Effect of Variation of Temperature on the Transesterification of Jatropha Seed Oil Using Homogeneous Catalyst

Article Preview

Abstract:

Transesterification is a chemical reaction which produces biodiesel from vegetable oils or animal fats.Transesterification of Jatropha seed oil and methanol with sodium hydroxide as a catalyst was carried out in an improvised batch reactor at different temperatures ranging from 32 65 degrees Celsius for 120minutes each. Molar ratio of methanol to oil used is 8:1.Aliquots of the reaction mixture were withdrawn at every 15 minutes interval of time from the time reaction starts for Gas Chromatographic analysis to determine percentage fatty acid methyl ester formed. The optimum percentage conversion, temperature and reaction time were found to be 99.9%, 65°C and 75minutes respectively. The fuel properties measured according to standard methods, were found to conform to International standard.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

473-476

Citation:

Online since:

September 2013

Export:

Price:

[1] Das L. M. (2008). Potential of Biofuels. Roundtable on Sustainable Biofuels, IIT Delhi. Centre for Energy Studies. Indian Institute of Technology, Delhi.

Google Scholar

[2] Pisarello M. I., Dalla Costa B., Mendow G., Querini C. A. (2010).

Google Scholar

[3] Refaat A. A. (2010). Different techniques for the production of biodiesel from waste vegetable oil. (A Review). Int. J. Environ. Sci Tech, 7(1), 183 – 213.

DOI: 10.1007/bf03326130

Google Scholar

[4] Meher, L. C. Sagar, D. V. and Naik, S. N., (2006), Technical aspects of biodiesel production by transesterification – a Review. Renewable and sustainable energy Reviews, 10: 248 – 268.

DOI: 10.1016/j.rser.2004.09.002

Google Scholar

[5] http: /en. wikipedia. org/wiki/biodiesel. production. nw. heed.

Google Scholar

[6] Sepidar sayyar, Zurina Zainaql Abidin. Robiah tunus and Azhari Muhannad (2009) Extraction of oil from Jatropha-optimization and kinetics. America Journal of Applied Sciences 6 (7): 1390 – 1395.

DOI: 10.3844/ajassp.2009.1390.1395

Google Scholar

[7] Rajesh Kumar Pandey, Rehman A., Sarviya R.M. Savita Dixit (2009), "Development of Clean Burning fuel for Compression. Ignition Engines, Asian J. Exp. Sci. vol. 23, No. 1, 223-234.

Google Scholar

[8] Refaat A.A. (2009). Correlation between the chemical structure of biodiesel and its physical properties (a review). Int. J. environ. Sci. Tech. 6 (4), 667 – 694.

Google Scholar

[9] Matthew Slinn, Kevin Kendall "Developing the reaction kinetics for a biodiesel reactor (2009) Bioresource Technology 100; pp.2324-2327.

DOI: 10.1016/j.biortech.2008.08.044

Google Scholar

[10] DJ Vujicic, D. Comicb, A. Zarubicaa, R. Micib, G. Boskovica, (2010) Kinetics of biodiesel synthesis from sunflower oil over Ca0 heterogeneous catalyst. Fuel 89: p.2054 -(2061).

DOI: 10.1016/j.fuel.2009.11.043

Google Scholar

[11] Makama B.Y. (2012) Effect of temperature on the transesterification of cod liver oil. Research Journal of chemical sciences vol. 2 (7), pp.82-84.

Google Scholar

[12] Biodiesel Handling and use Guidelines (2004). US. Department of Energy Efficiency and Renewable Energy (DOE/GO-10 2004 – 1999).

Google Scholar