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Kobalt Katkılı Kalsiyum Manganez Oksit Numunelerin Sentez ve Karakterizasyonu

Yıl 2020, Cilt: 7 Sayı: 2, 960 - 970, 30.12.2020

Tankut Ateş Süleyman Köytepe Omer Kaygılı

https://doi.org/10.35193/bseufbd.722519

Öz

Bu çalışmada, kobalt katkılı kalsiyum manganez oksit numunelerinin faz bileşimleri, kristal yapıları, yüzey morfolojileri ve termal özellikleri karakterize edildi. Co miktarının bu oksit yapı üzerindeki etkileri belirlendi. X-ışını kırınımı (XRD) sonuçları, kalsiyum manganez oksit fazlarının oluşumuna işaret etmektedir. Fourier dönüşümlü kızılötesi (FTIR) analizleri, her bir numune için peroksit yapısının oluşumunu doğrulamaktadır. Termal analiz sonuçları, üretilen numunelerin termal olarak kararlı olduklarını göstermektedir. Numunelerin taramalı elektron mikroskobu (SEM) gözlemleri ve enerji dağılımlı X-ışını (EDX) analizleri, Co katkısının morfolojiye etki ettiğini ve kalsiyum manganez oksit yapıya nüfuz ettiğini desteklemektedir.

