Preparation of Imitation Basalt Compound Based on Thermodynamic Calculation

In this paper, imitation basalt compounds using red mud, fly ash or coal gangue as raw materials were designed and prepared with the help of thermodynamic calculations. Thermodynamic calculations were used to obtain the suitable chemical composition. Then, the imitation compounds were prepared and their phase/compositions were analyzed. Finally, their high-temperature melting performance and crystallization ability were evaluated. The results show that the characteristic temperature and crystallization ability of the imitation basalt compounds were similar to those of basalt. Moreover, the viscosity of red mud imitation basalt compound approached the viscosity of basalt with the increase in temperature. This work suggests that red mud, fly ash and coal gangue can be mixed with quartz and other source materials to produce imitation basalt fiber. Therefore, thermodynamic calculation is an effective method to design and prepare high-performance imitation basalt compounds.


Introduction
Continuous basalt fiber is formed by drawing the basalt melt (at a melting temperature of 1450-1500 • C) with a wire drawing machine. The production process of basalt fiber determines that the production process produces less waste and less environmental pollution. The product is directly degradable in the environment without any hazard and is therefore an environmentally friendly material. Due to its excellent mechanical properties, resistance to chemical erosion, resistance to high temperature and environmental resistance [1], continuous basalt fiber and its composite materials have been extensively used in high-tech fields such as in military materials, transportation, chemical industry, and construction [2]. However, domestic basalt production is in short supply according to available data [3].
Basalt is a natural volcanic rock mainly consisting of SiO 2 , Al 2 O 3 , CaO, Fe 2 O 3 and MgO; its detailed composition is shown in Table 1. Variations in the chemical composition of basalt lead to an instability of basalt fiber performance, which is not conducive to the industrial production of high-performance basalt fiber. Moreover, the content of iron oxide in basalt ore is generally high, which is unfavorable for the melting of basalt ore and also easily causes the oxidation of the platinum-bismuth alloy leakage plate. As a result, the industrial production of basalt fiber cannot be achieved in a stable and consistent manner [4]. Therefore, it is necessary to prepare high-performance imitation basalt compounds which are suitable for the production of basalt fiber to help the development of the basalt fiber industry.
the Phase Diagram module of FactSage7.2 software (Thermfact/CRCT, Montreal, QC, Canada and GTT-Technologies, Achen, Germany) was used to obtain the ternary phase diagram of SiO2-Al2O3-CaO-Fe2O3-MgO-TiO2-O2, as shown in Figure 1. Here, the content of MgO, Fe2O3, and TiO2 was the same as that in the basalt sample. Since the points near the phase boundary are not easily crystallized during the cooling process, three points a (0.679 0.106 0.215), b (0.681 0.121 0.198), and c (0.698 0.085 0.217) near the phase boundary in the ternary phase diagram were selected according to the chemical composition of basalt. The sum of the mass ratios of SiO2, Al2O3, and CaO in the imitation basalt compounds is the same as that of the basalt sample. According to the coordinates of the three points a, b, and c in the ternary diagram of SiO2-Al2O3-CaO-Fe2O3-MgO-TiO2-O2, the chemical compositions of the imitation basalt compounds were calculated. Table 2 shows the calculated chemical compositions of the obtained imitation basalt compounds, with the same content of K2O and Na2O as that in the basalt sample.

Calculation of High-Temperature Viscosity
The high-temperature viscosities of basalt and three imitation basalt compounds were calculated by FactSage software. First, the Equilb module of FactSage software was adopted in order to obtain the uniform chemical compositions of the liquid phase in the system under thermodynamic equilibrium conditions. Then, the viscosity module of the FactSage software was applied to calculate the liquid phase chemical compositions obtained from the Equilb module to determine the liquid phase viscosity under the corresponding conditions. If a solid phase existed in the system, the Einstein-Rosce equation was adopted in order to calculate the liquid phase viscosity obtained from the viscosity module, and the solid phase content obtained from the Equilb module was used to obtain the viscosity of the solid-liquid mixture. The calculated viscosities were plotted as a function

Calculation of High-Temperature Viscosity
The high-temperature viscosities of basalt and three imitation basalt compounds were calculated by FactSage software. First, the Equilb module of FactSage software was adopted in order to obtain the uniform chemical compositions of the liquid phase in the system under thermodynamic equilibrium conditions. Then, the viscosity module of the FactSage software was applied to calculate the liquid phase chemical compositions obtained from the Equilb module to determine the liquid phase viscosity under the corresponding conditions. If a solid phase existed in the system, the Einstein-Rosce equation was adopted in order to calculate the liquid phase viscosity obtained from the viscosity module, and the solid phase content obtained from the Equilb module was used to obtain the viscosity of the solid-liquid mixture. The calculated viscosities were plotted as a function of temperature, as shown in Figure 2. The high-temperature viscosity of fly ash imitation basalt compound and coal gangue imitation basalt compound were calculated, and the obtained viscosities were plotted as a function of temperature, as shown in Figure 3.

