Application of Iron Powder Reduction Method to Remove Heavy Metals in Waste Pickling Acid

Article Preview

Abstract:

The removal of heavy metals in waste pickling acid by iron powder reduction was studied. The effects of reaction time, reaction temperature and dosage of iron powder on the removal efficiency of Zn, Cr, Ni and Pb in waste pickling acid were investigated. The results showed that, the removal rate of Cr tended to be stable after 2 h of reaction under magnetic stirring. After 4 hours, the removal rate of Zn,Ni and Pb tended to be stable. The temperature was increased from 20°C to 90 °C, the removal rates of Ni and Pb could be increased by 9.09% and 11.6%, while the removal rates of Zn and Cr were only increased by 1.15% and 2.85%; Increasing the dosage of iron powder was beneficial to the removal of heavy metals in waste pickling acid, and the combined amount of free acid in the waste acid would affect the removal efficiency of heavy metals. The research results had important guiding significance for the practical application of iron powder reduction method in the heavy metal purification project of waste pickling acid.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

377-386

Citation:

Online since:

March 2020

Export:

Price:

* - Corresponding Author

[1] Lu Huijie, Liang Huiting, Zhang Gongxiao, et al. Research progress of recycling and utilization of steel hydrochloric waste pickling acid. Shndong Chemical Insudtry, 43(2014) 46-50.

Google Scholar

[2] Yu Hui, Sun Cong-cong, Jiao Shao-jun, et al.Research Progress on Comprehensive Treatment and Resource Utilization of Waste Acid. The Administration and Technique of Environmental Monitoring, 30(2018)5-10.

Google Scholar

[3] He Miaomiao, Hu Xiaojun, Song Xueying, et al. Introduction to the treatment of water body polluted by heavy metal. Environmental Protection and Recycling Economy, 34(2014) 50-52.

Google Scholar

[4] Ma Jian-wei, Ren Shu-peng, Chu Yang, et al. Chemical precipitation method for treating heavy metal wastewater. Chemical Engineer, 275(2018)57-59.

Google Scholar

[5] Wang Shengfan, Mei Liyong, Wang Lei, et al. Treatment methods of heavy metal effluent and comparison. Guangdong Chemical Engineering, 44(2017) 99-100.

Google Scholar

[6] Cao Haifeng. Research progress in the technologies for the treatment of wastewater containing complexed heavy metal. Industrial Water Treatment, 35(2015)14-17.

Google Scholar

[7] Ma Jianwei, Ren Shupeng, Song Yarui. Advances in the Application of Zero-Valent Iron Technology in the Field of Wastewater Treatment. Chemistry, 82(2019)3-11.

Google Scholar

[8] Liu Zhiying, Wang Xiaojun, Zhao Shuang. Treatment of chemical plating low-concentration nickeliferous rinse water by reductive iron powder replacement method. Electroplating & Finishing, 35(2016) 427-430.

Google Scholar

[9] Zhang Yong-xiang, Ma Xiao-min. Removal of chromium(VI) from water by modified nano zero-valent iron. Applied Chemical Industry, 47(2018)1569-1573.

Google Scholar

[10] Liu Zhicheng. Study on resource utilization technologies of waste pickling acid in iron and steel enterprise. Xiangtan University, (2016).

Google Scholar

[11] Editorial board of SEPA Water and Effluent Monitor and Analytic Methods. Water and Effluent Monitor and Analytic Methods. Edition 4. Beijing: China Environmental Science Press, (2002).

Google Scholar