Chemical Bath Deposition of ZnO/ZnGa2O4 Core–Shell Nanowire Heterostructures Using Partial Chemical Conversion

The development of innovative heterostructures made of ZnO nanowires is of great interest for enhancing the performances of many devices in the fields of optoelectronics, photovoltaics, and energy harvesting. We report an original fabrication process to form ZnO/ZnGa2O4 core–shell nanowire heterostructures in the framework of the wet chemistry techniques. The process involves the partial chemical conversion of ZnO nanowires grown via chemical bath deposition into ZnO/ZnGa2O4 core–shell nanowire heterostructures with a high interface quality following their immersion in an aqueous solution containing gallium nitrate heated at a low temperature. The double-step process describing the partial chemical conversion relies on successive dissolution and reaction mechanisms. The present finding offers the possibility to fabricate ZnO/ZnGa2O4 core–shell nanowire heterostructures at low temperatures and over a wide variety of substrates with a large surface area, which is attractive for nanostructured solar cells, deep-UV photodetectors, and piezoelectric devices.


Introduction
As a compound semiconductor with attractive properties, zinc gallate, also known as zinc gallium oxide (ZnGa 2 O 4 ), has received increasing interest in recent years.Its wideband gap energy (4.4-5.0 eV), its relatively high electron mobility (up to 100 cm 2 •V −1 •s −1 ), and its high stability make it an interesting candidate for deep UV solar-blind photodetectors [1].ZnGa 2 O 4 crystallizes into a cubic spinel structure at ambient conditions, in which the divalent Zn cations occupy 1/8 of the tetrahedral sites, while the trivalent Ga cations occupy 1/2 of the octahedral sites in the normal spinel crystal [1].ZnGa 2 O 4 further shows an n-type electrical conductivity, but recent reports have demonstrated its potential p-type conductivity, opening the way for the development of p-n homojunction-based devices [2].
ZnGa 2 O 4 nanoparticles and thin films have typically been grown using a large number of methods, including pulsed-laser deposition, magnetron sputtering, metal-organic chemical vapor deposition, thermal synthesis, sol-gel process, and hydrothermal synthesis [3][4][5][6][7][8].Among them, hydrothermal synthesis offers several advantages, as a low-cost, low-temperature, and surface-scalable method.A first classical approach has consisted of mixing zinc and gallium salts in an aqueous solution in order to induce the precipitation of ZnGa 2 O 4 [8].A second more original approach has involved the chemical conversion of a solid phase serving as a sacrificial material.This method could involve zinc nanoparticles, but gallium-based compounds have been much more explored [9].Indeed, the standard Gibbs energy of reaction is favorable to form the ZnGa 2 O 4 phase instead of the mixture of the ZnO and Ga 2 O 3 phases [10].Accordingly, several reports have shown the chemical conversion of gallium-based compounds to ZnGa 2 O 4 [11][12][13][14].Chen et al. reported the synthesis of ZnGa 2 O 4 with cubic or octahedral shapes from GaOOH and Ga 2 O 3 , following the addition of Zn(NO 3 ) 2 under basic media.It was noticed that a better crystallinity of the particles originated from the GaOOH powder.However, an incomplete chemical conversion was revealed for this reaction operating at a lower pH (pH = 8) [11].Later, Yan et al. reported the chemical conversion of GaOOH to ZnGa 2 O 4 with a cubic shape, following the addition of Zn(CH 3 COO) 2 .The pH of the solution was not adjusted and was assumed to be in the acidic range [12].Liang et al. reported the chemical conversion of GaOOH and α-Ga 2 O 3 nanowires grown on FTO by adding Zn(CH 3 COO) 2 [13].The GaOOH nanowires were shown to be converted into ZnGa 2 O 4 nanowires with a cubic shape, in a similar manner to Ref. [12].However, the chemical conversion of α-Ga 2 O 3 nanowires led to the formation of ZnGa 2 O 4 nanotubes through the Kirkendall effect, which, in turn, kept the 1D morphology.A similar result was demonstrated by Lu et al., when partially converting GaN nanowires into GaN/ZnGa 2 O 4 core-shell nanowire heterostructures [14].The chemical conversion was performed with the help of Zn(NO 3 ) 2 as a zinc source and HMTA as a pH buffer.Interestingly, the reaction occurred at a lower temperature (85 • C) compared to the other methods described in Refs.[11][12][13], for which a higher temperature (>150 • C) was required.Until now, the chemical conversion of gallium-based compounds is therefore the only known method to obtain ZnGa 2 O 4 with a 1D morphology on a substrate using the hydrothermal synthesis method.However, the formation of vertically aligned dense arrays of gallium-based nanowires using a low-cost, low-temperature, and surface-scalable method is a tricky task.Only a couple of substrates are known to induce this type of growth, which is required to form nanowires [15,16].On the other hand, the formation of vertically aligned dense arrays of ZnO nanowires has been widely explored and demonstrated on a wide variety of substrates [17].However, the chemical conversion of ZnO to ZnGa 2 O 4 and its related mechanism have not been reported so far.
In this article, we present the partial chemical conversion of ZnO nanowires to ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures by using a low-temperature hydrothermal synthesis method.The influence of the gallium precursor concentration and of the initial pH (pH 0 ) of the solution on the ZnGa 2 O 4 shell growth is carefully investigated.We show the good coverage of the ZnGa 2 O 4 shell up to the complete embedment of ZnO nanowires by the ZnGa 2 O 4 shell.Then, the crystallinity of the ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures is optimized using different thermal annealing processes.The complete crystallization of the ZnGa 2 O 4 shell is shown to proceed at 400 • C under air at ambient pressure.Eventually, the mechanisms responsible for the partial chemical conversion of ZnO nanowires into ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures are discussed.

