHNS & BURNHAM, 1969;BURNHAM & NEKVASIL, 1986;NA-BELEK et al., 2010).In contrast, LONDON et al. (1989)   and LONDON (1990LONDON ( , 2008) ) explain the formation of pegmatites by disequilibrium crystallization from water unsaturated magmas, emphasizing the role of fluxing elements such as B, F, and P.
The aim of this study is to interpret the evolution of meltfluid in the late magmatic system responsible for deposition of the Čanište epidote-bearing pegmatite.A fluid inclusion study complemented by calculated thermodynamic equilibria of the mineral paragenesis shed light on the P-T-X conditions when the pegmatite formed.

GEOLOGICAL SETTING
The Pelagonian tectono-stratigraphic unit is a ca.420 km long and 60 km broad in the NNW-SSE striking part of the central Hellenides (Fig. 1), exposing Precambrian crystalline basement made of ortho-and paragneisses, micaschists and amphibolites.Granitoids intruded the Pelagonian basement during: I) Upper Carboniferous and II) Late Permian -Early Triassic magmatic events (MOST, 2003).According to the QAP classification, Pelagonian granitoids range from granite to quartz-diorite, but are mainly granodioritic in composition (DUMURDZANOV, 1985;MOST, 2003).The Upper Carboniferous granodiorite (299 ± 1 Ma, U/Pb zircon age dating; MOST, 2003) underwent compressional deformation and developed a greenschist to amphibolite-grade metamorphic overprint.A Late Permian -Early Triassic granodiorite (~245 ± 1 Ma, U/Pb zircon age dating; MOST, 2003) is represented by massive intrusive bodies within the Eastern Pelagonian zone, including the Selečka Mts.The relicts of concomitant metamorphism are not preserved.A sedimentary sequence, comprising carbonate and clastic rocks, was deposited during Triassic and Jurassic times.The geological structure of the Pelagonian zone is mostly a consequence of polyphase tectonometamorphic events during convergence of the Apulian and European plates between the Upper Jurassic and Upper Tertiary times (MOST, 2003).
The Čanište pegmatite is one of numerous pegmatite occurrences within the Eastern Pelagonian zone.The pegmatites vary in size from a few decimetres wide and tens of metres long to larger bodies tens of metres wide by hundreds of metres long.They differ according to the mineralogical features, the internal structures and the fractionation degree as well.Beside epidote-bearing ones (Čanište and Dunje localities), the most interesting are those enriched in uranium and thorium mineralization (Alinci and Crni Kamen localities; e.g.IVANOV et al., 1966;RADUSINOVIĆ & MARK OV, 1971;BERMANEC et al., 1988BERMANEC et al., , 1992;;ZEBEC & RADA-NOVIĆ-GUŽVICA, 1992).
The Čanište lens-shaped, up to 10 m wide pegmatite body, cuts Precambrian gneisses (DUMURDZANOV, 1985;MOST, 2003).The well developed internal zonation of the pegmatite is illustrated by an idealized paragenetic sequence (Fig. 2).Equigranular subhedral amazonite microcline is the main constituent of the wall zone (Fig. 3a), whereas quartz and biotite are accessory minerals.The first intermediate zone consists of giant epidote crystals (up to 2 m long; Fig. 3b), microcline, haematite, muscovite, garnet, quartz, and minor zircon and beryl (Fig. 3c).The second intermediate zone, composed of albite, quartz and minor microcline grades (Fig. 3c) into the monomineralic massive quartz core.

