Preparation of LLDPE/Modified Silica Nanoparticle with Triethoxyvinylsilane Film for Microwaveable Packaging

Abstract:

Nanocomposite films based on liner low density polyethylene (LLDPE), containing of 1 phr silica nanoparticle and 1, 3 and 5 %wt triethoxyvinylsilane as a new coupling were prepared and characterized using FTIR tests, scanning electron microscopy, tensile tests, oxygen and water vapor permeation measurements. Optimization of the technology involved in production of an exfoliated nanocompound is a complex process in which multiple variables and parameters are involved. The results of the study showed that the feed position of the nanoparticle in the double screw extruder is of vital importance in obtaining an exfoliated film. The maximum triethoxyvinylsilane used in the extruder was 3 %wt, for LLDPE/modified silica nanoparticle. There was no exfoliation or intercalation of the silica particle in the absence of triethoxyvinylsilane. The oxygen barrier properties of the LLDPE/modified silica nanoparticle film were significantly better than those of the LDPE/silica nanoparticle film. In addition to barrier properties, the LLDPE/silica/3%TEVS film also had better Young’s modulus and tensile strength than their counterparts without triethoxyvinylsilane.