Preparation of Imitation Basalt Compound
The basalt used in the present study was collected from Shandong Juyuan Basalt Fiber Co., Ltd., Zhangqiu, China; the red mud was obtained from Zunyi Alumina Plant, Zunyi, China; the fly ash and coal gangue were from Lingshou County Soil and Mineral Products Processing Factory, Shijiazhuang, China; quartz (AR), alumina (AR), ferric oxide (AR), magnesium oxide (AR), calcium carbonate (AR), sodium carbonate (AR), potassium hydroxide (UR), and titanium dioxide (AR) originated from Baihua Mall (Shanghai, China). In order to remove residual moisture, the raw The high-temperature viscosity of fly ash imitation basalt compound and coal gangue imitation basalt compound were calculated, and the obtained viscosities were plotted as a function of temperature, as shown in Figure 3. The high-temperature viscosity of fly ash imitation basalt compound and coal gangue imitation basalt compound were calculated, and the obtained viscosities were plotted as a function of temperature, as shown in Figure 3.

Preparation of Imitation Basalt Compound
The basalt used in the present study was collected from Shandong Juyuan Basalt Fiber Co., Ltd., Zhangqiu, China; the red mud was obtained from Zunyi Alumina Plant, Zunyi, China; the fly ash and coal gangue were from Lingshou County Soil and Mineral Products Processing Factory, Shijiazhuang, China; quartz (AR), alumina (AR), ferric oxide (AR), magnesium oxide (AR), calcium carbonate (AR), sodium carbonate (AR), potassium hydroxide (UR), and titanium dioxide (AR) originated from Baihua Mall (Shanghai, China). In order to remove residual moisture, the raw

Preparation of Imitation Basalt Compound
The basalt used in the present study was collected from Shandong Juyuan Basalt Fiber Co., Ltd., Zhangqiu, China; the red mud was obtained from Zunyi Alumina Plant, Zunyi, China; the fly ash and coal gangue were from Lingshou County Soil and Mineral Products Processing Factory, Shijiazhuang, China; quartz (AR), alumina (AR), ferric oxide (AR), magnesium oxide (AR), calcium carbonate (AR), sodium carbonate (AR), potassium hydroxide (UR), and titanium dioxide (AR) originated from Baihua Mall (Shanghai, China). In order to remove residual moisture, the raw materials were dried at a temperature of 393 K for 24 h. Following the drying processes, red mud, quartz, alumina, ferric oxide, magnesium oxide, calcium carbonate, potassium hydroxide, and sodium carbonate were, respectively, mixed in a weight ratio of 22.1:48.1:8.8:3.1:5.0:10.0:1.2:3.0 to prepare the red mud imitation basalt compound. Fly ash 1, quartz, alumina, ferric oxide, magnesium oxide, calcium carbonate, potassium hydroxide, sodium carbonate, and titanium dioxide were, respectively, mixed in a weight ratio of 33.0:41.6:0.1:6.1:5.1:11.1:1.4:5.6:0.3 to prepare the fly ash 1 imitation basalt compound. Fly ash 2, quartz, ferric oxide, magnesium oxide, calcium carbonate, potassium hydroxide, sodium carbonate, and titanium dioxide were, respectively, mixed in a weight ratio of 35.0:33.6:6.4:5.2:14.3:1.5:5.6:0.3 to prepare the fly ash 2 imitation basalt compound. Coal gangue, quartz, ferric oxide, magnesium oxide, calcium carbonate, potassium hydroxide, sodium carbonate, and titanium dioxide were, respectively, mixed in a weight ratio of 36.2:34.8:6.5:5.2:15.5:1.5:5.6:0.4 to prepare the coal gangue imitation basalt compound. The prepared imitation basalt compounds have the same chemical composition as the imitation basalt compound b in Table 2. The mixture was ground in a ball mill for 1 h to obtain a homogeneous mixture.

