초록

In this paper, we successfully synthesized Ti-coated Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode and microstructure and electrochemicalperformances for high-energy lithium-ion battery are investigated. The TiO2-coated LiNi0.8Co0.1Mn0.1O2 delivers excellent cationmixing and there is no big difference in morphology between pristine and TiO2 coated LiNi0.8Co0.1Mn0.1O2. The TiO2-coatedLiNi0.8Co0.1Mn0.1O2 has higher electrochemical performances (initial discharge capacity : 201.3 mAh g-1, rate capability : 90.5%at 4.0 C and cyclability : 79.4% after 100 cycles). It can be explained by the positive role of TiO2 layer on the surface ofLiNi0.8Co0.1Mn0.1O2.

키워드

Ti-coated Ni-rich layered LiNi0.8Co0.1Mn0.1O2, microstructure, cation mixing, higher electrochemical performances, TiO2 layer

참고문헌(3)open

  1. [학술지] 석정원 / 2019 / Effect of LiPO2F2 Electrolyte Additive on Surface Electrical Properties of LiNi0.6Co0.2Mn0.2O2 Cathode / Transactions on Electrical and Electronic Materials 20 (6) : 548 ~ 553

  2. [학술지] Sung-Joo Jo / 2020 / Enhanced the electrochemical performances of Ni-rich LiNi0.8Co0.1Mn0.1O2 cathode by ZrO2 coating / Journal of Ceramic Processing Research 21 (6) : 731 ~ 735

  3. [학술지] 이승환 / 2020 / Zirconium doped LiNi0.91Co0.06Mn0.03O2cathode as a superior cathode for lithium ion batteries / Journal of Ceramic Processing Research 21 (5) : 592 ~ 595