Anahtar Kelimeler

Kalsiyum Manganez Oksit X-Işını Kırınımı (XRD) Morfoloji Co Katkılama

Kaynakça

  • Erkişi, A. (2015). Bazı ABO3 Tipi Perovskite Yapıdaki Oksit Kristallerin Yapısal, Mekanik, Elektronik ve Manyetik Özelliklerinin Yoğunluk Fonksiyoneli Teorisi ile İncelenmesi. Doktora Tezi, Kırıkkale Üniversitesi, Fen Bilimleri Enstitüsü, Kırıkkale.
  • Coşkun, F.M. (2016). Katkılı Perovskit Güneş Pillerinin Üretimi ve Fotovoltaik Karakterizasyonu.Doktora Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Erzurum.
  • Paszkowicz, W., Piętosa, J., Woodley, S.M., Dłużewski, P.A., Kozłowski, M., & Martin, C.(2010). Lattice parameters and orthorhombic distortion of CaMnO3.Powder Diffraction, 25(1), 46-59.
  • Pektaş, M. (2011). La0.67Ca0.33MnO3 Alaşımında Ag katkılamanın İletkenlik ve Manyetik Özellikleri Üzerine Etkisi. Yüksek Lisans Tezi, İnönü Üniversitesi, Fen Bilimleri Enstitüsü, Malatya.
  • Zhang, F.P., Zhang, X., Lu, Q.M., Zhang, J.X., Liu,Y.Q., Fan,R.F.,&Zhang, G.Z.(2011). Doping induced electronic structure and estimated thermoelectric properties of CaMnO3 system.Physica B, 406, 1258-1262.
  • Zhang, F.P., Zhang, X., Lu,Q.M., Zhang,J.X., & Liu,Y.Q. (2011). Electronic structure and thermal properties of doped CaMnO3 systems.Journal of Alloys and Compounds, 509, 4171-4175.
  • Dukic, J., Boskovic, S.,& Matovic, B.(2009). Crystal structure of Ce-doped CaMnO3 perovskite.Ceramics International, 35, 787-790.
  • Wang, K., Jiang, W., Chen, J.N.,& Huang, J. Q.(2016). Study of the electronic structure and half-metallicity of CaMnO3/BaTiO3 superlattice.Superlattices and Microstructures, 97, 116-124.
  • Hamdad, N.,& Bouhafs, B.(2010). Theoretical analysis of the spin effect on the electronic and magnetic properties of the calcium manganese oxide CaMnO3: GGA+U calculation.Physica B, 405, 4595-4606.
  • Boskovic, S., Dukic, J., Matovic, B., Zivkovic, L. J., Vlajic, M.,& Krstic, V.(2008). Nanopowders properties and sintering of CaMnO3 solid solutions.Journal of Alloys and Compounds, 463, 282–287.
  • Pandey, K., Singh, D., Gupta, S.K., Yadav, P., Sonvane, Y., Lukačević, I., Kumar, M., Kumar, M.,& Ahuja, R.(2018). Improving electron transport in the hybrid perovskite solar cells using CaMnO3-based buffer layer.Nano Energy, 45, 287-297.
  • Ferreira, N.M., Neves, N.R., Ferro, M.C., Torres, M.A., Madre, M.A., Costa, F.M., Sotelo, A.,& Kovalevsky, A. V.(2019). Growth rate effects on the thermoelectric performance of CaMnO3-based ceramics.Journal of the European Ceramic Society, 39, 4184-4188.
  • Berbeth Mary, S., Francis, M., Sathe, V.G., Ganesan, V.,& Leo Rajesh, A.(2019). Enhanced thermoelectric property of nanostructured CaMnO3 by sol-gel hydrothermal method.Physica B: Physics of Condensed Matter, 575, 411707.
  • Liu, K.K., Liu, Z.Y., Zhang, F.P., Zhang, J.X., Yang, X.Y., Zhang, J.W., Shi, J.L., Ren, G., He, T.W.,& Duan, J. J.(2019). Improved thermoelectric performance in Pr and Sr Co-doped CaMnO3 materials.Journal of Alloys and Compounds, 808, 151476.
