초록

In this work, strontium titanate samples were prepared starting from SrCO3 and TiO2 powders mixture. Raw materials wereactivated mechanically in a planetary mill and then calcined at different temperatures (900 to 1300 oC). Powders after grindingwere analyzed by differential thermal analysis in order to follow the carbonate decomposition. On the other hand, samplesresulting from heat treatment were characterized by XRD, SEM and electrical measurements. XRD analysis determines thatSrTiO3 synthetized presents the cubic structure of perovskite. Complete reaction for SrTiO3 compound formation occurs at1200 oC. SEM observations indicate the presence of a microstructure with very small gran size and consequently a largenumber of grain boundaries. Electrical measurements suggest the formation of a material with high insulating capacity. Withthis evidence, it can be concluded that solid state reactions activated mechanically, proved to be an effective way to fabricatestrontium titanate compound with very fine microstructure and high insulating behavior.

키워드

SrTiO3 compound, Dielectric constant, Solid state reactions, Mechanical activation.

참고문헌(2)open

  1. [단행본] B. Perovskites / 2010 / Structure, Properties and Uses, Series:Chemical Engineering Methods and Technology / Nova Science Publishers : 1

  2. [단행본] A.K. Galwey / 1999 / Thermal Decomposition of Ionic Solids / Elsevier : 1