Pressure-Induced Exciton Formation and Superconductivity in Platinum-Based Mineral Sperrylite

We report a comprehensive study of Sperrylite (PtAs2), the main platinum source in natural minerals, as a function of applied pressures up to 150 GPa. While no structural phase transition is detected from pressure-dependent X-ray measurements, the unit cell volume shrinks monotonically with pressure following the third-order Birch–Murnaghan equation of state. The mildly semiconducting behavior found in pure synthesized crystals at ambient pressures becomes more insulating upon increasing the applied pressure before metalizing at higher pressures, giving way to the appearance of an abrupt decrease in resistance near 3 K at pressures above 92 GPa consistent with the onset of a superconducing phase. The pressure evolution of the calculated electronic band structure reveals the same physical trend as our transport measurements, with a non-monotonic evolution explained by a hole band that is pushed below the Fermi energy and an electron band that approaches it as a function of pressure, both reaching a touching point suggestive of an excitonic state. A Lifshitz transition of the electronic structure and an increase in the density of states may naturally explain the onset of superconductivity in this material.


I. INTRODUCTION
The enhancement of superconductivity as a function of applied pressures, known as the method to achieve the record-high transition temperature T c of 164 K at ∼31 GPa in the mercury-based cuprate superconductors [1], has recently come into strong focus due to the discoveries of near-room temperature superconductivity in hydride materials [2].It has also long been a standard method of finding enhanced superconductivity in a wide range of compounds including elements [3], heavy-fermions [4], topological insulators [5], and oxides [6].However, despite efforts to search for superconductivity in natural minerals [7] there are very few reports [8].
Sperrylite with formula PtAs 2 , named after Francis Louis Sperry, an American chemist in the late 1890s, forms in the cubic Pa-3 crystal structure shown in the inset of Fig. 1, with Pt and As atoms occuping 4a and 8c Wyckoff positions of the unit cell.Natural Sperrylite is tin-white crystallized and is known to be metallic, with indistinct cleavage on 001 planes.Recent studies of PtAs 2 and the related material PtSb 2 have focused mainly on their thermoelectric properties.Attributed to the presence of a corrugated flat electronic band [9], PtSb 2 reaches a maximum power factor of 43 µW/cmK 2 at 400 K [10] with Ir partially substituted.A higher value of 65 µW/cmK 2 at 440 K [11] was obtained by Rh substitution into PtAs 2 .Recently, the related pyrite material PtBi 2 , which was predicted to be a three-dimensional Dirac semimetal [12], displayed superconductivity under very large applied pressures [13] that appear to alter the * paglione@umd.edumaterials electronic structure to be nearly compensated.Overall, the Pt-based pyrite system hosts several intriguing properties and presents sensitivity to unit cell density that warrants further investigation.
Here we have conducted high-pressure measurements on synthesized PtAs 2 single crystals up to 150 GPa in order to investigate whether superconductivity can also be induced by increase of the unit cell density, as well as to understand how electronic structure evolves.We find that the very small gap semiconducting behavior that occurs at ambient pressure is non-monotonically modified by applied pressures, giving way to a superconducting transition that emerges above 90 GPa and onsets as high as 3.5 K at the highest explored pressure of 150 GPa.We consider the evolution of the crystal structure with pressure and study the electronic structure to reveal a possible emergence of excitonic insulator behavior as well as a transformation to a new electronic structure that is supportive of superconductivity.