  • Zhang, F.P., Lu, Q.M., Zhang, X.,& Zhang, J. X.(2013). Electrical transport properties of CaMnO3 thermoelectric compound: a theoretical study.Journal of Physics and Chemistry of Solids, 74, 1859-1864.
  • Baranovskiy, A., Graff, A., Klose, J., Mayer, J.,& Amouyal, Y.(2018). On the origin of vibrational properties of calcium manganate based thermoelectric compounds.Nano Energy, 47, 451-462.
  • Baranovskiy, A.,& Amouyal, Y.(2016). Structural stability of calcium-manganate based CaO(CaMnO3)m (m = 1, 2, 3, ∞) compounds for thermoelectric applications.Journal of Alloys and Compounds, 687, 562-569.
  • Phaga, P., Vora-Ud, A.,& Seetawan, T.(2012). Invention of Low Cost Thermoelectric Generators.Procedia Engineering, 32, 1050–1053.
  • Nakhowong, R.(2016). Preparation and characterization of calcium manganese oxide (CaMnO3) nanofibers by electrospinning.Materials Letters, 163, 222-225.
  • Kabir, R., Tian, R., Zhang, T., Donelson, R., Teck Tan, T.,& Li, S.(2015). Role of Bi doping in thermoelectric properties of CaMnO3.Journal of Alloys and Compounds, 628, 347-351.
  • Zhu, Y., Wang, C., Wang, H., Su, W., Liu, J.,& Li, J.(2014). Influence of Dy/Bi dual doping on thermoelectric performance of CaMnO3 ceramics.Materials Chemistry and Physics, 144, 385-389.
  • Kara, F., Kurban, M., &Coşkun, B. (2020). Evaluation of electronic transport and optical response of two-dimensional Fe-doped TiO2 thin films for photodetector applications.Optik, 210, 164605.
  • Kurban, M. (2018) Electronic structure, optical and structural properties of Si, Ni, B and N-doped a carbon nanotube: DFT study.Optik, 172, 295-301.
  • Zhan, B., Lan, J., Liu, Y., Lin, Y., Shen, Y.,& Nan, C.(2014). High Temperature Thermoelectric Properties of Dy-doped CaMnO3 Ceramics.J. Mater. Sci. Technol., 30(8), 821-825.
  • Park, J.W., Kwak, D.H., Yoon, S.H.,& Choi, S. C.(2009). Thermoelectric properties of Bi, Nb co-substituted CaMnO3 at high temperature.Journal of Alloys and Compounds, 487, 550–555.
  • Cullity, B. D. (1978).Elements of X–ray Diffraction 2nd Ed. Addison–Wesley Publishing Company, Massachusetts, 102.
  • Nandan, K. R., & Ruban Kumar, A. (2019). Structural and electrical properties ofCa0.9Dy0.1MnO3 prepared by sol-gel technique. Journal of Materials Research and Technology, 8(3), 2996-3003.
  • Hassan, A. M., Abd El-Wahab, H., Mohy Eldin, A., Naser, A. M., Fouad, O. A., & Wahba, O. A. G. (2011). Synthesis, Characterization and Application ofMixed Metal OxidesPart Ι= CaMnO3, Ca2Cr2O5, CaSb2O6. Egypt. J. Chem., 54(4), 447-461.
  • Melo Jorge, M.E., Correia dos Santos, A., & Nunes, M.R. (2001). Effects of synthesis method on stoichiometry, structure and electrical conductivity of CaMnO3-δ. International Journal of Inorganic Materials, 3, 915-921.
  • Mastronardo, E., Qian, X., Coronado, J. M., & Haile, S. (2019). Fe-doped CaMnO3 for thermochemical heatstorage application. AIP Conference Proceedings, 2126, 210005-1 – 210005-8.
  • Goldyreva, E. I., Leonidov, I. A., Patrakeev M. V., & Kozhevnikov, V. L. (2012). Oxygen non-stoichiometry and defect equlibria in CaMnO3−δ. Journal of Solid State Electrochemistry, 16, 1187-1191.