Deposition Techniques
The fabrication process of the ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures is presented in Figure 1.ZnO nanowire arrays were prepared using a double-step process of a sol-gel process and a chemical bath deposition.The ZnO seed layer was first deposited on a silicon substrate by dip coating, using the conditions described in Ref. [18], including an equimolar concentration of 375 mM for zinc acetate dihydrate [Zn(Ac) 2 •2H 2 O, Sigma Aldrich (St. Louis, MO, USA)] and monoethanolamine [MEA, Sigma Aldrich], as well as a withdrawal speed of 3.3 mm/s.Then, the silicon substrate coated with the ZnO seed layer was placed face-down in a sealed reactor to form ZnO nanowire arrays via chemical bath deposition using the conditions described in Ref. [19], including an equimolar concentration of 30 mM for zinc nitrate hexahydrate [Zn(NO 3 ) 2 •6H 2 O, Sigma-Aldrich] and hexamethylenetetramine [HMTA, Sigma-Aldrich].ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures were obtained by immersing the ZnO nanowire arrays in a sealed reactor containing a dissolved gallium nitrate [Ga(NO 3 ) 3 •xH 2 O, Sigma Aldrich] solution, with x considered to be 8 at a concentration varying in the range of 16-100 mM.The pH 0 of the solution was adjusted to a range of values varying from 8.56 to 9.65 by the addition of NaOH (Sigma Aldrich).The sealed reactor was kept at 90 • C in a regular oven for 3 h.

Annealing Process
The ZnO/ZnGa2O4 core-shell nanowire heterostructures were eventually treated thermally under air at ambient pressure using an annealing temperature of 400 °C, 600 °C, and 900 °C.The temperature ramp was carried out in successive steps every 100 °C, from 200 °C to the annealing temperature, with a rising temperature ramp set at 10 °C/min.The dwell time was set to 30 min.At the end of the annealing process, the samples were cooled down under air to room temperature.

Characterization Techniques
The morphological properties of ZnO nanowires and ZnO/ZnGa2O4 core-shell nanowire heterostructures were investigated using field-emission scanning electron microscopy (FESEM) images in top-view and cross-sectional view configurations using a ZEISS GeminiSEM 300 instrument (Carl Zeiss, Oberkochen, Germany).X-ray diffraction (XRD) patterns were collected with a BRUKER D8 Advance diffractometer using Cu Kα1 radiation according to the Bragg-Brentano configuration.Cross-sectional transmission electron microscopy (TEM) lamella were prepared using the semi-automated polishing tripod technique with the MultiPrepTM system (Allied High Tech Products, Inc., Cerritos, CA, USA).A GATAN PIPS II system was used for the final polishing.High-resolution TEM (HRTEM) images were recorded with a JEOL JEM 2010 LaB6 microscope (Tokyo, Japan) operating at 200 kV, with a 0.19 nm point-to-point resolution.

