Microwave Induced Pyrolysis of Biomass

Article Preview

Abstract:

Microwave heating has attracted much attention recently due to its nature of volumetric heating and instant heating. In this study, microwave heating was adopted not only as a heating method but also an approach to enhance the pyrolysis of biomass. Microwave induced pyrolysis was carried out at 500°C with silicon carbide as a microwave energy absorber. Conventional pyrolysis of gumwood was also conducted under the same operating temperature as microwave-enhanced pyrolysis. The yields of pyrolytic bio-oil and bio-gas under microwave heating are 8.52 wt% and 73.26 wt% respectively, which are higher than the products obtained via conventional methods under similar operating conditions. A series tests were performed to compare the difference between the yields of pyrolytic products, i.e. gaseous products (bio-gas), liquid products (bio-oil) and solid products( bio-char). Scanning Electron Microscope (SEM), Gas Chromatograph/Mass Spectrum (GC-MS) and Gas Chromatograph (GC) were used in this study to characterize the morphology of bio-chars, the composition of bio-gas and bio-oil respectively. The bio-oil produced via microwave pyrolysis has simpler constituents compared with that produced via conventional pyrolysis. The proportion of syngas (H2+CO) and methane (CH4) in the gas product produced under microwave-enhanced pyrolysis are 62.52 vol % and 22.41vol % respectively, which are higher than those in the products of conventional pyrolysis. It is clear that microwave-enhanced pyrolysis has shown a great potential as an alternative method for biomass conversion.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

127-133

Citation:

Online since:

May 2013

Export:

Price:

[1] IEA. World Energy Outlook 2011. In. Paris: International Energy Agency; 2011, p.659.

Google Scholar

[2] Damartzis T, Zabaniotou A. Thermochemical conversion of biomass to second generation biofuels through integrated process design—A review. Renewable and Sustainable Energy Reviews (2011); 15:366-378.

DOI: 10.1016/j.rser.2010.08.003

Google Scholar

[3] Zhang L, Xu C, Champagne P. Overview of recent advances in thermo-chemical conversion of biomass. Energy Conversion and Management (2010); 51:969-982.

DOI: 10.1016/j.enconman.2009.11.038

Google Scholar

[4] V. L. Budarin JHC, B. A. Lanigan, P. Shuttleworth, S. W. Breeden, A. J. Wilson, D. J. Macquarrie, K. Milkowski, J. Jones, T. Bridgeman, A. Ross. The preparation of high-grade bio-oils through the controlled, low temperature microwave activation of wheat straw. Bioresour. Technol. (2009); 100:6064-6068.

DOI: 10.1016/j.biortech.2009.06.068

Google Scholar

[5] D. S. Scott JP. The continuous flash pyrolysis of biomass. The Canadian Journal of Chemical Engineering (1984); 62:404-412.

Google Scholar

[6] X. Q. Zhao ZLS, H. Z. Liu, Z. Q. Li, L. Z. Li, C. Y. Ma. Microwave pyrolysis of corn stalk bale: A promising method for direct utilization of large-sized biomass and syngas production. J. Anal. Appl. Pyrolysis (2010); 89:87-94.

DOI: 10.1016/j.jaap.2010.06.001

Google Scholar

[7] A. Baysar KJJ, J.L. Kuester. Microwave heating applications in thermochemical biomass conversion. In: Research in Thermochemical Biomass Conversion. London: Elsevier Applied Science; 1988, pp.680-695.

DOI: 10.1007/978-94-009-2737-7_52

Google Scholar

[8] W. K. Tu JLS, C. Y. Chang, C. F. Chang, C. F. Lin, S. Y. Yang, J. T. Kuo, D. G. Shaw, Y. D. You, D. J. Lee. Products and bioenergy from the pyrolysis of rice straw via radio frequency plasma and its kinetics. Bioresource Technology (2009); 100:2052-2061.

DOI: 10.1016/j.biortech.2008.09.052

Google Scholar

[9] Kırtay E. Recent advances in production of hydrogen from biomass. Energy Conversion and Management (2011); 52:1778-1789.

DOI: 10.1016/j.enconman.2010.11.010

Google Scholar

[10] Bridgwater AV. Review of fast pyrolysis of biomass and product upgrading. Biomass and Bioenergy (2012); 38:68-94.

DOI: 10.1016/j.biombioe.2011.01.048

Google Scholar

[11] Bridgwater AV. Principles and practice of biomass fast pyrolysis processes for liquids. Journal of Analytical and Applied Pyrolysis (1999); 51:3-22.

