Los efectos térmicos del Complejo Plutónico de Santa Eulalia (sur de Portugal) en las rocas metaígneas y metasedimentarias encajantes ; Thermal effects of the Santa Eulália Plutonic Complex (southern Portugal) on the meta-igneous and metasedimentary host rocks

The Santa Eulália Plutonic Complex (SEPC) is a late-Variscan granitic body located in the northern part of the Ossa Morena Zone, a inner zone of the Variscan Iberian Massif. The SEPC host rocks are composed of metaigneous and metasedimentary units, from Upper Proterozoic to Paleozoic ages, with a NW-SE structure, cross-cut by the SEPC. The SEPC host rocks, with low grade metamorphism show well preserved primary sedimentary or igneous mineralogical, textural and structural features. The thermal effect induced by the SEPC is restricted to the roof pendants. At N and NE of the SEPC, textures and paragenesis resulting from thermal metamorphism, are not related to the SEPC intrusion but to a previous magmatism, controlled by the NW-SE regional anisotropies. The restriction of the thermal effects to the pluton roof may be caused by a combination of several interrelated factors: higher volume of granitic mass, thermal effect by advection of fluids and longer period of prevalence of high thermal conditions. The geochemical study of SEPC host rocks shows the heterogeneous character and diversity of metasedimentary, igneous and meta-igneous rocks. The whole rock geochemical data indicate that all the metasedimentary lithologies derived from an upper continental crustal source and the igneous and meta-igneous rocks show no evidence of metasomatic effects by the SEPC emplacement.


Introduction
The Ossa Morena Zone (OMZ) is one of the inner zones of the Variscan Iberian Massif, which is considered to be accreted to the Iberian Autochthonous terrane during the Cadomian cycle (Ribeiro et al., 2010).To the north, the OMZ is limited by the Coimbra-Cordoba Shear Zone (CCSZ), considered as a Cadomian suture, reactivated as a Variscan structure.To the south, the suture between the OMZ and the South Portuguese Terrane (SPT) corresponds to the SW-Iberia Variscan suture (Quesada et al., 1994;Fonseca et al., 1999;Ribeiro et al., 2010).
The OMZ is characterized by a poliphase ductile deformation and metamorphism.Two or three Variscan phases are recognizable at OMZ. D 1 structures display WNW-ESE strike and have around 370 Ma in age; D 2 phase is characterized by the development of N-S or NNW-SSE folding and shear; finally, D 3 structures display a NW-SE trend and are dated at 306 Ma (Moita et al., 2005;Ribeiro et al., 2007).The regional structure in the OMZ has a NW-SE orientation.
In the portuguese part of the OMZ several sectors with distinct stratigraphy and structure are identified by Oliveira et al. (1991).From the north to the south the following sectors are recognized: (i) Blastomilonitic Belt, (ii) Alter do Chão-Elvas, (iii) Estremoz-Barrancos, (iv) Montemor-Ficalho and (v) Beja Massif.This study will cover: Blastomilonitic Belt, also known as the Coimbra-Cordoba Shear Zone (CCSZ) and the CCSZ southern margin (Pereira et al., 2013), the Alter do Chão-Elvas sector and although with less detail, the Estremoz-Barrancos sector (Araújo et al., 2013;Fig. 1).
The Santa Eulália Plutonic Complex (SEPC) is a late-Variscan granitic pluton in the SW sector of the Iberian Orogen.This granite with 400 km 2 cross-cuts the regional NW-SE Variscan structures, namely a major high-grade and high-strain shear zone in the contact between two axial geotectonic zones of the Iberian Variscan Belt: Central Iberian Zone (CIZ) and Ossa Morena Zone (OMZ).
In the published geological map (Gonçalves, 1972(Gonçalves, , 1975) ) a regular metamorphic thermal aureole (1.5 to 2 km) surrounding the SEPC is represented.However, the present study highlights the absence of thermal effects in surrounding rocks, except in the roof pendants.
In this study the evaluation of the thermal effects promoted by the SEPC intrusion are presented as a part of a multidisciplinary study.This evaluation is supported mainly by petrographic study, complemented by lithogeochemical data.

