Kinetics of Siderite Ore Roasting in the Shaft Furnace

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Kinetics of the siderite ore roasting in the air, helium and hydrogen flows has been studied in a gasometrical unit with continuous mass variation logging. We have derived the expression for determination of an apparent degree of calcination and identified its dependence on the size of the prill, the heat treatment duration, and gas-phase composition. Using a generalized chemical kinetics equation, we have obtained a formula for calculation of the decomposition period for siderite ore samples. It has been found that calcination rate increases with the temperature rise, irrespective of the sample size and atmospheric composition. Calcination process has been studied at low temperatures. We have demonstrated that it is feasible to describe the process of siderite ore thermal dissociation by a first-order kinetics equation. We have obtained the expression to calculate the duration of this process depending on different parameters. Using a generalized chemical kinetics equation, we have obtained a formula for checking the expressions that describe the experimental data. We have studied kinetics of the reduction of roasted ore samples at various temperatures using different sizes of the samples. The obtained results have been applied for optimization of the design values and operating conditions of the siderite ore roasting in shaft furnaces. These will also be used for designing a shaft furnace consisting of a calcination zone, reduction zone (metallization zone) and metallized product cooling zone, which will increase iron content in the end-product to 65-70%.

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456-461

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February 2019

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[1] B.P. Yuriev, S.G. Melamud, N.A. Spirin, V.V. Shatsillo, Technological and thermotechnical basics of preparation of siderite ore for metallurgical treatment, OOO AMK Den RA, Yekaterinburg, (2016).

Google Scholar

[2] B.P. Yuriev, S.G. Melamud, N.A. Spirin, The study of kinetics of Bakal siderite ore dissociation, Izvestiya vuzov, Ferrous industry 10 (2012) 12-14.

DOI: 10.17073/0368-0797-2012-10-12-14

Google Scholar

[3] N.V. Akhlyustina, Influence of chemical mineralogical composition of siderite and sideroplesite on the decomposition onset temperature, Izvestiya vuzov, Mining journal 8 (1979) 135-138.

Google Scholar

[4] M.M. Goldman, L.P. Ni, A.I. Ardasheva, T.B. Tursunbaev, Siderite behaviour during roasting, Izvestiya vuzov, Non-ferrous industry 3 (1977) 41-44.

Google Scholar

[5] B.P. Yuriev, T.I. Kostousova, The study of the properties of siderite ore and the products of its roasting during heat treatment, Izvestiya vuzov, Ferrous industry 3 (1999) 17-23.

Google Scholar

[6] M.N. Zaparnyuk, E.G. Neshporenko, Determination of thermodynamic conditions of energy efficient siderite ore treatment, Nauka i proizvodstro Urala 11 (2015) 2-3.

Google Scholar

[7] L.I. Leontiev, N.A. Vatolin, S.V. Shavrin, N.S. Shumakov, Pyrometallurgical Treatment of Multimetal Ore, Metallurgia, Moscow, (1997).

Google Scholar

[8] Z.I. Kostina, S.A. Krylova, I.V. Ponurko, The question of siderite ore treatment, International journal of applied and fundamental research 11, 4 (2015) 580-585.

Google Scholar

[9] V.I. Bolshakov, High-Efficient Energy-Saving Blast-Furnace Smelting Process, Naukova dumka, Kiev, (2007).

Google Scholar

[10] O. Muhl, Erfahrungsbericht uber die Schwertrube-Lyklonanlage an Steiurischen Erzberg, Berg-und Huttenmannische Monashefte 126, 8 (1981) 344-348.

Google Scholar

[11] A. Kardi, Moznosti Ldokonalenia technologie up ravy Sideritovej rudy vzavode LB Rudnany, Rudy 31, 3 (1983) 75-79.

Google Scholar

[12] B.P. Yuriev, V.A. Goltsev, The influence of siderite ore composition, design values and operating conditions on the shaft furnace performance, Stal 4 (2013) 6-10.

Google Scholar

[13] B.P. Yuriev, S.G. Melamud, Roasting of siderite ore with the use of solid fuel, Stal 7(2012)2-4.

Google Scholar

[14] B.P. Yuriev, Calculation procedure for heating time of siderite ore at phase changes, Izvestiya vuzov, Ferrous industry 3 (2011) 61-64.

Google Scholar

[15] B.P. Yuriev, V.V. Shatsillo, S.G. Melamud, Procedure for determination of solid fuel consumption for siderite ore roasting in various gas media, Izvestiya vuzov, Ferrous industry 2 (2008) 8-11.

Google Scholar

[16] B.P. Yuriev, A.G. Zhunev, Peculiarities of desulphurization during Bakal siderite ore roasting, Stal 12 (2009) 12-16.

Google Scholar

[17] B.P. Yuriev, S.G. Melamud, V.V. Shatsillo, Influence of design values and operating conditions of shaft furnaces on the properties of siderite ore and the products of its roasting, Ferrous metallurgy: Bulletin of Chermetinformatsia institute 9(1281) (2006) 16-33.

Google Scholar

[18] V.A. Krasnoborov, S.L. Yaroshevsky, A.A. Denisov et al., Siderite Ore: Efficiency and Industrial Perspectives for Blast-furnace Smelting, Novy Mir, Donetsk, (1996).

Google Scholar

[19] M.E. Blank, B.A. Bokovikov, T.D. Trapeznikova, B.P. Yuriev, Experimental studies of siderite ore roasting, in: Thermotechnical Research of the Processes and Units in Ferrous Metallurgy, Metallurgia, Moscow, (1986) 9-12.

Google Scholar

[20] B.P. Yuriev, V.V. Shatsillo, S.G. Melamud, Principles of recognition for heat of reactions taking place in a roasted siderite ore layer during determination of optimal fuel consumption in the shaft furnace, Izvestiya vuzov, Ferrous industry 8 (2008) 3-5.

Google Scholar