DOI: 10.1016/s0165-2370(99)00005-4

Google Scholar

[12] Y. Tian WZ, Z. Y. Ren, D. D. Chen. Estimation of a novel method to produce bio-oil from sewage sludge by microwave pyrolysis with the consideration of efficiency and safety. Bioresour. Technol. (2011); 102:2053-2061.

DOI: 10.1016/j.biortech.2010.09.082

Google Scholar

[13] M. R. Islam HH, M. R. A. Beg. Liquid fuels and chemicals from pyrolysis of motorcycle tire waste: Product yields, compositions and related properties. Fuel (2008); 87:3112-3122.

DOI: 10.1016/j.fuel.2008.04.036

Google Scholar

[14] T. Kwak SM, S. Lee, J. W. Park, B. R. Min, Y. D. Yoo. Environmental aspects of gasification of Korean municipal solid waste in a pilot plant. Fuel (2006); 85:2012-2017.

DOI: 10.1016/j.fuel.2006.03.012

Google Scholar

[15] D. E. Clark WHS. Microwave processing of materials. Annual Review of Materials Science (1996); 26:299-331.

Google Scholar

[16] E. T. Thostenson TWC. Microwave processing: fundamentals and applications. Composites Part A: Applied Science and Manufacturing (1999); 30:1055-1071.

DOI: 10.1016/s1359-835x(99)00020-2

Google Scholar

[17] T. J. Appleton RIC, S. W. Kingman, I. S. Lowndes, A. G. Read. Microwave technology for energy-efficient processing of waste. Applied Energy (2005); 81:85-113.

DOI: 10.1016/j.apenergy.2004.07.002

Google Scholar

[18] M. Miura HK, A. Sakurai, T. Kakuchi, K. Takahashi. Rapid pyrolysis of wood block by microwave heating. J. Anal. Appl. Pyrolysis (2004); 71:187-199.

DOI: 10.1016/s0165-2370(03)00087-1

Google Scholar

[19] A. de la Hoz AD-O, A. Moreno. Microwaves in organic synthesis. Thermal and non-thermal microwave effects. Chemical Society Reviews (2005); 34:164-178.

DOI: 10.1039/b411438h

Google Scholar

[20] R. Omar AI, R. Yunus, K. Khalid, M. I. Aida Isma. Characterization of empty fruit bunch for microwave-assisted pyrolysis. Fuel (2011); 90:1536-1544.

DOI: 10.1016/j.fuel.2011.01.023

Google Scholar

[21] E. Antonakou AL, M. H. Nilsen, A. Bouzga, M. Stöcker. Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals. Fuel (2006); 85:2202-2212.

DOI: 10.1016/j.fuel.2006.03.021

Google Scholar

[22] A. A. Salema FNA. Microwave induced pyrolysis of oil palm biomass. Bioresour. Technol. (2011); 102:3388-3395.

DOI: 10.1016/j.biortech.2010.09.115

Google Scholar

[23] M. Koberg MC, A. Ben-Amotz, A. Gedanken. Bio-diesel production directly from the microalgae biomass of Nannochloropsis by microwave and ultrasound radiation. Bioresour. Technol. (2011); 102:4265-4269.

DOI: 10.1016/j.biortech.2010.12.004

Google Scholar

[24] Y. Fernandez BF, A. Dominguez, J. J. Pis, J. A. Menendez Obtaining synthesis gas by heat treatment in microwave biomass and biogas. Afinidad (2008); 65:103-109.

Google Scholar

[25] A. Dominguez JAM, Y. Fernandez, J. J. Pis, J. M. V. Nabais, P. J. M. Carrott, M. M. L. Carrott. Conventional and microwave induced pyrolysis of coffee hulls for the production of a hydrogen rich fuel gas. J. Anal. Appl. Pyrolysis (2007); 79:128-135.

DOI: 10.1016/j.jaap.2006.08.003

Google Scholar

[26] Y. F. Huang WHK, S. L. Lo, C. F. Lin. Total recovery of resources and energy from rice straw using microwave-induced pyrolysis. Bioresour. Technol. (2008); 99:8252-8258.

DOI: 10.1016/j.biortech.2008.03.026

Google Scholar

[27] Fernández Y, Menéndez JA. Influence of feed characteristics on the microwave-assisted pyrolysis used to produce syngas from biomass wastes. Journal of Analytical and Applied Pyrolysis (2011); 91:316-322.

DOI: 10.1016/j.jaap.2011.03.010

Google Scholar

[28] Salema AA, Ani FN. Microwave-assisted pyrolysis of oil palm shell biomass using an overhead stirrer. Journal of Analytical and Applied Pyrolysis (2012); 96:162-172.

DOI: 10.1016/j.jaap.2012.03.018

Google Scholar