ANALYTICAL METHODS
Feldspar, epidote, quartz, garnet and zircon crystals were separated for X-ray powder diffraction (XRD) and electronmicroprobe analyses.The XRD analyses were conducted on oriented samples using a Philips diffractometer PW 3040/60 X'Pert PRO (45 kV, 40 mA) with CuK α monochromatised radiation (λ=1.54056Å) and θ-θ geometry.Samples were scanned between 4 and 63 ° 2θ with 0.02 ° step per 0.5 minute.The goniometer was calibrated against a quartz standard.Phase identification was performed using X'Pert Highscore software package (PANanalytical, 2004) in support with ICDD-PDF 2 database (2004).Unit cell parameters were calculated with the least-square refinement program UNIT-CELL (HOLLAND & REDFERN, 1997).
The chemical composition of selected samples was estimated by the JEOL 733 electron microprobe equipped with the Tracor Northern 5500 and 5600 automation.An accelerating voltage of 15 kV and a beam current of 20 nA were used in the analyses.Beam diameter varied with the mineral phase analyzed: 2 mm for zircon, garnet and epidote and 20 mm for feldspars.The following standards were used: albite (Na, Al, Si), sanidine (K), gehlenite (Ca), almandine (Fe), rutile (Ti), tephroite (Mn), zircon (Zr), diopside (Mg), sanbornite (Ba), rubidium microcline (Rb), pollucite (Cs), crocoite (Pb), synthetic REE phosphates (La, Ce, Pr, Nd, Sm, Gd, Er, Yb), synthetic yttrium iron garnet (Y), synthetic hafnon (Hf), synthetic UO 2 (U) and synthetic ThO 2 (Th).Minimum detection limits for all analyzed range from 200 to 300 ppm.Fluid inclusion investigations were carried out on microcline, albite, epidote and quartz crystals.Microthermometric measurements of fluid inclusions were performed using a Linkam THMS 600 stage mounted on an Olympus BX 51 microscope using 10x and 50x Olympus long-working distance objective lenses for visible light.Two synthetic fluid ) were used to calibrate the equipment.The precision of the system was ±2.0 °C for homogenization temperature, and ±0.2 °C in the temperature range between -60 and +10 °C.
The laser Raman spectroscopy, used for the semiquantitative analysis of CO 2 and N 2 in the CO 2 -rich phases of fluid inclusions, was performed on the Dilor LabRAM instrument.A laser beam is focused through an Olympus BX 40 microscope onto the fluid inclusion of interest.The objective lenses of 50x and 100x magnification, combined with a confocal optical arrangement, enable a spatial resolution in the order of a cubic micrometer.Frequency-doubled Nd-YAG green laser (532 nm, 100 mV) was employed.Measurements can also be performed at temperature range between -190 and 600 °C, using the Linkam THMSG 600 heating-cooling stage described above.
Bulk ion compositions of fluid inclusions were established by ion chromatographic analysis applying the technique modified after BOTTREL et al. (1988).About 1 g of cleaned grains and 5 ml of double-distilled and de-ionized water were ground with an agate mortar and pestle to fine powder.The milky solution produced was centrifuged to separate the leachate from the sample.A Dionex DX-500 system with a micromembrane suppressor and pulsed amperometric detector was used for analyses of anions and cations.Detection limits are in the 0.1 ppb (mg/l) range.
The first transitional zone represents mineralogically the most diverse unit of the Čanište pegmatite.It comprises euhedral columnar crystals of epidote, up to 2 m long, embedded in a medium-to coarse-grained matrix of haematite, muscovite, quartz, albite, microcline and garnet.Zircon and beryl grains occur sporadically.
Garnet crystals are not very common.They vary in size, reaching up to 2 cm and have a deep red color.The cell parameters, calculated from diffraction lines using the least-squares method, are a = 11.713(2)Å and V = 1607(1) Å 3 .The molar proportions of garnet end-members were calculated from the electron microprobe data (Table 2) according to the procedure published by LOCOCK (2008).Grossular, with 39.9 -40.7 mole %, represents the principal garnet con- stituent.The proportion of almandine is estimated within a range between 38.0 and 38.1 mole %.Spessartine content spans between 15.2 and 15.9 mole %.Andradite and pyrope contents vary up to 5.2 and 1.2 mole %, respectively.Pinkish, several cm long, zircon crystals display the following unit cell parameters: a = 6.811(4)Å, b = 5.988(6) Å and V = 261.7(3)Å 3 .Its chemical composition and structural formula, calculated on the basis of four atoms of oxygen per formula unit, are summarized in Table 3.
Albite and quartz represent the principal constituents of the second transitional zone.Amazonite microcline occurs sporadically.Blocky white albite occurs in the form of crystals up to 10 cm in size.The unit cell parameters, calculated from diffraction lines using the least-squares method, are a= 8.142( 6  the criteria proposed by ROEDDER (1984).Primary fluid inclusions are sub-rounded to irregular in shape and up to 10 mm in size.Usually these inclusions occur in individual clusters or in isolation.Based on the number of phases, the primary microcline-hosted fluid inclusions could be subdivided into two additional sets: 1) polyphase (L+V+S) and 2) twophase (L+V) inclusions.
