Effects of Atmospheric Plasma Treatment on the Surface Properties of Wood-Plastic Composites

Article Preview

Abstract:

Wood-plastic composites are a group of materials with potential to penetrate markets currently dominated by plastic or wood products. The surface properties of wood-plastic composite materials have been found to be similar to those of polyolefin materials, thereby presenting a challenge to the use of adhesive joining methods. Plasma chemistry can be performed to improve the adhesive properties of polyolefin materials. In this research, the effect of atmospheric plasma treatment on polypropylene and spruce (Picea abies) wood-plastic composite surfaces is investigated by contact angle measurement with sessile drop method and tensile strength tests of glued samples. The plasma treatment is performed on extruded WPC profiles. Confocal Raman microscopy and scanning electron microscopy are used for analysis of the material surface. The results show an increase in the contact angle of plasma treated WPC materials and an improvement in the tensile strength of glued samples following plasma treatment. Observation of the Raman spectrum indicates an increase in polar groups after plasma treatment. Scanning electron microscopy shows changes in the surface of the treated samples, which can be seen as increased porosity, possibly due to etching as a result of the plasma treatment. It is concluded that atmospheric plasma treatment for adhesion improvement of WPC materials can therefore be applied successfully, although it has a mechanical effect on the surface of the material.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 718-720)

Pages:

176-185

Citation:

Online since:

July 2013

Export:

Price:

[1] A. Eder, S. Strobl, P. Schwarzbauer, Worldwide Market Report on "Wood-Plastic Composites" Revised Ed. 2007, Wood-K plus, (2007)

Google Scholar

[2] B.S. Gupta, I. Reiniati, M-P.G. Laborie, Surface properties and adhesion of wood fiber reinforced thermoplastic composites, Colloids and Surfaces A: Physicochem. Eng. Aspects 302 (2007) 388-395

DOI: 10.1016/j.colsurfa.2007.03.002

Google Scholar

[3] A. Wolkenhauer, G. Avramidis, E. Hauswald, H. Militz, W. Viöl, Plasma treatment of wood-plastic composites to enhance their adhesion properties, Journal of Adhesion Science and Technology 22 (2008) 2025-2037

DOI: 10.1163/156856108x332543

Google Scholar

[4] L. Yang, T. Yan, L. Xinying, Z. Yanhua, D. Mingwei, Study on the surface properties of wood/polyethylene composites treated under plasma, Applied Surface Science 257 (2010) 1112-1118

DOI: 10.1016/j.apsusc.2010.08.032

Google Scholar

[5] I. Novák, V. Pollák, I. Chodák, Study of surface properties of polyolefins modified by corona discharge plasma, plasma processes and polymers 3 (2006) 355-364

DOI: 10.1002/ppap.200500163

Google Scholar

[6] A.A. Fridman, Plasma chemistry, Cambridge University Press, (2008)

Google Scholar

[7] B. Chakraborty, Principles of Plasma Mechanics, New Age International Ltd, (2003)

Google Scholar

[8] M. Pykönen, Influence of Plasma Modification on Surface Properties and Offset Printability of Coated Paper, Åbo Akademi University, (2010)

Google Scholar

[9] E.V. Kuvaldina, V.V. Rybkin, V.A. Titov, T.G. Shikova, D.A. Shutov, Oxidation and degradation of polypropylene in an oxygen plasma, High Energy Chemistry 38/6 (2004) 411-414

DOI: 10.1023/b:hiec.0000048241.43342.f4

Google Scholar

[10] A. Bismarck, W. Brostow, R. Chiu, H.E. Hagg Lobland, K.K.C. Ho, Effects of surface plasma treatment on tribology of thermoplastic polymers, Polymer Engineering and Science 48 (2008) 1971-1976

DOI: 10.1002/pen.21103

Google Scholar

[11] L. Carrino, G. Moroni, W. Polini, Cold plasma treatment of polypropylene surface: A study on wettability and adhesion, Journal of Materials Processing Technology 121 (2002) 373-382

DOI: 10.1016/s0924-0136(01)01221-3

Google Scholar

[12] L. Carrino, W. Polini, L. Sorrentino, Ageing time of wettability on polypropylene surfaces processed by cold plasma, Journal of Materials Processing Technology 153-154 (2004) 519-525

DOI: 10.1016/j.jmatprotec.2004.04.134

Google Scholar

[13] D.H. Williams, I. Fleming, Spectroscopic Methods in Organic Chemistry, fifth Ed., McGraw-Hill Publishing Company, (1995)

Google Scholar

[14] Information on http://www.shimadzu.com/an/ftir/support/faq/5.html

Google Scholar

[15] R.M. Rowell, Handbook of Wood Chemistry and Wood Composites, CRC Press, (2005)

Google Scholar

[16] H. Moghadamzadeh, H. Rahimi, M. Asadollahzadeh, A.R. Hemmati, Surface treatment of wood polymer composites for adhesive bonding, International Journal of Adhesion & Adhesives 31 (2011) 816-821

DOI: 10.1016/j.ijadhadh.2011.08.001

Google Scholar