Effect of the Gallium Nitrate Concentration of the Solution on the ZnGa2O4 Shell Formation
The effect of the Ga(NO3)3 concentration of the solution on the morphological properties of the ZnGa2O4 shell and its uniformity was investigated using FESEM and XRD measurements.The pH0 of the solution was set to 9.27 at room temperature in order to (i) avoid the dissolution of ZnO nanowires during the addition of the Ga(NO3)3 solution with a pH0 of ≈2.5 [17], (ii) favor the predominant formation of Ga(OH)4 − anions acting as reacting species [20], and (iii) keep the positive surface charge of the top face and sidewalls of ZnO nanowires made of the polar c-plane and non-polar m-planes, respectively, with a point-of-zero-charge of 8.75 and 10.2 at room temperature [21,22].The present conditions are designed to establish attractive electrostatic interactions between the positively charged surfaces of ZnO nanowires and the Ga(OH)4 − reacting species [13,14].Typical FESEM images of ZnO nanowires coated with the ZnGa2O4 shell obtained for Ga(NO3)3 concentrations of 16, 50, and 100 mM are presented in Figure 2. The FESEM images show the formation of spherical-shaped nanoparticles (i.e., nanospheres) around the ZnO nanowires, regardless of the Ga(NO3)3 concentration.For each Ga(NO3)3 concentration, the nanospheres exhibit a mean size lying in the range of 30-50 nm.The nanospheres preferentially form on the top of ZnO nanowires, but their formation is also seen on the sidewalls of ZnO nanowires.For a Ga(NO3)3 concentration of 16 and 50 mM, the nanospheres

Annealing Process
The ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures were eventually treated thermally under air at ambient pressure using an annealing temperature of 400 • C, 600 • C, and 900 • C. The temperature ramp was carried out in successive steps every 100 • C, from 200 • C to the annealing temperature, with a rising temperature ramp set at 10 • C/min.The dwell time was set to 30 min.At the end of the annealing process, the samples were cooled down under air to room temperature.

Characterization Techniques
The morphological properties of ZnO nanowires and ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures were investigated using field-emission scanning electron microscopy (FESEM) images in top-view and cross-sectional view configurations using a ZEISS GeminiSEM 300 instrument (Carl Zeiss, Oberkochen, Germany).X-ray diffraction (XRD) patterns were collected with a BRUKER D8 Advance diffractometer using Cu K α1 radiation according to the Bragg-Brentano configuration.Cross-sectional transmission electron microscopy (TEM) lamella were prepared using the semi-automated polishing tripod technique with the MultiPrepTM system (Allied High Tech Products, Inc., Cerritos, CA, USA).A GATAN PIPS II system was used for the final polishing.High-resolution TEM (HRTEM) images were recorded with a JEOL JEM 2010 LaB 6 microscope (Tokyo, Japan) operating at 200 kV, with a 0.19 nm point-to-point resolution.