II. METHODS
Naturally occurring Sperrylite mineral samples were obtained from the Department of Mineral Sciences at the Smithsonian Museum of Natural History as part of a broad search for superconductivity in natural minerals [7].However, since no superconductivity was detected, we proceed with focus on lab-synthesized single-crystal samples of PtAs 2 in order to characterize the material's intrinsic properties and minimize impurity effects.Crystals were grown using a standard molten flux technique from lead flux with ratio PtAs 2 :Pb = 1:20.This mixture was heated to 1100 o C in an alumina crucible over 5 hours, then cooled to 600 o C over 60 hours, subsequently removing crystals from the melt by centrifuging the lead flux.Typical dimensions of obtained single crystals varied from several millimeters to over 1 cm, and samples were polished to ∼ (2 × 1 × 0.1) mm 3 for transport measurements.
Electrical transport and x-ray diffraction experiments under high pressures utilized diamond anvil cells (DACs) to generate pressures in excess of 100 GPa.The electrical transport DAC was constructed with a non-magnetic (BeCu), screw-driven cell body, and the high-pressure chamber comprised a 300 µm standard anvil, a nonmagnetic MP35N gasket with a 90 µm hole, and a 260 µm, 8-probe designer anvil.The mismatched anvil sizes resulted in significant damage to the exterior of the culet of the designer anvil after the experiments; the CVD-grown diamond exhibited a ring-shape gouge approximately 300 µm in diameter, the same size as the culet of the opposing anvil in the experiment.Pressure in the chamber was measured via ruby fluorescence.Electrical transport data was acquired with a 4-probe technique using an AC resistance bridge to determine resistivity as a function of temperature using a commercial cryostat.
The DAC used for X-ray diffraction consisted of an asymmetric, steel piston-cylinder cell body combined with two opposed anvils with 250 µm diameter culets compressing a rhenium gasket pre-indented to approximately 35 µm in thickness.A 65 µm hole was drilled into the rhenium gasket using an electric discharge machine.Copper powder, a few ruby spheres, and the powdered  PtAs 2 were loaded into the pressure chamber before gasloading the pressure chamber with neon as the pressuretransmitting medium.X-ray diffraction data was collected at the APS/HPCAT 16 BM-D beamline using a transmission geometry with a 29.2 keV beam aligned along the compression axis of the anvils.The x-ray beam was micro-focused to a spot size of 6×17 µm, and the detector was calibrated with a CeO 2 standard.Pressure was increased using a gas membrane that was included in the DAC.Pressure was calibrated from the equation of state of copper [14].Analysis of the x-ray diffraction data was carried out using Fit2D [15] and EXPGUI/GSAS-I [16].
Electronic structure calculations were obtained via first-principles density functional theory calculation using the WIEN2K [17] implementation of the full potential linearized augmented plane wave method within the PBE generalized gradient approximation.We used the lattice parameters from Ref. 18.The k-point mesh was taken to be 14×14×14.To simulate the pressure effects on the electronic structure of PtAs 2 , the band structure and density of states calculations were then performed utilizing the same structure, but adjusting the ambient pressure cubic lattice constant a 0 by factors of 0.9, 0.873, and 0.87 to mimic applied pressures of 123, 186 and 194 GPa, respectively, following the measured compression as described below.