Polyphase inclusions comprise up to 50 vol.% of solid phases, highly saline aqueous solution and vapour bubbles (Fig. 4a).Solid phases are usually transparent and inactive in Raman spectra.Salt melting temperatures from 450 °C up to 600 °C (the limit of the heating-freezing stage) suggest salinity higher than 53.3 wt.% NaCl equ.(BODNAR & VI-TYK, 1994).According to Raman microspectroscopy data the vapour bubbles contain only water vapour.Total homogenization occurs by the vapour phase disappearance at temperatures higher than 480 °C.The part of fluid inclusions did not homogenize below the upper temperature limit of the heating stage (600 °C), and consequently the bulk fluid properties and isochores can be calculated only for those inclusions with total homogenization below 600 °C (Fig. 6).
Two phase inclusions contain liquid and vapour phases at room temperature (Fig. 4b).Degree of fill (F) varies between 0.75 and 0.80.Eutectic temperature (T e ) around -52 The partitioning of the albite component between coexisting microcline and plagioclase solid-solutions can be employed as a pressure-dependent geothermometer (WHIT-NEY & STROMER, 1977).Whereas temperature estimated from the two-feldspar geothermometer increases with pressure by l8 °C per kilobar (STROMER & WHITNEY, 1985), the formation temperature can be determined through a combination of the two-feldspar geothermometer with the fluid inclusion data (Fig. 6).
The secondary inclusions in the wall zone amazonite microcline lie along curved trails, display irregular shape and comprise two phases (L+V).Their size below 5 mm precludes microthermometric measurements.
Epidote is the only mineral from the first intermediate zone that hosts fluid inclusions large enough for microthermometric measurements.Primary fluid inclusions occur either isolated or as clusters.They are two-phase (liquid + vapour) up to 15 mm in size, with an elongated, rounded or irregular shape (Fig. 4c).Some inclusions enclose birefringent insoluble solids (Fig. 4d).The solids might be crystals trapped accidentally during the formation of fluid inclusions, rather than daughter minerals, judging by their inconsistent phase ratios.The vapour phase occupies around 20% of the total volume.Raman microspectroscopy only revealed the presence of water.Initial melting temperature between -42 and -62 °C suggests the presence of divalent cations, most likely Ca, Fe and Mg (BARKER, 1995).The final ice melting temperature spanning from -5.6 to -6.7 °C (Fig. 5a) indicates moderately saline fluids (8.7 and 10.1 wt.% NaCl equ.).Homogenization to a liquid phase occurs at temperatures between 180 and 210 °C (Fig. 5b).The calculated fluid density ranges from 0.925 to 0.961 g/cm 3 .
The bulk leachate data of fluid inclusions in epidote suggest Cl -as major anion and Na + and Mg 2+ as the dominant cations (Table 5).
Secondary inclusions, distributed along healed fractures of random orientation, were too small for microthermometric measurements (less than 5 mm).
Fluid inclusions were examined in quartz and albite from the second intermediate zone.The majority of the inclusions have a size below 10 mm.Primary inclusions occur as single, isolated inclusions, or as randomly oriented groups, and commonly mark zones of host crystal growth.These inclusions exhibit irregular to rounded shapes and contain liquid and vapour phases with consistent volumetric proportions (F ≈ 0.80).Frequently, inclusions comprise an insoluble solid phase, interpreted as accidentally trapped crystals (Fig. 4e).Raman microspectroscopy recorded only the presence of water, as for the samples from the first intermediate zone.
Eutectic temperatures around -52 °C indicate a Ca-Na-Cl system (SHEPHERD et al., 1985).The temperatures of final ice melting ranging from -3.4 to -4.2 °C (Fig. 5a) corresponding to salinity between 5.6 and 6.7 wt.% NaCl equ.Temperatures of homogenization into a liquid phase were recorded within an interval between 165 and 180 °C (Fig. 5b).Bulk fluid density, estimated from fluid inclusion data, spans from 0.931 to 0.951 g/cm 3 .Constructed isochores are shown in Figure 6.The intersection of isochores with the two-feldspar geothermometer published by WHITNEY & STROMER (1977), and corrected for pressure according to the procedure described by STROMER & WHITNEY (1985), revealed the formation temperature of the second intermediate zone in the range between 445 and 465 °C under pressure between 4.8 and 5.6 kbar.
Fluid inclusions from the monomineralic massive quartz core show irregular to rounded shapes and range in size up to 15 mm (Fig. 4f).They occur either isolated or in clusters of 5 to 10 inclusions arranged in three-dimensional, nonplanar arrays.Inclusions comprise two phases (liquid and vapour) and have uniform degree of fill around 0.8.Micro-Raman spectroscopy measurements recognized the presence of CO 2 within the vapour phase.
Due to poor optical quality, an initial melting temperature (eutectic temperature, T e ) was not detected.The formation of the CO 2 clathrate phase additionally hampers interpretation of low temperature microthermometric data.Cla th rate melting temperature (T m clat ) in the interval between +8.1 and +8.9 °C (Fig. 5a) corresponds to a salinity of 2.2 to 3.8 wt.% equ.NaCl.Homogenization of the carbonic phase proceeds into vapour phase around 28 °C.Total homogenization by vapour-bubble disappearance occurs in a temperature range between 155 and 170 °C (Fig. 5b).Bulk fluid density, calculated by the BULK software (BAKKER, 2003), ranges between 0.882 and 0.892 g/cm 3 .
The leachate data revealed the predominance of Na + , K + and Cl -in the aqueous fluids responsible for the massive quartz core crystallization (Table 5).