Effect of the Gallium Nitrate Concentration of the Solution on the ZnGa 2 O 4 Shell Formation
The effect of the Ga(NO 3 ) 3 concentration of the solution on the morphological properties of the ZnGa 2 O 4 shell and its uniformity was investigated using FESEM and XRD measurements.The pH 0 of the solution was set to 9.27 at room temperature in order to (i) avoid the dissolution of ZnO nanowires during the addition of the Ga(NO 3 ) 3 solution with a pH 0 of ≈2.5 [17], (ii) favor the predominant formation of Ga(OH) 4 − anions acting as reacting species [20], and (iii) keep the positive surface charge of the top face and sidewalls of ZnO nanowires made of the polar c-plane and non-polar m-planes, respectively, with a point-of-zero-charge of 8.75 and 10.2 at room temperature [21,22].The present conditions are designed to establish attractive electrostatic interactions between the positively charged surfaces of ZnO nanowires and the Ga(OH) 4 − reacting species [13,14].Typical FESEM images of ZnO nanowires coated with the ZnGa 2 O 4 shell obtained for Ga(NO 3 ) 3 concentrations of 16, 50, and 100 mM are presented in Figure 2. The FESEM images show the formation of spherical-shaped nanoparticles (i.e., nanospheres) around the ZnO nanowires, regardless of the Ga(NO 3 ) 3 concentration.For each Ga(NO 3 ) 3 concentration, the nanospheres exhibit a mean size lying in the range of 30-50 nm.The nanospheres preferentially form on the top of ZnO nanowires, but their formation is also seen on the sidewalls of ZnO nanowires.For a Ga(NO 3 ) 3 concentration of 16 and 50 mM, the nanospheres coalesce to form a fairly continuous shell around the ZnO nanowires.Instead, for a Ga(NO 3 ) 3 concentration of 100 mM, the nanospheres do not form a continuous shell.The shell composed of nanospheres extends from the top of the ZnO nanowires to their bottom, close to the ZnO seed layer, regardless of the Ga(NO 3 ) 3 concentration.However, the density of nanospheres is lower and lower as the position gets closer to the bottom of the ZnO nanowires, regardless of the Ga(NO 3 ) 3 concentration.The base of ZnO nanowires thus remains relatively bare.The effect is particularly pronounced when using the Ga(NO 3 ) 3 concentration of 16 mM.Also, it is worth noting that the top of some ZnO nanowires has been dug during the chemical conversion process, possibly indicating a partial dissolution process from the top polar c-planes.
coalesce to form a fairly continuous shell around the ZnO nanowires.Instead, for a Ga(NO3)3 concentration of 100 mM, the nanospheres do not form a continuous shell.The shell composed of nanospheres extends from the top of the ZnO nanowires to their bottom, close to the ZnO seed layer, regardless of the Ga(NO3)3 concentration.However, the density of nanospheres is lower and lower as the position gets closer to the bottom of the ZnO nanowires, regardless of the Ga(NO3)3 concentration.The base of ZnO nanowires thus remains relatively bare.The effect is particularly pronounced when using the Ga(NO3)3 concentration of 16 mM.Also, it is worth noting that the top of some ZnO nanowires has been dug during the chemical conversion process, possibly indicating a partial dissolution process from the top polar c-planes.The XRD measurements of ZnO nanowires coated with the ZnGa2O4 shell obtained for Ga(NO3)3 concentrations of 16, 50, and 100 mM are presented in Figure 3.The XRD patterns show the presence of ZnO nanowires with the wurtzite structure (i.e., the P63mc space group) through the diffraction peaks at 31.77°, 34.42°, 36.25°,47.54°, 56.60°, and 62.86° corresponding to the (100), ( 002), ( 101), ( 102), (110), and (103) planes, respectively, according to the 00-036-1451 ICDD file.The remaining diffraction peaks at 18.44°, 30.31°, 35.70°, 37.34°, 43.41°, 47.51°, 53.85°, 57.40°, and 63.04° are all attributed to the ZnGa2O4 shell with the cubic spinel structure (i.e., the Fd-3m space group) according to the 00-038-1240 ICDD file and correspond to the (111), ( 220), (311), ( 222), (400), (331), (422), (511), and (440) planes, respectively.Interestingly, the XRD analysis does not reveal any residual traces of the GaOOH and Ga(OH)3 phases, which could have been obtained during the chemical conversion.The cubic spinel structure of the ZnGa2O4 shell was also shown in HRTEM images, as depicted in Figure 4.A typical HRTEM image of a ZnO/ZnGa2O4 core-shell nanowire heterostructure projected along the [2-1-10] ZnO // [114] ZnGa2O4 zone axes is presented in Figure 4a, where the alignment of the {01-10} planes of the ZnO core with the {220} planes of the ZnGa2O4 shell is clearly revealed.The interface between the ZnO core and the ZnGa2O4 shell is quite abrupt, indicating that the partial chemical conversion is a pow-  The cubic spinel structure of the ZnGa2O4 shell was also shown in HRTEM images, as depicted in Figure 4.A typical HRTEM image of a ZnO/ZnGa2O4 core-shell nanowire heterostructure projected along the [2-1-10] ZnO // [114] ZnGa2O4 zone axes is presented in Figure 4a, where the alignment of the {01-10} planes of the ZnO core with the {220} planes of the ZnGa2O4 shell is clearly revealed.The interface between the ZnO core and the ZnGa2O4 shell is quite abrupt, indicating that the partial chemical conversion is a powerful method to form ZnO/ZnGa2O4 core-shell nanowire heterostructures with a high quality.The Fast Fourier Transform (FFT) image taken at the interfacial area, as presented in Figure 4b, further confirms the aforementioned observations.The influence of the Ga(NO3)3 concentration of the solution on the formation of the ZnGa2O4 shell by the partial chemical conversion of ZnO nanowires in aqueous solution eventually reveals that a value of 50 mM is considered to be the optimal Ga(NO3)3 concentration to provide the best trade-off between the nanosphere size, density, and coverage.The influence of the Ga(NO 3 ) 3 concentration of the solution on the formation of the ZnGa 2 O 4 shell by the partial chemical conversion of ZnO nanowires in aqueous solution eventually reveals that a value of 50 mM is considered to be the optimal Ga(NO 3 ) 3 concentration to provide the best trade-off between the nanosphere size, density, and coverage.