III. RESULTS
Fig. 1 presents powder X-ray diffraction data measured using the synthetic PtAs 2 crystals at ambient pressure, with fitting performed using the previously reported pyrite structure [18].Refinement of the diffraction spectrum yields a lattice constant of 5.9752(2) Å, which is consistent with previous results [19].Powder X-ray diffraction spectra of PtAs 2 measured in the DAC were fit to extract unit cell dimensions as a function of pressure, plotted as volume (i.e., lattice parameter a 3 ) in Fig. 2. PtAs 2 does not undergo any structural phase transition within the measured pressure range, rather showing a continuous decrease of the unit cell volume as the pressure increases to 150 GPa.This evolution follows the Birch-Murnaghan isothermal equation of state (EOS): where P is the pressure, V 0 is the reference volume, V is the deformed volume, B 0 is the bulk modulus, and B ′ 0 is the derivative of the bulk modulus with respect to pressure.Fitting the experimental data in Fig. 2 to this model yields values B 0 =224 ± 3 GPa and B ′ 0 =3.62 ± 0.07 for the bulk modulus and derivative term, respectively.The resultant fit is displayed in Fig. 2 along with a comparison to previously measured data [19].The EOS provides an excellent fit, while the comparison to previous work shows a slight discrepancy which could possibly be due to the use of natural mineral specimens by Tschauner et al., which are likely not as pure as the crystals synthesized for this study.The previous study also claimed a better fit using the Vinet equation due to the small pressure derivative of the bulk modulus, however the excellent fit to Birch-Murnaghan EOS shown in Fig. 2 suggests the value of B 0 obtained in the present study is more valid for pure PtAs 2 .
A study of the magnetic susceptibility for synthesized PtAs 2 , presented in Fig. 3(a), shows paramagnetic behavior on both warming and cooling curves, with no evidence of magnetism.The lack of temperature dependence is similar to previous reports for PtAs 2 as well as RhAs 2 and IrAs 2 [20], although the historical study reports a diamagnetic response.Fig. 3(b) presents the electrical resistivity of PtAs 2 at ambient pressure, which is also lacking any significant features.At high temperatures, the transport behavior is that of a semi-metal where resistivity is nearly flat, exhibiting a slight decrease on cooling down to a broad minimum centered near 200 K, followed by an increase with moderately activated behavior.Fitting to a standard Arrhenius activated behavior using ρ(T ) = ρ(0)e ∆/k B T through the range 50-200 K as illustrated in the inset, we obtain a rather small value for the thermally activated energy gap ∆ = 3.96 meV.Below 50 K, ρ(T ) deviates from activated behavior, which indicates that there may be another conduction channel or scattering mechanism at low temperatures that requires further investigation.
Fig. 4 presents the resistance temperature dependence of a PtAs 2 crystal mounted in the DAC cell and pressurized up to 150 GPa.The R(T ) data exhibit a nonmonotonic evolution as a function of applied pressure, with the lowest applied pressure data (4.2GPa) exhibiting a semiconducting behavior similar to that of ambient pressure, that evolves to a more insulating behavior at mid range pressures before becoming more metallic at higher pressures.As shown in the inset in Fig. 4, an abrupt drop in resistivity below about 4 K emerges at pressures above 77 GPa, which we attribute to the emergence of superconductivity.Due to the extremely high pressures of this phase, it is difficult to perform other experiments to confirm the superconducting state.However, the increasing drop that is evident with increasing pressure is consistent with such a state.Given the appearance of superconductivity near 2 K in the related pyrite material PtBi 2 near ∼ 10 GPa [13], it is not surprising that a similar onset occurs in PtAs 2 , albeit at much higher pressures.However, we note that the purported electronic structures are quite different as discussed below, so further work is required to understand the relationship between the two materials.
The evolution of resistivity with applied pressure is quantified in Fig. 5.As shown in panel a), the nonmonotonic evolution is evident when comparing the evolution of resistance values at 2 K and 300 K, which exhibit different dependence as a function of pressure.Normalizing the absolute changes by plotting their ratio in panel b) reveals a striking peak near ∼20 GPa.The temperature dependence of resistivity qualitatively changes with pressure evolution and exhibits deviations from simple semiconductor-like activated behavior at low temperatures, suggesting there is a more complex behavior that is not captured by a simple Arrhenius function.To quantify this evolution, we apply a power law fit of the form where G 0 is the residual zero-temperature conductance, a is a scaling coefficient for the temperature (T ) dependence and n is the power law exponent.In Fig. 5(c) we see the pressure effect on the conductance model described in equation (1), which shows the evolution from a simpler 1/T power law at low pressures to a stronger behavior with a peak in the power law exponent n at a similar pressure as the resistance ratio plot in panel b).
While the power law fits deviate from the measured data, this model is meant to capture a general phenomenological trend rather than fit a specific model.Below we discuss possible sources of this non-monotonic behavior tied to the evolution of the electronic band structure.
In Fig. 6 we present the band structure and density of states for PtAs 2 , which appears to be consistent with database calculations [21] that indicate a trivial topological structure, unlike that of PtBi 2 [12] and likely due to the gapped nature of the band structure and lighter pnictogen anion in PtAs 2 .We study the evolution of the PtAs 2 band structure as a function of cubic unit cell densities calculated for lattice constants of a 0 , 0.9a 0 , 0.873a 0 and 0.87a 0 with respect to the ambient pressure lattice constant a 0 .These densities correspond to estimated applied pressures of 0, 123, 186 and 194 GPa as calculated using the unit cell volume dependence measured by xray diffraction shown in Fig. 2. As is evident, there is a hole band centered between the Γ and M Brillouin zone points that remains very close to the chemical potential at all densities, an electron pocket at R that rapidly moves higher in energy (i.e.further from the chemical potential) while another electron pocket at Γ gradually drops toward the chemical potential.Together, this evo- lution of the band structure is broadly consistent with the measured electrical transport behavior, including the non-monotonic evolution of its temperature dependence as discussed below.
As shown in Fig. 6(a), the ambient pressure hole band (blue) centered between Γ and M points just barely cuts across the Fermi level, reflecting a non-metallic semimetal behavior consistent with our experimental observation.By applying pressure, this band is very subtly pushed down below the chemical potential, opening an indirect semiconducting gap between this band and the electron band centered at the Γ point (red).This change in the hole band is hard to discern when comparing to the first high pressure panel for a = 0.9a 0 (123 GPa), but is clear when we plot the position of the band edges versus pressure with higher point density in Fig. 7.As shown, the calculated hold band edge crosses the chemical potential at approximately 20 GPa effective pressure, which is precisely where we observe a non-monotonic change in the evolution of transport features (see Fig. 5(b)).Thus, this semimetal-semiconductor crossover in the lowpressure regime provides a good explanation of our transport data in the same pressure range.With increasing pressure, e.g. from a=0.9a 0 (123 GPa) to 0.837a 0 (186 GPa), the indirect gap narrows and eventually the conduction and valence bands touch the Fermi level at the same time, very close to a = 0.873a 0 as shown in Fig. 6(c).This approach results in a situation favoring the formation of an exciton insulator state [22], where the formation of electron-hole pairs occurs with a binding energy typically within tens of meV.In PtAs 2 , the pressure-induced shrinking of the energy gap toward the touching point at a = 0.873a 0 provides ripe conditions for a thermodynamically stable excitonic state, which should in principle onset once the gap energy falls below the excitonic binding energy.Without further experiments, it is unclear what energy range is required to achieve this condition, but the experimental transport data shown in Fig. 5(b) clearly marks a trend toward smaller and smaller activation energies above the ∼20 GPa resistance maximum, with a plateau reached above approximately 50 GPa.More interesting, the calculated pressure of the band touching point is very near the pressure where we have observed a sudden drop in resistance at low temperatures, which we attributed in the discussion above to an onset of superconductivity.It is certainly tempting to consider whether there is a correlation between these two events, and whether a more exotic type of pairing mechanism may be at play.Excitonic pairing mechanisms have long been proposed as a possible route to superconductivity, and mostly focus on a proximitized excitonic medium [23].Howeve, more recent proposals have suggested an intrinsic pairing mechanism is possible that involves a spin-triplet model that avoids strong Coulomb repulsion issues [24].What relation the band structure, superconductivity and exciton formation have requires further study to elucidate.
In any case, the interesting evolution of band structure at least entails several notable topological changes.These so-called Lifshitz transitions are known to give rise to interesting changes in electronic and physical properties, such as shown in the iron- [25] and nickel-pnictides, for example in the electronic nematic system BaNi 2 As 2 [26] where a Lifshitz transition appears to be associated with phase transitions involving superconductivity.
As shown in Figs.6-7, there are at least two notable Lifshitz transitions that occur PtAs 2 which we have attributed to measured changes in transport properties.This is also observed in the evolution of the electronic density of states (DOS) at the Fermi level (see Fig. 6), which first decreases and then increases with increasing pressure.Therefore, both the evolution of the band structure and DOS reveal the same physical trend as shown in Fig. 5. Furthermore, the components of the DOS plotted in Fig. 6 exhibit an interesting evolution that entails a valence valence band mainly composed of As 3p orbitals and a conduction band made up of Pt 5d orbitals at ambient pressure: upon increasing pressure, the Pt-5d bands are pushed away from the Fermi level and eventually the bands around the Fermi level are dominated by As-3p orbitals, which no longer have a covalent character but appear to be metallic.At the highest pressures, the higher DOS at the Fermi level could in principle also play a role in stabilizing superconductivity, but to understand how exciton formation also plays a role will require a microscopic model and further study.