Geological setting
The SEPC is a ring igneous complex composed, from the rim to the core, of a medium-to coarsegrained pink granite (G0-group), involving large (kilometric) elongated masses of mafic (gabbroic) to intermediate (granodioritic) rocks, and a central gray medium-grained granite (G1-group) typically biotitic, sometimes showing a slight porphyritic tendency, namely in a few outcrops located near the contact with the peripheral G0-type ring (Lopes et al., 1997(Lopes et al., , 1998;;Menéndez et al., 2006).
The SEPC host rocks show lithological diversity and are composed of igneous and meta-igneous and metasedimentary units, from Upper Proterozoic to Lower Paleozoic ages (Table 1).
The lithostratigraphic units, as well as the major thrust are represented in fig. 1.The area surrounding the SEPC is characterized by a Variscan senestral tectonic regime, which is marked by the NW-SE inducido por el CPSE se limita a los roof pendants.Al N y NE del CPSE, las texturas y paragénesis resultantes del metamorfismo térmico, no están relacionadas con la intrusión del CPSE sino con un magmatismo anterior, controlado por anisotropías regionales NW-SE.
shear zone, namely the Coimbra-Cordoba Shear Zone (CCSZ) and the Alter do Chão shear zone (Fig. 1).The SEPC is limited to NE by the CCSZ and to SW by the Juromenha vertical thrust (Araújo et al., 2013).To the east the SEPC is limited by a major NNE-SSW tectonic structure, the Messejana fault.This fault had a complex tectonic history, from a late Variscan time with left lateral strike-slip fault, to a transtensional fault in Triassic-Jurassic time (Schermerhorn et al., 1978).
It should be noted that the roof pendants consist of lithological fragments of host rocks, located at the roof of the granitic body.These fragments preserve the regional structure of the surrounding rocks.The roof pendants of the SEPC have cartographic expression, namely in the western sector of the granitic massif, in G0 facies, at SW of the Alter do Chão shear zone (Fig. 1).

The meta-igneous and metasedimentary host rocks
The SEPC host rocks are composed of low to highgrade metamorphic rocks.In the NE-sector of Alter do Chão shear zone two lithostratigraphic units are present: a low grade metasedimentary Ediacaran unit The lithostratigraphic units are bounded by major high-strain transcurrent faults placing side by side different rock types and different metamorphic grades.All these units show a regional vertical structure (Fig. 1).