Analysis of Chemical Compositions and Components
The chemical compositions of basalt, red mud, fly ash 1, fly ash 2, coal gangue, quartz, alumina, and the resulting imitation basalt compounds were analyzed by a Zetium X-ray fluorescence spectrometer (Holland Panalytical, Almelo, The Netherlands).
The phase components of basalt red mud, fly ash 1, fly ash 2, and coal gangue were analyzed by X'Pert PRO MPD X-ray diffractometer (Holland Panalytical, Almelo, The Netherlands).

Investigation of High-Temperature Melting Performance
The softening temperature, hemispherical temperature and flow temperature of the samples were tested by a MTLQ-RD-3 melting point meter (Chongqing University of Science and Technology, Chongqing, China), and the morphology changes of the samples were recorded.
The high-temperature viscosity of basalt and red mud imitation basalt compound were measured by RSV-1600 high-temperature viscosity tester (Orton, Los Angeles, CA, USA), and measured viscosity values were plotted as a function of temperature.

Investigation of Crystallization Ability
To study their crystallization ability, the samples were first heated from room temperature to 1500 • C by a GSL-1700 high-temperature tube furnace (Hefei Kejing Material Technology Co., Ltd., Hefei, China); then, the temperature was maintained at 1500 • C for 1 h and then cooled to 700 • C at a rate of 5 • C/min. Finally, the samples were cooled to room temperature in the furnace. The crystallization degree of samples was analyzed by X'Pert PRO MPD X-ray diffractometer. The microstructures of the samples after high-temperature treatment were characterized by EM-30 Pluse scanning electron microscope (COXEM, Daejeon, Korea). Figure 2 shows that the viscosity values of imitation basalt compound b and basalt were relatively close. Therefore, the imitation basalt compound b was prepared. Figure 4 shows that red mud was mainly composed of serpentine, hematite, gibbsite, hydrogrossular, cancrinite, and biotite. Fly ash 1 was mainly composed of calcite, mullite, and gypsum, while fly ash 2 was mainly composed of mullite and quartz. Coal gangue mainly consisted of muscovite, kaolinite, and quartz. Basalt was mainly composed of diopside, anorthoclase, amphibole, and albite.    Table 3 shows the chemical composition of some raw materials. Table 4 shows the chemical composition of the imitation basallt compounds.   Table 3 shows the chemical composition of some raw materials. Table 4 shows the chemical composition of the imitation basallt compounds.  Figure 5 shows the high-temperature microscopic images and characteristic temperatures of the samples. Characteristic temperatures of fly ash, red mud and coal gangue were much higher than that of basalt, which may be related to their phase components and chemical compositions. Compared with fly ash, red mud, and coal gangue, the characteristic temperatures of the imitation basalt compounds were significantly lower. The characteristic temperature of imitation basalt compounds approached that of basalt, which can be explained by their similar chemical compositions. This indicates that, when the chemical compositions of imitation basalt compounds were similar, the influence of phase components on their characteristic temperature was very limited. Therefore, the characteristic temperatures of imitation basalt compounds prepared by red mud, fly ash, and coal gangue were strongly dependent on their chemical compositions.   Figure 5 shows the high-temperature microscopic images and characteristic temperatures of the samples. Characteristic temperatures of fly ash, red mud and coal gangue were much higher than that of basalt, which may be related to their phase components and chemical compositions. Compared with fly ash, red mud, and coal gangue, the characteristic temperatures of the imitation basalt compounds were significantly lower. The characteristic temperature of imitation basalt compounds approached that of basalt, which can be explained by their similar chemical compositions. This indicates that, when the chemical compositions of imitation basalt compounds were similar, the influence of phase components on their characteristic temperature was very limited. Therefore, the characteristic temperatures of imitation basalt compounds prepared by red mud, fly ash, and coal gangue were strongly dependent on their chemical compositions.  Figure 6 indicates that the measured viscosity of red mud imitation basalt compound gradually approaches that of basalt with the increase in temperature. When the temperature range was 1450-1460 °C, the difference in viscosity between the red mud imitation basalt compound and basalt was less than 9 poise. Comparing the calculated viscosities of the imitation basalt compounds in Figure 3 with the measured viscosities of basalt in Figure 6, it can be seen that the calculated viscosities of the imitation basalt compounds decreased rapidly with the increase in temperature, which was  Figure 6 indicates that the measured viscosity of red mud imitation basalt compound gradually approaches that of basalt with the increase in temperature. When the temperature range was 1450-1460 • C, the difference in viscosity between the red mud imitation basalt compound and basalt was less than 9 poise. Comparing the calculated viscosities of the imitation basalt compounds in Figure 3 with the measured viscosities of basalt in Figure 6, it can be seen that the calculated viscosities of the imitation basalt compounds decreased rapidly with the increase in temperature, which was consistent with the measured viscosities of the red mud imitation basalt compound. Thus, it can be deduced that the high-temperature melting performance of the imitation basalt compound was strongly dependent on its chemical composition and that imitation basalt compound with excellent high-temperature melting performance can be obtained by thermodynamic calculations. X-ray diffraction patterns of the samples are shown in Figure 7, which shows that the crystallization behavior of samples cooled from 1500 °C to room temperature. It can be seen that kamaishilite, pyroxene, and merwinite crystals were precipitated out of the red mud melt. However, fly ash and coal gangue were in a solid state at 1500 °C. Therefore, mullite and quartz in the fly ash, anorthite, and alumina in the coal gangue may not be produced by crystallization. It was observed that there was no crystallization during the cooling of basalt and imitation basalt compounds from 1500 °C to room temperature, indicating that both the basalt complex and the basalt have a lower crystallization ability. However, the area of the basalt diffraction peak is smaller than that of the basalt complex, which indicates that the basalt has a lower crystallinity. Similarly, the crystallinity of the red mud-like basalt compound is lower than that of other imitation basalt compound, and the fly ashlike basalt compound has similar crystallinity to the gangue-like basalt compound, which indicates that the crystallization ability of the imitation basalt compound was strongly dependent on its chemical composition. Thus, imitation basalt compounds with low crystallization ability can be obtained by thermodynamic calculations.   X-ray diffraction patterns of the samples are shown in Figure 7, which shows that the crystallization behavior of samples cooled from 1500 • C to room temperature. It can be seen that kamaishilite, pyroxene, and merwinite crystals were precipitated out of the red mud melt. However, fly ash and coal gangue were in a solid state at 1500 • C. Therefore, mullite and quartz in the fly ash, anorthite, and alumina in the coal gangue may not be produced by crystallization. It was observed that there was no crystallization during the cooling of basalt and imitation basalt compounds from 1500 • C to room temperature, indicating that both the basalt complex and the basalt have a lower crystallization ability. However, the area of the basalt diffraction peak is smaller than that of the basalt complex, which indicates that the basalt has a lower crystallinity. Similarly, the crystallinity of the red mud-like basalt compound is lower than that of other imitation basalt compound, and the fly ash-like basalt compound has similar crystallinity to the gangue-like basalt compound, which indicates that the crystallization ability of the imitation basalt compound was strongly dependent on its chemical composition. Thus, imitation basalt compounds with low crystallization ability can be obtained by thermodynamic calculations.