IV. CONCLUSION
In conclusion, we present structural and electrical transport properties of the platinum-based mineral Sperrylite (PtAs 2 ) as a function of applied pressures up to 150 GPa, and compare our results with electronic structure calculations as a function of the cubic unit cell lattice density to help elucidate an unusual non-monotonic evolution of transport from semi-conducting to metallic at high pressures.As oppposed to the monotonic evolution of the unit cell density with pressure, which is well described by a third-order Birch-Murnaghan equa-FIG.6.Low energy electronic band structure (top panels) and electronic density of states (bottom panels) of PtAs2 as a function of unit cell density, using lattice parameters of a = 1.0a0 (a), a = 0.90a0 (b),a = 0.873a0 (c),a = 0.87a0 (d), where a0 is the lattice constant for the ambient pressure unit cell.The corresponding value of pressure P for each calculation is estimated based on formula (1).tion of state, the calculated evolution of electronic bands -from semi-metallic to insulating to metallic with in-creasing pressure -well explains the evolution of electrical transport, and suggest an excitonic instability may arise near the high pressure band-touching point.At the highest pressures, the observation of a sudden drop in resistance at 3 K suggests the onset of superconductivity very close to the calculated band-touching point, suggesting a strong interplay between the excitonic band structure evolution and appearance of superconductivity in this compound.