Effect of the pH 0 of the Solution on the ZnGa 2 O 4 Shell Formation
The effect of the pH 0 of the solution in a narrow range favoring attractive electrostatic interactions between the positively charged surfaces of ZnO nanowires and the Ga(OH) 4 − reacting species on the morphological properties of the ZnGa 2 O 4 shell and its uniformity was investigated using FESEM and XRD measurements.The Ga(NO 3 ) 3 concentration of the solution was set to 50 mM.Typical FESEM images of ZnO nanowires coated with the ZnGa 2 O 4 shell obtained for pH 0 values of 8.56, 8.64, 9.00, 9.27, and 9.65 are presented in Figure 5.The FESEM images again show the formation of nanospheres around the ZnO nanowires, regardless of the pH 0 value.For pH 0 values of 8.56, 8.64, 9.00, and 9.27, the size of the nanospheres lies in the range of 20-50 nm.Interestingly, the mean size of nanospheres progressively increases as the pH 0 value is increased from 8.56 to 9.27.In contrast, for the pH 0 value of 9.65, the size of the nanospheres is much larger and jumps to the range of 90-130 nm.Overall, the nanospheres are distributed homogeneously around the ZnO nanowires.Again, they preferentially form on the top of the ZnO nanowires, but their formation is also seen on the sidewalls of the ZnO nanowires.For pH 0 values of 8.56 and 8.64, the nanospheres only coalesce on the top of the ZnO nanowires to form a continuous shell.In contrast, isolated nanospheres sparsely occur on the sidewalls of the ZnO nanowires, with no contact between them.The density of nanospheres around the ZnO nanowires significantly increases for a pH 0 value of 9.00, such that coalescence starts proceeding.For a pH 0 value of 9.27, the nanospheres coalesce to form a fairly continuous shell around the ZnO nanowires.At this pH 0 , the shell covers up to 2/3 of the ZnO nanowire height, but their base still remains relatively bare.For a pH 0 value of 9.65, the nanospheres completely impregnate the ZnO nanowire arrays from the bottom to their top and hence the morphology of the core-shell nanowire heterostructure is lost at the benefit of a full 2D encapsulation acting as a planarization process.
spheres progressively increases as the pH0 value is increased from 8.56 to 9.27.In contrast, for the pH0 value of 9.65, the size of the nanospheres is much larger and jumps to the range of 90-130 nm.Overall, the nanospheres are distributed homogeneously around the ZnO nanowires.Again, they preferentially form on the top of the ZnO nanowires, but their formation is also seen on the sidewalls of the ZnO nanowires.For pH0 values of 8.56 and 8.64, the nanospheres only coalesce on the top of the ZnO nanowires to form a continuous shell.In contrast, isolated nanospheres sparsely occur on the sidewalls of the ZnO nanowires, with no contact between them.The density of nanospheres around the ZnO nanowires significantly increases for a pH0 value of 9.00, such that coalescence starts proceeding.For a pH0 value of 9.27, the nanospheres coalesce to form a fairly continuous shell around the ZnO nanowires.At this pH0, the shell covers up to 2/3 of the ZnO nanowire height, but their base still remains relatively bare.For a pH0 value of 9.65, the nanospheres completely impregnate the ZnO nanowire arrays from the bottom to their top and hence the morphology of the core-shell nanowire heterostructure is lost at the benefit of a full 2D encapsulation acting as a planarization process.The XRD measurements of the ZnO nanowires coated with the ZnGa2O4 shell obtained for pH0 values of 8.56, 8.64, 9.00, 9.27, and 9.65 are presented in Figure 6.The presence of ZnO nanowires with the wurtzite structure is revealed through the diffraction peaks at 31.77°, 34.42°, 36.25°,47.54°, 56.60°, and 62.86° corresponding to the (100), ( 002), (101), ( 102), (110), and (103) planes, respectively.The remaining diffraction peaks at 18.44°, 30.31°, 35.70°, 37.34°, 43.41°, 47.51°, 53.85°, 57.40°, and 63.04° are, respectively, assigned to the (111), ( 220), (311), ( 222), (400), (331), (422), (511), and (440) planes of the ZnGa2O4 shell with the cubic spinel structure.Interestingly, the intensity of the diffraction peaks related to the ZnGa2O4 shell strongly increases as the pH0 value is increased from 8.56 to 9.65,  The influence of the pH0 of the solution on the formation of the ZnGa2O4 shell by the partial chemical conversion of ZnO nanowires in aqueous solution finally shows that a value of 9.27 is considered as the optimal pH0 to lead to the best compromise between nanosphere size, density, and coverage.The influence of the pH 0 the solution on the formation of the ZnGa 2 O 4 shell by the partial chemical conversion of ZnO nanowires in aqueous solution finally shows that a value of 9.27 is considered as the optimal pH 0 to lead to the best compromise between nanosphere size, density, and coverage.