DISCUSSION
Magmatic differentiation by crystal fractionation generally results in the transition of low-volatile content silicate melt (producing normal igneous rocks), through hydrous silicate melt (producing pegmatites), to late-stage water-rich fluids (producing metal ore deposits) (ROEDDER, 1992).The majority of fluid inclusion studies performed on pegmatites suggest crystallization from a water-saturated system and, consequently, immiscibility between the melt phase and volatile fluid (e.g.BEURLEN et al., 2001;THOMAS et al., 2011;THOMAS & DAVIDSON, 2012).
The crystallization evolution of the Čanište epidotebearing pegmatite, is reconstructed using thermodynamic mineral equilibria and fluid inclusion data.The pegmatite originates from intrusion of granodioritic melt into the Pelagonian crystalline basement in the Upper Carboniferous (MOST, 2003).The melt that ultimately produced the Čanište pegmatite was relatively Fe-rich in its initial stage, as indicated by the crystallization of epidote, haematite and almandine.The complete absence of fluxes (B, P, F), and relatively high concentrations of compatible elements (e.g., Ca, Fe, Zr) are very different in comparison to common granitic systems, although similar chemistry has been related with leucotonalitic to quartz leucogabbroic pegmatites (NOVÁK & GA-DAS, 2010).The Čanište pegmatite exhibits a zoned internal structure with four distinctive zones: the wall zone, two intermediate zones and the quartz core.Textural characteristics suggest primary crystallization from melt in order; wall zone → first intermediate zone → second intermediate zone → core.The progressive crystallization resulted in melt composition changes.Concentrations of Ca, Fe and K decreased, and concentrations of Na and Si increased.Fluid inclusion data suggest subsequent crystallization under a steady decrease of temperature and isobaric conditions.Furthermore, fluid inclusion study indicates that aqueous fluids played an important role in the genesis of the Čanište pegmatite.The CO 2 content increased with progressive fractional crystallization, and a significant amount of CO 2 is present only in the very late stage of crystallization.
The presence of primary highly saline aqueous inclusions in the wall zone microcline supports the magmatic origin of the entrapped fluid (e.g.ROEDDER, 1992).Coexisting polyphase (L+V+S) and two-phase (L+V) inclusions as well as large variation in salinity suggest the accidental entrapment near the L/L+S interface of the P-T-X space (e.g.BAKKER & ELBURG, 2006).Whereas the trapping conditions might be estimated from the intersection of isochores constructed for two sets of simultaneously trapped fluid inclusions, and assuming that two principal sets of primary inclusions are contemporaneous, only the minimum possible formation temperature and pressure (600 °C, 3.8 kbar; Fig. 6) can be defined due to lack of homogenization temperatures for high temperature polyphase inclusions.The absence of aplites indicates a nearly constant pressure during pegmatite crystallization (e.g.NABELEK et al., 2010).Assuming a pressure of between 4.8 and 5.6 kbar, (estimated for the second intermediate zone by the combination of two-feldspar geothermometer and fluid inclusion data), the formation temperature of the wall zone then ranges from ca. 650 to 760 °C (Fig. 6).
The formation temperature of the first intermediate zone in the interval between 445 and 550 °C is constrained from the microthermometric data obtained on epidote, assuming  nearly constant pressure during the pegmatite crystallization (4.8-5.6 kbar, Fig. 6).The mineral assemblage comprising almandine, microcline, haematite, muscovite and quartz can be used as an indicator of oxygen fugacity.According to thermodynamic data published by KELLEY (1960), HELGE-SON et al. (1978), WAGMAN et al. (1982), SHOCK &HELGESON (1988) andANOVITZ et al. (1993) and the following equation: oxygen fugacity during deposition of the first intermediate zone was between 10 -22 and 10 -19.5 bar (Fig. 7).
Electron microprobe data were mostly used to calculate chemical formulas of selected minerals from the first intermediate zone.Whereas the epidote group comprises a widespread and chemically complex family of silicates the composition of which can be represented as A 2 M 3 (T 2 O 7 )(TO 4 ) O(OH) (A = Ca 2+ , Mn 2+ , Sr 2+ , REE 3+ ; M = Al 3+ , Fe 3+ , Fe 2+ , Mn 3+ , Mg 2+ ; T = Si 4+ , Al 3+ ), the major issue was to estimate definite mineral formula.According to the data listed in Table 1, epidote from the Čanište pegmatite belongs to the clinozoisite subgroup with the formula (Ca 1.96-1.99Mn 0.02- 0.03 Fe 2+ 0.00-0.02)(Al 2.17-2.46Fe 3+ 0.51-0.82Ti 0.00-0.01)(Si 2 O 7 ) (Si 0.99-1.00Al 0.00-0.01O 4 )O(OH).The majority of analyzed points (PT1 -PT6) display P s value [P s = Fe 3+ /(Fe 3+ +Al)] in the range between 26 and 29 supporting the magmatic origin of epidote (TULLOCH, 1986;SCHMIDT & POLI, 2004).The presence and relative proportions of various garnet endmembers can give insights into conditions of formation.The garnet from the Čanište pegmatite is predominantly grossular with subordinate almandine and spessartine components, minor andradite and a negligible pyrope content.Almandinebearing mineral paragenesis generally points to the weakly evolved granitic/granodioritic rocks generated at great depths (e.g.GREEN, 1977;WHITWORTH, 1992).Zircon from the Čanište epidote-bearing pegmatite has a nearly stoichiometric composition with a Zr/Hf atomic ratio between 39 and 41.The content of U, Th and REE, unusually low for the pegmatitic mineral assemblage, is indicative of the weakly differentiated pegmatitic system.
Crystallization of minerals from the wall and the first intermediate zone decreased activities of calcium, potassium and iron.Consequently, the residual melt has been enriched in water, silica and sodium.Increased sodium activity induced crystallization of the second intermediate zone mineral assemblage with albite and quartz as the major constituents.Microcline occurs sporadically.As already mentioned, microthermometric measurements connected with the two-feldspar geothermometer, constrain the second intermediate zone crystallization conditions at temperatures between 445 and 465 °C under pressure between 4.8 and 5.6 kbar (Fig. 6).
The very last stage in the Čanište pegmatite genesis is represented by the crystallization of the massive quartz core.According to fluid inclusion data, the massive quartz core was produced under the influence of low-saline and CO 2 enriched fluid at a temperature between 400 and 480 °C, assuming the formation pressure between 4.8 and 5.6 kbar (Fig. 6).