FIG. 1 .
FIG.1.X-ray diffraction data from powdered PtAs2 single crystals, with a small amount of lead identified as originating from the growth flux.Black dots, red lines, and green lines represent the observed, fitting curve and the difference between the two, respectively.The insert shows the unit cell of PtAs2 , with Pa-3 cubic crystal structure (grey and pink spheres represent Pt and As atoms, respectively.

FIG. 2 .
FIG. 2. Cubic unit cell volume of PtAs2 obtained by X-ray diffraction under applied pressures.Data from this study (purple diamonds) is fit (solid line) to the Birch-Murnaghan isothermal equation of state as described in the text, and compared to data measured in a previous study (blue squares) by Tschauner et.al. [19].

FIG. 3 .
FIG. 3. (a) Temperature-dependent magnetic susceptibility measured at 1 T of a lab-synthesized PtAs2 single crystal.(b) Electrical resistivity temperature dependence of labsynthesized PtAs2 single crystal at ambient pressure.Inset shows Arrhenius plot of data indicating semiconducting behavior at low temperatures.

kFIG. 4 .
FIG.4.Resistance of single crystal PtAs2 as a function of applied pressures in the range 4.2-150 GPa.Data points represent experimentally meaured data, and solid lines are results of phenomenological power law fit to equation 2. The inset shows a zoom of the low-temperature resistance at pressures (top to bottom) of 77, 92, 110, 115, and 150 GPa, respectively, highlighting the drop in resistance due to onset of a superconducting state.

FIG. 5 .
FIG. 5. Evolution of PtAs2 sample resistance features as a function of applied pressure, shown (a) at room temperature (orange squares) and 2 K (blue triangles), and (b) as a ratio (purple triangles).(c) Evolution of the temperature power law exponent n from fits to conductance model R(T ) = 1/(G0 + aT n ) as a function of pressure, as explained in the text.

FIG. 7 .
FIG. 7. Position of electron (circles) and hole (squares) band edges with respect to the Fermi energy (E=0) as a function of calculated pressure from DFT band structure calculations.