Discussion
The chemical bath deposition of ZnO/ZnGa2O4 core-shell nanowire heterostructures using a partial chemical conversion of ZnO nanowires in aqueous solution has been investigated using FESEM, HRTEM, and XRD measurements.By analogy with the chemical conversion of GaN, α-GaOOH, and α-Ga2O3 in aqueous solution to ZnGa2O4 [13,14], a schematic diagram of the double-step process is summarized in Figure 8.The partial chemical conversion of ZnO nanowires relies on the successive dissolution and reaction mechanisms, which are highly dependent upon the pH value.Under neutral and moder-

Discussion
The chemical bath deposition of ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures using a partial chemical conversion of ZnO nanowires in aqueous solution has been inves-tigated using HRTEM, and XRD measurements.By analogy with the chemical conversion of GaN, α-GaOOH, and α-Ga 2 O 3 in aqueous solution to ZnGa 2 O 4 [13,14], a schematic diagram of the double-step process is summarized in Figure 8.The partial chemical conversion of ZnO nanowires relies on the successive dissolution and reaction mechanisms, which are highly dependent upon the pH value.Under neutral and moderately basic conditions, the progressive dissolution of the surfaces of ZnO nanowires operates to release Zn(OH) 2(aq) species in aqueous solution [24].These Zn(II) species are assumed to react with the predominant Ga(III) species-Ga(OH) 4 − ion complexes [25].This results in the formation of the ZnGa 2 O 4 shell as nanospheres, for which the shape depends on the dissolution process of the surfaces of the ZnO nanowires, while the size depends on their reactivity.It is well known that the polar c-planes located on the top of the ZnO nanowires exhibit a greater chemical reactivity than the non-polar m-planes on their sidewalls [26].As a the ZnGa 2 O 4 shell composed of nanospheres is more dense and thicker on the top of the ZnO nanowires.This particularity has already been used to form ZnO/TiO 2 epitaxial core-shell nanowire heterostructures with a varying thickness [27], as well as ZnO/Zn 2 TiO 4 core-shell nanowire heterostructures, and TiO 2 nanotubes [28].In the present case, the fabrication of ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures opens perspectives for nanostructured solar cells [29], deep-UV photodetectors [30], and piezoelectric devices [31], for which the management of charge carriers and interface properties is of primary importance.In the case of deep-UV photodetectors, the present ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures may benefit from the absorption of deep-UV with the ZnGa 2 O 4 shell and from the electron transport with the ZnO nanowires [1,30].In the case of piezoelectric devices, the ZnGa 2 O 4 shell may passivate the surface states of ZnO nanowires, affecting the density of surface traps and hence the piezoelectric potential [1,31].

Conclusions
In summary, the development of innovative core-shell heterostructures, along with the control of the interfacial properties of ZnO nanowires, are of great interest for the enhancement of the performances of many devices.We have reported an original fabrication process to form ZnO/ZnGa2O4 core-shell nanowire heterostructures in the framework of the wet chemistry technique.The process involves the partial chemical conversion of ZnO nanowires grown via chemical bath deposition into ZnO/ZnGa2O4 core-shell nanowire heterostructures following their immersion in an aqueous solution containing Ga(NO3)3 heated at 90 °C.The ZnGa2O4 shell has been found to form uniformly, following a coalescence process of isolated nanospheres.It exhibits a pure spinel structure and a high interface quality with ZnO nanowires.The crystallinity of the ZnGa2O4 shell has been improved by a post-deposition thermal annealing at 400 °C under air at ambient pressure.The effect of the pH0 value and Ga(NO3)3 concentration of the solution on the structural properties of the ZnGa2O4 shell has further been revealed, showing the possibility to tune its morphology and thickness.The double-step process describing the partial chemical conversion has been discussed, relying on the progressive dissolution of the surfaces of the ZnO nanowires releasing Zn(OH)2(aq) species and their reaction with the predominant Ga(OH)4 − ion complexes.The present findings offer the possibility to fabricate ZnO/ZnGa2O4 core-shell nanowire heterostructures at low temperatures and over a wide

