Structural Analysis of Multiphase La1-XSrxCo1-XFexO3-δ

Article Preview

Abstract:

Multiphase La1-xSrxFe1-yCoyO3-δ has been synthesized by sol-gel method and characterized by powder X-diffraction. Structure refinements of multiphase were undertaken to analyze compositions of compounds, and structure parameters were determined by Rietveld method, respectively. It was found that products were easier to be prepared in the condition of a precursor dealed with by high-speed disintegrator, and products synthesized at 1173K were composed of two phases of which La0.75Sr0.25Co0.2Fe0.8O3-δ is an orthorhombic structure with space group Pbnm and La0.46Sr0.54Co0.2Fe0.8O3-δ trigonal structure with space group R-3c. Structure geometry becomes more regular with increasing Sr content.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

74-77

Citation:

Online since:

December 2010

Export:

Price:

[1] J.M. Ralph, J.T. Vaughey and M. Krumpelt: Electrochem. Soc. Proc. Vol. 16 (2001), p.466.

Google Scholar

[2] J. -W. Kim, A.V. Virkar, K. -Z. Fung, et al.: J. Electrochem. Soc. Vol. 146 (1999), p.69.

Google Scholar

[3] V.V. Kharton, A.P. Viskup, D.M. Bochkov, et al.: Solid State Ionics. Vol. 110 (1998), p.61.

Google Scholar

[4] G.C. Kostogloudis and Ch. Ftikos: Solid State Ionics. Vol. 126 (1995), p.143.

Google Scholar

[5] S.P. Jiang: Solid State Ionics. Vol. 146 (2002), p.1.

Google Scholar

[6] E.P. Murray, M.J. Sever and S.A. Barnett: Solid State Ionics. Vol. 148 (2002), p.27.

Google Scholar

[7] J. Mizusaki, J. Tabuchi, T. Matsuura, et al.:J. Electrochem. Soc. Vol. 136 (1989), p. (2082).

Google Scholar

[8] Y. Teraoka, H.M. Zhang, K. Okamoto, et al.: Mater. Res. Bull. Vol. 23 (1988), p.51.

Google Scholar

[9] S. Sekido, H. Tachibana, Y. Yamamura, et al.: Solid State Ionics. Vol. 37 (1990), p.253.

Google Scholar