Critical review on use of different types of bio-diesel as sustainable fuel for Internal Combustion Engines

Received Date: Jul 30, 2021 / Accepted Date: Aug 10, 2021/ Published Date: Aug 13, 2021 Abstract World’s major transportation energy requirement cannot be met alone by use of fossil fuel based petroleum products. So, as a supplement and sustainable energy usage scope and production of bio diesel is highlighted in this article. Bio-diesel can also be the part of renewable biomass sources available freely on this planet. Use of bio diesel can be made successfully by minor modification in existing transportation vehicles easily. Still further research is going on for to overcome the limitations regarding use of bio diesel in I.C. engines like as piston ring sticking, injector chocking etc. due to its high viscosity. The present work focuses on use of bio diesel in terms of its performance characteristics in IC Engines.


Introduction
Renewable and alternative energy sources are becoming more demanding and necessary due to increases in crude oil prices and exhaust gas emissions due to fossil fuels throughout the world. Vegetable oils are widely used for various purposes in industry to complete its requirement for energy in different applications. Due to lower sulphur content and massive source for renewable resource makes it evitable for substantial energy production requirements for transportation vehicles. Previous test results for use of vegetable oil in transportation engines were found satisfactory. This makes it promising alternative to conventionally used fossil fuel based petroleum products. The use of biodiesel in engine usage is limited by its excessive viscosity. To overcome this problem mainly thermochemical treatment is provided to reduce viscosity to suit engine requirements. Chemical treatment can be further explored to methods like pyrolysis, micro emulsion, transesterification, dilution etc. Mostly use of vegetable oil in blended along with main fuel to minimal fuel processing and limited engine modification [1][2][3]. A variety of vegetable oils such as those from soybean, rapeseed, sunflower, jatropha -carcass, palm, and cottonseed etc. have been widely investigated for production of biodiesel. Rapeseed oil and some other vegetable oils when transformed to their methyl esters have many characteristics such as density, viscosity, energy content, and Page: 2 www.raftpubs.com cetane number close to that of diesel. Recently non-edible oil produced from jatropha-curcass seeds has gained interest as this plant can be easily grown on wastelands [4][5].
The vegetable oil esters are practically free of sulphur and have a high cetane number generally in the range 46 to 60 depending upon the feedstock. The cetane number of methyl esters tends to be slightly lower than of ethyl or higher esters. Biodiesel from saturated feed stocks such as animal fat and recycled restaurant cooking fats will generally have a higher cetane number than the esters of oils high in poly-unsaturates such as soybean oil. Due to presence of oxygen, biodiesel have a lower calorific value than the diesel fuels [6][7]. The emission studies show that the use of biodiesel results in reduction of CO, HC and PM, but slight increase in NOx emissions. Reduction in CO emission could probably be attributed to presence of oxygen in the fuel molecule. Decomposition of biodiesel produces a variety of oxygenated hydrocarbons in addition to hydrocarbons. Response of the standard HC measurement technique, the heated flame ionization detector is different for the methyl esters than HC emission and this could be partly responsible for the difference in HC emissions between the normal diesel fuels and biodiesel. The methyl esters have a lower compressibility, which results in advance of dynamic injection timing.