CONCLUSION
Textural features and fluid inclusion data suggest that the Čanište epidote-bearing pegmatite formed as a result of subsequent and successive crystallization from a granodioritic melt.Mineral assemblages, especially the presence of almandine and U, Th, REE-depleted zircon, suggests a weakly differentiated pegmatitic system.
The course of pegmatite crystallization was proceeding close to isobaric conditions.The formation pressure is estimated within the range of between 4.8 and 5.6 kbar (average at 5.2 kbar).The primary wall zone mineral assemblage (microcline ± biotite, quartz) crystallized from the melt between 650 to 760 °C.Cooling of the melt below 550 °C at oxygen fugacity between 10 -22 and 10 -19.5 bar, caused deposition of the first intermediate zone (epidote + haematite + grossular + muscovite + quartz + almandine ± zircon, beryl, microcline, quartz).Progress of crystallization decreased activities of calcium, iron and potassium, and increased water, silica and sodium contents in the residual melt.The second intermediate zone comprises albite, which crystallized from the Na-enriched melt.The formation temperature estimated from the fluid inclusion data, as well as from two-feldspar geothermometer, spans the range from 445 to 465 °C.The massive quartz core was produced at temperatures between 400 and 480 °C from the very last melt residue enriched in silica, water and CO 2 content.