Synthesis and Characterization of Cobalt-Doped Calcium Manganese Oxide Samples

Yıl 2020, Cilt: 7 Sayı: 2, 960 - 970, 30.12.2020

Tankut Ateş Süleyman Köytepe Omer Kaygılı

https://doi.org/10.35193/bseufbd.722519

Öz

In this study, the phase compositions, crystal structures, surface morphologies, and thermal properties of cobalt-doped calcium manganese oxide samples were characterized. The effects the amount of Co on this oxide structure were determined. X-ray diffraction (XRD) analysis results indicate the formation of the calcium manganese oxide phases. Fourier transform infrared (FTIR) analyses verify the formation of the perovskite structure for each sample. Thermal analysis results show that the as-produced samples are thermally stable. The scanning electron microscope (SEM) observations and energy dispersive X-ray (EDX) analyses support that the Co-doping affects the morphology and influences the calcium manganese oxide structure.

Anahtar Kelimeler

Calcium Manganese Oxide X-Ray Diffraction (XRD) Morphology Co-Doping

Kaynakça

  • Erkişi, A. (2015). Bazı ABO3 Tipi Perovskite Yapıdaki Oksit Kristallerin Yapısal, Mekanik, Elektronik ve Manyetik Özelliklerinin Yoğunluk Fonksiyoneli Teorisi ile İncelenmesi. Doktora Tezi, Kırıkkale Üniversitesi, Fen Bilimleri Enstitüsü, Kırıkkale.
  • Coşkun, F.M. (2016). Katkılı Perovskit Güneş Pillerinin Üretimi ve Fotovoltaik Karakterizasyonu.Doktora Tezi, Atatürk Üniversitesi, Fen Bilimleri Enstitüsü, Erzurum.
  • Paszkowicz, W., Piętosa, J., Woodley, S.M., Dłużewski, P.A., Kozłowski, M., & Martin, C.(2010). Lattice parameters and orthorhombic distortion of CaMnO3.Powder Diffraction, 25(1), 46-59.
  • Pektaş, M. (2011). La0.67Ca0.33MnO3 Alaşımında Ag katkılamanın İletkenlik ve Manyetik Özellikleri Üzerine Etkisi. Yüksek Lisans Tezi, İnönü Üniversitesi, Fen Bilimleri Enstitüsü, Malatya.
  • Zhang, F.P., Zhang, X., Lu, Q.M., Zhang, J.X., Liu,Y.Q., Fan,R.F.,&Zhang, G.Z.(2011). Doping induced electronic structure and estimated thermoelectric properties of CaMnO3 system.Physica B, 406, 1258-1262.
  • Zhang, F.P., Zhang, X., Lu,Q.M., Zhang,J.X., & Liu,Y.Q. (2011). Electronic structure and thermal properties of doped CaMnO3 systems.Journal of Alloys and Compounds, 509, 4171-4175.
  • Dukic, J., Boskovic, S.,& Matovic, B.(2009). Crystal structure of Ce-doped CaMnO3 perovskite.Ceramics International, 35, 787-790.
  • Wang, K., Jiang, W., Chen, J.N.,& Huang, J. Q.(2016). Study of the electronic structure and half-metallicity of CaMnO3/BaTiO3 superlattice.Superlattices and Microstructures, 97, 116-124.
  • Hamdad, N.,& Bouhafs, B.(2010). Theoretical analysis of the spin effect on the electronic and magnetic properties of the calcium manganese oxide CaMnO3: GGA+U calculation.Physica B, 405, 4595-4606.
  • Boskovic, S., Dukic, J., Matovic, B., Zivkovic, L. J., Vlajic, M.,& Krstic, V.(2008). Nanopowders properties and sintering of CaMnO3 solid solutions.Journal of Alloys and Compounds, 463, 282–287.
  • Pandey, K., Singh, D., Gupta, S.K., Yadav, P., Sonvane, Y., Lukačević, I., Kumar, M., Kumar, M.,& Ahuja, R.(2018). Improving electron transport in the hybrid perovskite solar cells using CaMnO3-based buffer layer.Nano Energy, 45, 287-297.
  • Ferreira, N.M., Neves, N.R., Ferro, M.C., Torres, M.A., Madre, M.A., Costa, F.M., Sotelo, A.,& Kovalevsky, A. V.(2019). Growth rate effects on the thermoelectric performance of CaMnO3-based ceramics.Journal of the European Ceramic Society, 39, 4184-4188.
  • Berbeth Mary, S., Francis, M., Sathe, V.G., Ganesan, V.,& Leo Rajesh, A.(2019). Enhanced thermoelectric property of nanostructured CaMnO3 by sol-gel hydrothermal method.Physica B: Physics of Condensed Matter, 575, 411707.
  • Liu, K.K., Liu, Z.Y., Zhang, F.P., Zhang, J.X., Yang, X.Y., Zhang, J.W., Shi, J.L., Ren, G., He, T.W.,& Duan, J. J.(2019). Improved thermoelectric performance in Pr and Sr Co-doped CaMnO3 materials.Journal of Alloys and Compounds, 808, 151476.