Composition and Properties of Bio-Fuel
Fats and oils (lipids) consist of 95-98% triglycerides. Minor constituents present in oils include free fatty acids, mono-and diglycerides, phospholipids, tocopherols, sterols, natural colouring agents as well as more or less volatile odorous compounds. Triglycerides are composed of a glycerol molecule esterified with three similar or different fatty acid molecules.  Page: 3 www.raftpubs.com Biodiesel compared to diesel. Change in injection timing and differences in cetane number and combustion characteristics and particulate emissions are observed to be significantly lower with biodiesel compare to diesel fuels. Volumetric fuel consumption with biodiesel is higher than diesel due to its lower heating value. An increase of 10-11% in fuel consumption compared to diesel may be expected when comparing their heating values. Some twenty fatty acids are found in nature and their numerous possible combinations with the three alcohol functions of the glycerol produce a wide variety of triglycerides and therefore of oils. Generally, biomass-derived feed stocks for the production of liquid bio-fuels can be classified into the following three categories according to the source, i.e. triglyceride-based biomass, starch-and sugar-derived biomass, and cellulosic biomass. A variety of liquid biofuels can be produced from triglycerides based biomass such as vegetable oils, animal fats, waste cooking oils and microalgae oils as shown in Figure 1 [8][9][10]. Vegetable oils first developed as fuel for direct use, after more or less deep purification. The oil most frequently produced from rapeseed and sunflower, are composed of fatty acids with carbon chains (18 carbon atoms) including three chains globally longer than those of the hydrocarbons found in diesel. These oils have high molecular weights, about 0.88 kg/mole, density above 910 kg/m 3 , and low volatility. On heating, they generally crack at temperatures in the region of 300°C. The main characteristics of vegetable oils appear in Table 1 [11][12][13][14][15]. The usage of vegetable oils as diesel fuel depends on world market prices for mineral products and is therefore of special interest at present only for countries with a large excess of vegetable oil production. The measurement of density, viscosity and carbon residue is critical before using vegetable oil in transportation engine for its purity. The density of vegetable oil is ranges from 900 and 960 kg/m 3 [16][17][18] while the viscosity of vegetable oil is much higher than conventional diesel fuel.
The high viscosity of vegetable oil causes detrimental effects like clogging injection pump, filter and fuel injector nozzle etc. resulted to lower injection rate, poor ignition property and incomplete combustion. Thermodynamic efficiency decreases drastically and also substantial increase in proportions of soot particles in the exhaust emission.
Viscosity is a rapid indicator of fuel quality before use, especially if the nature of the feedstock is not well known, or if the oil could have been deteriorated or polymerized during storage. As Figure 2 [19][20] indicates, the viscosity of pure SVO is much higher than that of diesel fuel at normal operating temperatures. This can cause premature wear of fuel pumps and injectors and can also dramatically alter the structure of the fuel spray coming out of the injectors to increase droplet size, decrease spray angle, and increase spray penetration.  Page: 4 www.raftpubs.com

Effect of Bio-Fuel on combustion
As biodiesel is produced from vegetable oils or animal fats, its use has been promoted as a means for reducing greenhouse gas CO2 emissions that would otherwise be produced from the combustion of Petroleum-based fuels. The total impact that biodiesel could have on global warming would be a function not just of its combustion products but also of the emissions associated with the full biodiesel production and consumption lifecycle. On an average the carbon content on mass basis of plant-based biodiesel is 77.8% and of animal fat based biodiesel is 76.1% compared to 86.7% for the Petroleum based diesel [21]. Since biodiesel is free from sulfur hence less sulfate emissions and particulate reduction is reported in the exhaust. Due to near absence of sulfur in biodiesel, it helps reduce the problem of acid rain due to transportation fuels. Higher thermal efficiency, lower BSFC and higher exhaust temperatures are reported for all blends of biodiesel compared to mineral diesel Biodiesel is oxygenated fuel (hence more complete combustion) and causes lesser particulate formation and emission. This is also due to oxygenated nature of biodiesel where more oxygen is available for burning and reducing hydrocarbon emissions exhaust as shown in the Figure 3 [22].  Page: 5 www.raftpubs.com The biodiesel have a slightly higher carbon content per unit energy (2.068 kg/100MJ) than the conventional diesel (2.042 kg/100MJ) and thus may be expected to give higher CO2 emissions on combustion. The measured data however, suggest that the combustion generated CO2 from biodiesel and conventional diesel are substantially similar as shown in Figure 4 [23]. The cost of vegetable oil production is much higher than the conventional fuel distillation process and refining. So, this green energy production requires substantial reduction in fuel cost taxation for to make it cost comparable against conventional fuels [24]. The production cost can be lowered further by addition of alternatives like non edible oils such as karanja, jatrpha, mahua etc. are easily available at low cost in different parts of continental places on earth. Moreover, use of waste frying oils also be a potential source of biomass for vegetable oil production in this fast food era in countries like USA, Chine, India etc. This also eliminates expenditure incurred on waste water treatment in sewerage plants and its further recycling operations too.

Conclusions
Use of vegetable oil for biodiesel production having great potential in renewable energy as plant can be growing every year. They are termed a source of green energy as it does not having harmful sulphur content in it. The main problem of using vegetable oils in diesel engines is the high viscosities of such fuels. Due to the need to adapt the combustion time, use of vegetable oils in diesel engines generally leads to higher CO, HC and PM. In contrast, due to their slower combustion and lower temperatures in the combustion chamber, vegetable oils reduce NOx emissions. While vegetable oils represent an alternative fuel, they will continue to present risks related to their intrinsic characteristics, which neither car nor agricultural tractor and machinery manufactures are willing to assume. The obtained results prove that the uses of vegetable oil as biodiesel are good alternative to conventional diesel fuel as petroleum based fossil deposits were found for the limited period.