Petrography of host rocks
The petrographic study was based on 18 sampling sites (Fig. 1), located in the surrounding host rocks and in the roof pendants.On these samples 23 thin sections for detailed petrographic analysis have been studied.
On the ESE margin of the SEPC, the pelitic rocks of the Série Negra present anisotropies, which are marked by a compositional sedimentary bedding.The sample SE 6a (phyllite), which is close to the ESE of the SEPC, has a granolepidoblastic texture with a quartz-moscovite matrix and post-kinematic small biotite crystals transverse or mimetic, over the foliation (Fig. 2a).These phyllites intercalated with quartz-phyllites show mineralogy and texture pointing to the transition from chlorite to biotite zone.
On the northern margin of the SEPC, quartz-pelitic rocks of the Série Negra (sample ASM 110), adjacent to the Assumar shear zone and to the Barquete granite, 526 Ma in age (Pereira et al., 2011) show heterogranular granoblastic polygonal texture with deformation lamellae and quartz ribbons typical of dinamothermal metamorphism prior to the intrusion of the SEPC (Fig. 2b).
Metasomatized alkaline rocks, adjacent to the NE contact of the SEPC (sample SE 13) present homogeneous texture with a banded structure preserved.The mineralogy of these rocks is composed of clinopyroxene, scapolite, riebeckite, epidote, perthite potassium feldspar, plagioclase and opaque minerals (Fig. 2c).Their spatial association with ordovician alkaline rocks (Gonçalves, 1971) intrusive in metassedimentary sequence (Série Negra and Carbonate Formation) with NW-SE trending, explain the mineralogy, namely the presence of the Na-amphibole.The compositional banding, the texture and the mineral composition of these rocks (Table 2), with Na-amphiboles suggest that they have resulted from thermal/metasomatic effects of alkaline intrusion over the adjacent carbonate rocks.
Carbonate Formation samples, even when located a few meters from the SEPC, do not show recrystallization due to thermal contact.These samples are impure carbonate rocks and heterogranular calcsilicate rocks, with primary mineralogical and textural features still preserved, namely detrital micas and granular variations which mark the stratification (S 0 ).These features are not observed in the samples of the same unit when located in roof pendants (sample SE 4) where the texture is strongly poligonized and the mineralogical composition is calcite, vesuvianite, tremolite, epidote and opaques (Fig. 2d).
The siliciclastic and the volcanic rocks, both of the Vila Boim Formation and of the Terrugem Volcanic-sedimentary Complex, outcropping at SW of the Alter do Chão shear zone, present metamorphic thermal effects only in the roof pendants.At roof of the SEPC the basic volcanic rock are amphibolitized and the siliciclastic rocks show paragenesis with fibrolite, polygonal quartz, calcite, plagioclase, cordierite, andalusite and quartz "pool" involving the plagioclase with metamorphic texture.This kind of texture indicate partial melting process (Fig. 2e).In the surrounding host rocks, at the west of the SEPC, the phyllites of Terrugem Volcanic-sedimentary Complex (sample ASM 027) show micro-veins with granite affinity composition (2 mm thick) with biotite, quartz, chlorite and apatite.These veins are parallel to the rock structure, marked by stratification and foliation (S 0 //S n ).Neither blastese effects or mineralogical modification were observed in the phyllites adjacent to the veins (Fig. 2f).In phyllites the quartz grains show clastic textures with heterogeneous shape and size.

Geochemistry
The geochemical composition of the host rocks shows very well the diversity of metasedimentary and meta-igneous lithologies (Table 2).The samples studied include basic volcanic (sample SE 2) and pelitic rocks (samples SE 8a, SE 8b) of the Vila  Boim Formation, carbonate (samples SE 4 and SE 9b) and meta-igneous rocks (basic rocks: samples SE 9a and SE 9d and acid rocks: sample SE 9c) intercalated or intrusive in the Carbonate Formation, pelitic rocks of Terrugem Volcanic-sedimentary Complex ( sample SE 7), amphibolites (sample SE 12a) of the Série Negra and finally banded alkaline rocks (samples SE 11, SE 12b) and metasomatized alkaline rocks (SE 13) respectively intruded or intercalated in the Série Negra.
The Rare Earth Elements (REE) patterns were plotted in separeted graphs according to the sedimentary or igneous character of the samples (Fig. 3a and Fig. 3b).
The pelitic and carbonate metasedimentary rocks show a typical continental crust REE pattern with high LREE fractionation (La/Sm = 1.06-10.56),marked negative Eu anomaly and low HREE fractionation (Gd/Yb = 1.38-2.57),but with different ∑REE values.The carbonate rocks show the lower values of ∑REE, and the more pelitic rocks (samples SE 7 and SE 8a) show the highest values (Fig. 3a).The meta-igneous rocks present quite different REE patterns (Fig. 3b