Conclusions
In summary, the development of innovative core-shell heterostructures, along with the control of the interfacial properties of ZnO nanowires, are of great interest for the enhancement of the performances of many devices.We have reported an original fabrication process to form ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures in the framework of the wet chemistry technique.The process involves the partial chemical conversion of ZnO nanowires grown via chemical bath deposition into ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures following their immersion in an aqueous solution containing Ga(NO 3 ) 3 heated at 90 • C. The ZnGa 2 O 4 shell has been found to form uniformly, following a coalescence process of isolated nanospheres.It exhibits a pure spinel structure and a high interface quality with ZnO nanowires.The crystallinity of the ZnGa 2 O 4 shell has been improved by a post-deposition thermal annealing at 400 • C under air at ambient pressure.The effect of the pH 0 value and Ga(NO 3 ) 3 concentration of the solution on the structural of the ZnGa 2 O 4 shell has further been revealed, showing the possibility to tune its morphology and thickness.The double-step process describing the partial chemical conversion has been discussed, relying on the progressive dissolution of the surfaces of the ZnO nanowires releasing Zn(OH) 2(aq) species and their reaction with the predominant Ga(OH) 4 − ion complexes.The present findings offer the possibility to fabricate ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures at low temperatures and over a wide variety of substrates with a large surface area, which is attractive for nanostructured solar cells, deep-UV photodetectors, and piezoelectric devices.

Nanomaterials 2024 ,
14,  x FOR PEER REVIEW 3 of 11 with x considered to be 8 at a concentration varying in the range of 16-100 mM.The pH0 of the solution was adjusted to a range of values varying from 8.56 to 9.65 by the addition of NaOH (Sigma Aldrich).The sealed reactor was kept at 90 °C in a regular oven for 3 h.

Figure 1 .
Figure 1.Schematic of the fabrication process of the ZnO/ZnGa2O4 core-shell nanowire heterostructures using wet chemistry.

Figure 1 .
Figure 1.Schematic of the fabrication process of the ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures using wet chemistry.

Figure 2 .
Figure 2. Top-view and cross-sectional view FESEM images of ZnO nanowire arrays coated with the ZnGa2O4 shell after a partial chemical conversion using a solution with a Ga(NO3)3 concentration of (a) 16 mM, (b) 50 mM, and (c) 100 mM for a given pH0 value of 9.27.

Figure 3 .
Figure 3. XRD patterns of ZnO nanowire arrays coated with the ZnGa 2 O 4 shell after a chemical conversion using a solution with a Ga(NO 3 ) 3 concentration of 16 mM, 50 mM, and 100 mM for a given pH 0 value of 9.27.

Figure 3 .
Figure 3. XRD patterns of ZnO nanowire arrays coated with the ZnGa2O4 shell after a chemical conversion using a solution with a Ga(NO3)3 concentration of 16 mM, 50 mM, and 100 mM for a given pH0 value of 9.27.

Figure 4 .
Figure 4. (a) HRTEM image at the interface of a ZnO/ZnGa2O4 core-shell nanowire heterostructure projected along the [2-1-10] ZnO // [114] ZnGa2O4 zone axes.(b) Corresponding FFT image of the interfacial area.The {01-10} planes of the ZnO core are aligned with the {220} planes of the ZnGa2O4 shell.The TEM analysis is illustrated with a ZnO nanowire coated with the ZnGa2O4 shell after a partial chemical conversion using a solution with a Ga(NO3)3 concentration of 50 mM for a given pH0 value of 9.27.

Figure 4 .
Figure 4. (a) HRTEM image at the interface of a ZnO/ZnGa 2 O 4 core-shell nanowire heterostructure projected along the [2-1-10] ZnO // [114] ZnGa 2 O 4 zone axes.(b) Corresponding FFT image of the interfacial area.The {01-10} planes of the ZnO core are aligned with the {220} planes of the ZnGa 2 O 4 shell.The TEM analysis is illustrated with a ZnO nanowire coated with the ZnGa 2 O 4 shell after a partial chemical conversion using a solution with a Ga(NO 3 ) 3 concentration of 50 mM for a given pH 0 value of 9.27.

Figure 5 .
Figure 5. Top-view and cross-sectional view FESEM images of ZnO nanowire arrays coated with the ZnGa2O4 shell after a partial chemical conversion using a solution with a pH0 value of (a) 8.56, (b) 8.64, (c) 9.00, (d) 9.27, and (e) 9.65 for a given Ga(NO3)3 concentration of 50 mM.