  • Zhang, F.P., Lu, Q.M., Zhang, X.,& Zhang, J. X.(2013). Electrical transport properties of CaMnO3 thermoelectric compound: a theoretical study.Journal of Physics and Chemistry of Solids, 74, 1859-1864.
  • Baranovskiy, A., Graff, A., Klose, J., Mayer, J.,& Amouyal, Y.(2018). On the origin of vibrational properties of calcium manganate based thermoelectric compounds.Nano Energy, 47, 451-462.
  • Baranovskiy, A.,& Amouyal, Y.(2016). Structural stability of calcium-manganate based CaO(CaMnO3)m (m = 1, 2, 3, ∞) compounds for thermoelectric applications.Journal of Alloys and Compounds, 687, 562-569.
  • Phaga, P., Vora-Ud, A.,& Seetawan, T.(2012). Invention of Low Cost Thermoelectric Generators.Procedia Engineering, 32, 1050–1053.
  • Nakhowong, R.(2016). Preparation and characterization of calcium manganese oxide (CaMnO3) nanofibers by electrospinning.Materials Letters, 163, 222-225.
  • Kabir, R., Tian, R., Zhang, T., Donelson, R., Teck Tan, T.,& Li, S.(2015). Role of Bi doping in thermoelectric properties of CaMnO3.Journal of Alloys and Compounds, 628, 347-351.
  • Zhu, Y., Wang, C., Wang, H., Su, W., Liu, J.,& Li, J.(2014). Influence of Dy/Bi dual doping on thermoelectric performance of CaMnO3 ceramics.Materials Chemistry and Physics, 144, 385-389.
  • Kara, F., Kurban, M., &Coşkun, B. (2020). Evaluation of electronic transport and optical response of two-dimensional Fe-doped TiO2 thin films for photodetector applications.Optik, 210, 164605.
  • Kurban, M. (2018) Electronic structure, optical and structural properties of Si, Ni, B and N-doped a carbon nanotube: DFT study.Optik, 172, 295-301.
  • Zhan, B., Lan, J., Liu, Y., Lin, Y., Shen, Y.,& Nan, C.(2014). High Temperature Thermoelectric Properties of Dy-doped CaMnO3 Ceramics.J. Mater. Sci. Technol., 30(8), 821-825.
  • Park, J.W., Kwak, D.H., Yoon, S.H.,& Choi, S. C.(2009). Thermoelectric properties of Bi, Nb co-substituted CaMnO3 at high temperature.Journal of Alloys and Compounds, 487, 550–555.
  • Cullity, B. D. (1978).Elements of X–ray Diffraction 2nd Ed. Addison–Wesley Publishing Company, Massachusetts, 102.
  • Nandan, K. R., & Ruban Kumar, A. (2019). Structural and electrical properties ofCa0.9Dy0.1MnO3 prepared by sol-gel technique. Journal of Materials Research and Technology, 8(3), 2996-3003.
  • Hassan, A. M., Abd El-Wahab, H., Mohy Eldin, A., Naser, A. M., Fouad, O. A., & Wahba, O. A. G. (2011). Synthesis, Characterization and Application ofMixed Metal OxidesPart Ι= CaMnO3, Ca2Cr2O5, CaSb2O6. Egypt. J. Chem., 54(4), 447-461.
  • Melo Jorge, M.E., Correia dos Santos, A., & Nunes, M.R. (2001). Effects of synthesis method on stoichiometry, structure and electrical conductivity of CaMnO3-δ. International Journal of Inorganic Materials, 3, 915-921.
  • Mastronardo, E., Qian, X., Coronado, J. M., & Haile, S. (2019). Fe-doped CaMnO3 for thermochemical heatstorage application. AIP Conference Proceedings, 2126, 210005-1 – 210005-8.
  • Goldyreva, E. I., Leonidov, I. A., Patrakeev M. V., & Kozhevnikov, V. L. (2012). Oxygen non-stoichiometry and defect equlibria in CaMnO3−δ. Journal of Solid State Electrochemistry, 16, 1187-1191.
Toplam 31 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Bölüm Makaleler
Yazarlar

Tankut Ateş 0000-0002-4519-2953

Süleyman Köytepe 0000-0002-4788-278X

Omer Kaygılı 0000-0002-2321-1455

Yayımlanma Tarihi 30 Aralık 2020
Gönderilme Tarihi 17 Nisan 2020
Kabul Tarihi 22 Ağustos 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 7 Sayı: 2

Kaynak Göster

APA Ateş, T., Köytepe, S., & Kaygılı, O. (2020). Kobalt Katkılı Kalsiyum Manganez Oksit Numunelerin Sentez ve Karakterizasyonu. Bilecik Şeyh Edebali Üniversitesi Fen Bilimleri Dergisi, 7(2), 960-970. https://doi.org/10.35193/bseufbd.722519