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HomeKey Engineering MaterialsKey Engineering Materials Vol. 727SnO2 Nanoparticles for Lithium-Ion Batteries...

SnO₂ Nanoparticles for Lithium-Ion Batteries Prepared by Sol-Gel Method

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Abstract:

Nanostructured SnO₂ is an attractive anode material for high-energy-density lithium-ion batteries because of the fourfold higher theoretical charge capacity than commercially used graphite. However, the poor capacity retention at high rates and long-term cycling have intrinsically limited applications of nanostructured SnO₂ anodes due to large polarization and ~300% volume change upon lithium insertion/extraction. Here we report the design of SnO₂ nanoparticles, which are synthesized by sol-gel method, with an aim at overcome the above problems for the high-performance reversible lithium storage. The results showed that the mean sizes of SnO₂ particles treated with 6 wt.% ammonia were less than 30 nm, which can store charge with a capacity density as high as ~1888 mAh/g. Even when the discharge rate was increased to 0.5 C, it still retained ~1017 mAh/g.

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Functional Materials Research II

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Periodical:

Key Engineering Materials (Volume 727)

Pages:

718-725

DOI:

https://doi.org/10.4028/www.scientific.net/KEM.727.718

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Online since:

January 2017

Authors:

Xu Yan Liu, Yan Lin Han, Qiang Li, Deng Pan*

Keywords:

Anode Material, Lithium-Ion Battery, Nanoparticle, Sol-Gel, TiN Dioxide

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* - Corresponding Author

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