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HomeMaterials Science ForumMaterials Science Forum Vol. 833Synthesis and Structural Characterization of Ti2C...

Synthesis and Structural Characterization of Ti₂C Nanosheets

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Abstract:

In this paper, two-dimensional (2D) Ti₂C nanosheets were synthesized by exfoliation of Ti₂AlC powders in HF solution at room temperature. The surface atomic composition and chemistry of as-prepared Ti₂C nanosheets were studied by XPS. The specific surface area of Ti₂C nanosheets were determined by BET. The as-prepared Ti₂C nanosheets are stacked and held together, which leads to the lower specific surface area of the as-prepared Ti₂C nanosheets.

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Applied Materials and Technologies

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Periodical:

Materials Science Forum (Volume 833)

Pages:

44-47

DOI:

https://doi.org/10.4028/www.scientific.net/MSF.833.44

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Online since:

November 2015

Authors:

Jing Xiao Li, Yu Lei Du*, Chong Cui

Keywords:

MXene, Ti₂C Nanosheets, Two-Dimensional Structure

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* - Corresponding Author

[1] M. Naguib, M. Kurtoglu, V. Presser, J. Lu, J. Niu, M. Heon, L. Hultman, Y. Gogotsi, M.W. Barsoum, Two-dimensional nanocrystals produced by exfoliation of Ti3AlC2, Adv. Mater. 23 (2011) 4248-4253.

DOI: 10.1002/adma.201102306

[2] M. Naguib, O. Mashtalir, J. Carle, V. Presser, J. Lu, L. Hultman, Y. Gogotsi, M.W. Barsoum, Two-dimensional transition metal carbon, ACS Nano. 6 (2012) 1322-1331.

DOI: 10.1021/nn204153h

[3] M. Naguib, J. Come, B. Dyatkin, V. Presser, P. -L. Taberna, P. Simon, M.W. Barsoum Y. Gogotsi, MXene: a promising transition metal carbide anode for lithium-ion batteries, Electrochem. Commun. 16 (2012) 61-64.

DOI: 10.1016/j.elecom.2012.01.002

[4] M.R. Lukatskaya, O. Mashtalir, C.E. Ren, Y. Dall'Agnese, P. Rozier, P.L. Taberna, M. Naguib, P. Simon, M.W. Barsoum, Y. Gogotsi, Cation intercalation and high volumetric capacitance of two-dimensional titanium carbide, Science 341 (2013).

DOI: 10.1126/science.1241488

[5] Q. Hu, D. Sun, Q. Wu, H. Wang, L. Wang, B. Liu, A. Zhou, J. He, MXene: a new familily promising hydrogen storage medium, J. Phys. Chem. A 117 (2013) 14253-14260.

DOI: 10.1021/jp409585v

[6] Q. Peng, J. Guo, Q. Zhang, J. Xiang, B. Liu, A. Zhou, R. Liu, Y. Tian, Unique lead adsorption behavior of activated hydroxyl group in two-dimensional titanium carbide, J. Am. Chem. Soc. 136 (2014) 4113-4116.

DOI: 10.1021/ja500506k

[7] L.Y. Gan, D. Huang, U. Schwingenschlögl, Oxygen adsorption and dissociation during the oxidation of monolayer Ti2C, J. Mater. Chem. A 1 (2013) 13672-13678.

DOI: 10.1039/c3ta12032e

[8] Y. Xie, P.R.C. Kent, Hybrid density functional study of structural and electronic properties of functionlized Tin+iXn (X= C, N) monolayers, Phys. Rev. B 87 (2013) 235441.

[9] T.H. Wang, Y.F. Zhu, Q. Jiang, Bandgap opening of bilayer graphene by dual doping from organic molecule and substrate, J. Phys. Chem. C 117 (2013) 12873-12881.

DOI: 10.1021/jp402583j

[10] J. Xiao, D. Choi, L. Cosimbescu, P. Koech, J. Liu, J.P. Lemmon, Exfoliated MoS2 nanocomposite as an anode material for lithium ion batteries, Chem. Mater. 22 (2010) 4522-4524.

DOI: 10.1021/cm101254j

[11] J. Yang, H. Z. Bai, Q. Jiang, J. S. Lian, Visible-light photocatalysis in nitrogen-carbon-doped TiO2 films obtained by heating TiO2 gel-film in an ionized N2 gas, Thin Solid Films 516 (2008) 1736-1742.

DOI: 10.1016/j.tsf.2007.05.034

[12] D. Gu, Y. Lu, B. Yang, Y. Hu, Facile preparation of micro-mesoporous carbon-doped TiO2 photocatalysts with anatase crystalline walls under template-free condition, Chem. Commun. (2008) 2453-2455.

DOI: 10.1039/b800596f

[13] Y. Fu, H. Du, S. Zhang, W. Huang, XPS characterization of surface and interfacial structure of sputtered TiNi films on Si substrate, Mat. Sci. Eng. A 403 (2005) 25-31.

DOI: 10.1016/j.msea.2005.04.036

[14] S.K. Parayil, H.S. Kibombo, C.M. Wu, R. Peng, J. Baltrusaitis, R.T. Koodali, Enhanced photocatalytic water splitting activity of carbon-modified TiO2 composite materials synthesized by a green synthetic approach, Int. J. Hydrogen Energ. 37 (2012).

DOI: 10.1016/j.ijhydene.2012.02.067

[15] W.F. Wei, X.W. Cui, W.X. Chen, D.G. Ivey, Phase-controlled synthesis of MnO2 nanocrystals by anodic electrodeposition: implications for high-rate capability electrochemical supercapacitors, J. Phys. Chem. C 112 (2008) 15075-15083.

DOI: 10.1021/jp804044s