Thermal effects induced by the SEPC
The lithological and metamorphic diversity of the host rocks imply different degrees of evidence for thermal effects of the SEPC.Undoubtedly the pelitic rocks and impure carbonate lithologies (limestones and dolomitic limestones) of low grade are the most favorable to constraint contact effects.It is much more difficult the discrimination of these effects on igneous rocks or high grade metamorphic rocks.
In the pelitic and impure carbonate lithologies surrounding the SEPC, the mineralogical, textural and structural features of the very-low to low grade metamorphic conditions previous to the SEPC intrusion are preserved, namely the sedimentary bedding.The thermal effects of this intrusion are expressed only by very small post-kinematic crystals of biotite, transverse or mimetic, over the foliation in the pelitic  Evenson et al., 1978).
Estudios Geológicos, 70(2), julio-diciembre 2014, e016, ISSN-L: 0367-0449.doi: http://dx.doi.org/10.3989/egeol.41730.322rocks (Fig. 2a) and by a slightly recristalization of the calcite of cabonate rock matrix.These features are well demonstrated in the samples SE 6a, SE 6b and SE 6c collected very close to the ESE margin of the SEPC.The same evidence is present in the sample ASM 027, located in the western margin of the SEPC.
In the alkaline host rocks, intrusive in the metasedimentary rocks of the Série Negra, the igneous primary structure, texture and high-T minerals are preserved, namely the compositional banding typical of a primary magmatic differentiation.The petrographic features of the alkaline and metasomatized alkaline rocks and their geochemical composition point to the absence of thermal/metasomatization effects of the SEPC on these rocks.The metasomatization present in the sample SE 13 has resulted from the contact between the alkaline rock and the adjacente carbonate rock.The adjacent calc-silicate rocks present mineralogical composition consistent with thermal/metasomatic effets related to the alkaline rock intrusion.So, the lithologies of N and NE margins of the SEPC show thermal metamorphic textures, structural anisotropies and paragenesis, which are not related to the SEPC intrusion but to a previous magmatism.
On the other hand all the lithologies present in the roof pendants, namely pelitic, carbonate and basic volcanic rocks, exhibit a strong thermal effect, without metasomatic evidence.The occurrence of thermal effects restricted to the pluton roof may be caused by a combination of several interrelated factors: the volume ratio granite/host rocks is much higher in the roof pendants than in the surrounding host rocks, higher volume of granitic mass, thermal effect by advection of fluids, longer period of prevalence at elevated thermal conditions.
The previous very-low to low metamorphic grade of the host rocks of the SEPC, indicates an intrusion in a shallow and cold crustal level, and thus implying a thermal shock.However the absence of lateral thermal effects could be explained by quick cooling and the low volume ratio granite/rock wall.

Conclusions
The SEPC is a late-Variscan granitic body located in the northern part of the Ossa Morena Zone.The SEPC host rocks are composed of igneous, metaigneous, and metasedimentary units, from Upper Proterozoic to Paleozoic ages, with a NW-SE structure.The SEPC host rocks, show very-low to high grade metamorphism.Those with very-low to low grade metamorphism present primary sedimentary or igneous mineralogical, textural and structural features well preserved.Both at east or at west, the host rocks comprise phyllite and quartz-phyllite, in chlorite zone conditions, without any thermal effects even at short metric distance from the contact.
The thermal effects of the SEPC intrusion on the igneous and meta-igneous rocks (granites, migmatites, gabbros, alkaline rocks, basic and acid volcanic rocks) are not evident, because the mineralogy and texture of these rocks are stable at high temperature.At N and NE of the SEPC, textures and paragenesis of high-T are not related to the SEPC intrusion but to a previous magmatism (Barquete granite and peralkaline rocks), controlled by the NW-SE regional anisotropies.These rocks show evidences of dynamo thermal metamorphism previous to SEPC.
The restriction of the thermal effects to the pluton roof may be caused by a combination of several interrelated factors: higher volume of granitic mass, thermal effect by advection of fluids, longer period of prevalence of high thermal conditions.
The geochemical study of the SEPC host rocks shows the heterogeneous character and diversity of metasedimentary, igneous and meta-igneous rocks.The whole rock geochemical data indicate that all the metasedimentary lithologies derived from an upper continental crustal source.The geochemical composition of the igneous and meta-igneous rocks do not show evidence of metasomatic effects by the SEPC emplacement.
These data suggest that the thermal effects of the SEPC in the host rocks are mostly restricted to the roof pendants.
): the alkaline rocks have low or null Eu anomaly, a high fractionation of LREE and low fractionation of HREE.The basic rocks have a flat LREE and HREE patterns without Eu anomaly (samples SE 2 and SE 12a), and finally, the acid igneous rocks show a fairly steep LREE and flat HREE patterns.