Figure 3 :
Figure 3: a) Photomicrographs of microcline from the wall zone; b) the transition from the first intermediate zone comprising epidote, hematite, muscovite and quartz into the second intermediate zone with albite and quartz.Abbreviations: Ab -albite; Ep -epidote; Hem -hematite; Mic -microcline; Ms -muscovite; Qtz -quartz.

Figure 4 :
Figure 4: Photomicrographs of representative primary fluid inclusions from different sub-units of the Čanište epidote-bearing pegmatite: a) hydrosaline (L+V+S) inclusion recorded within microcline from the wall zone; b) two-phase (L+V) inclusion hosted by microcline from the wall zone; c) two-phase inclusion (L+V) within epidote from the first intermediate zone; d) threephase inclusion (L+V+S) contains accidentally trapped anisotropic solid phase, epidote from the first intermediate zone; e) inclusion with accidentally trapped crystal, quartz from the second intermediate zone; f) two-phase (L+V) inclusions from the quartz core.

Figure 5 :
Figure 5: Microthermometric data for fluid inclusions from different subunits of the Čanište epidote-bearing pegmatite; a) Plots of ice-melting (T m ice ) and clathrate-melting (T m CLAT ) temperatures; b) Plots of homogenization temperatures.

Figure 6 :
Figure 6: Pressure-temperature diagram summarizing the relevant information relating to the P-T history of the Čanište epidote-bearing pegmatite.

Table 1 :
Representative microprobe analyses, calculated formulas and distribution of the key cation sites for epidote from the first intermediate zone of the Čanište epidote-bearing pegmatite.
< d.l.-below detection limit * Total iron content given as Fe 2 O 3 K, Na and Mg are below detection limits ** Determined by stoichiometry inclusion standards (SYN FLINC; pure H 2 O and mixed H 2 O-CO 2

Table 2 :
Representative microprobe analyses, calculated formulas, distribution of the key cation sites and the end-member contents for garnets from the first intermediate zone of the Čanište epidote-bearing pegmatite.

Table 3 :
Representative microprobe analyses and calculated formulas for zircon from the first intermediate zone of the Čanište epidote-bearing pegmatite.

Table 4 :
Representative microprobe analyses and calculated formulas for feldspars from the second intermediate zone of the Čanište epidote-bearing pegmatite.

Table 5 :
The bulk leachate analyses for epidote and quartz from the Čanište epidote-bearing pegmatite.