Figure 6 .
Figure 6.XRD patterns of ZnO nanowire arrays coated with the ZnGa2O4 shell after a chemical conversion using a solution with a pH0 value of 8.56, 8.64, 9.00, 9.27, and 9.65 for a given Ga(NO3)3 concentration of 50 mM.

Figure 6 .
Figure 6.XRD patterns of ZnO nanowire arrays coated with the ZnGa 2 O 4 shell after a chemical conversion using a solution with a pH 0 value of 8.56, 8.64, 9.00, 9.27, and 9.65 for a given Ga(NO 3 ) 3 concentration of 50 mM.

3. 3 .
Study of the Crystallization Process of the ZnGa 2 O 4 Shell The study of the formation of a ZnGa 2 O 4 shell by the partial chemical conversion of ZnO nanowires in aqueous solution allowed for the creation of a ZnGa 2 O 4 shell.Although a crystallized ZnGa 2 O 4 phase was identified using XRD, the presence of amorphous or poorly crystallized regions in the shell cannot be excluded.It is thus specifically important to study the evolution of the crystallinity of the ZnGa 2 O 4 phase after a post-deposition thermal annealing process under air at ambient pressure.The annealing time was kept below 10 h to limit the development of the insulating character of ZnGa 2 O 4 [23].The structural characterization of the annealed ZnO/ZnGa 2 O 4 core-shell nanowire heterostructures was carried out using XRD measurements.The XRD patterns collected before and after thermal annealing at 400 • C, 600 • C, and 900 • C are presented in Figure 7.The diffraction peaks at 31.77 • , 34.42 • , 36.25 • , 47.54 • , and 62.86 • again correspond to the (100), (002), (101), (102), and (103) planes of the ZnO nanowires.The diffraction peak at 32.96 • is attributed to the harmonic of the (002) plane coming from the Si substrate.The remaining diffraction peaks at 18.44 • , 30.31 • , 35.70 • , 37.34 • , 43.41 • , 47.51 • , 53.85 • , 57.40 • , and 63.04 • are, respectively, assigned to the (111), (220), (311), (222), (400), (331), (422), (511), and (440) planes of the ZnGa 2 O 4 shell.The XRD analysis does not highlight any residual traces from other phases.The intensity of the diffraction peaks related to the ZnGa 2 O 4 shell before thermal annealing is particularly low, revealing its low crystallinity.Conversely, the intensity of the diffraction peaks related to the ZnGa 2 O 4 shell strongly increases after thermal annealing, showing a higher crystallinity.However, the diffraction peaks of the ZnGa 2 O 4 shell roughly keep the same intensity, regardless of the annealing temperature.Therefore, a well-crystallized ZnGa 2 O 4 shell can be obtained from the annealing temperature of 400 • C under air, with the annealing time beginning at about 2 h.It is further worth noting the broadening of the diffraction peak at 34.42 • , corresponding to the (002) plane of the ZnO nanowires, which may result from the creation of defects at their top, hence revealing their progressive dissolution during the immersion process.Nanomaterials 2024, 14, x FOR PEER REVIEW 8 of 11nanowires, which may result from the creation of defects at their top, hence revealing their progressive dissolution during the immersion process.

Figure 7 .
Figure 7. (a) XRD patterns of ZnO nanowires coated with the ZnGa2O4 shell before and after thermal annealing under air at 400 °C, 600 °C, and 900 °C and (b) magnification between 30° and 40°.The chemical conversion parameters were set to a Ga(NO3)3 concentration of 50 mM and a pH0 value of 9.27.

Figure 7 .
Figure 7. (a) XRD patterns of ZnO nanowires coated with the ZnGa 2 O 4 shell and after thermal annealing under air at 400 • C, 600 • C, and 900 • C and (b) magnification between 30 • and 40 • .The chemical conversion parameters were set to a Ga(NO 3 ) 3 concentration of 50 mM and a pH 0 value of 9.27.

Nanomaterials 2024 , 11 Figure 8 .
Figure 8. Schematic diagram of the double-step process describing the partial chemical conversion of ZnO into ZnGa2O4 through successive dissolution and reaction mechanisms.

Figure 8 .
Figure 8. Schematic diagram of the double-step process describing the partial chemical conversion of ZnO into ZnGa 2 O 4 through successive dissolution and reaction mechanisms.