Results and Discussion
complex, which indicates that the basalt has a lower crystallinity. Similarly, the crystallinity of the red mud-like basalt compound is lower than that of other imitation basalt compound, and the fly ashlike basalt compound has similar crystallinity to the gangue-like basalt compound, which indicates that the crystallization ability of the imitation basalt compound was strongly dependent on its chemical composition. Thus, imitation basalt compounds with low crystallization ability can be obtained by thermodynamic calculations.  Figure 8 indicates that the basalt compound has a uniform matrix composition after hightemperature treatment, and the results of the X-ray diffraction analysis indicate that the basalt compound is amorphous. Therefore, the imitation basalt compound after high-temperature treatment is a uniform amorphous matrix. This indicates that the prepared basalt compound is suitable for the production of basalt fiber.  Figure 8 indicates that the basalt compound has a uniform matrix composition after high-temperature treatment, and the results of the X-ray diffraction analysis indicate that the basalt compound is amorphous. Therefore, the imitation basalt compound after high-temperature treatment is a uniform amorphous matrix. This indicates that the prepared basalt compound is suitable for the production of basalt fiber. Figure 8 indicates that the basalt compound has a uniform matrix composition after hightemperature treatment, and the results of the X-ray diffraction analysis indicate that the basalt compound is amorphous. Therefore, the imitation basalt compound after high-temperature treatment is a uniform amorphous matrix. This indicates that the prepared basalt compound is suitable for the production of basalt fiber.

Conclusions
(1) The as-prepared imitation basalt compounds exhibited excellent high-temperature melting performance and low crystallization ability, indicating that red mud, fly ash, and coal gangue with different chemical compositions and phase components can be used to produce imitation basalt fiber.
(2) Using thermodynamic calculations to obtain the chemical composition of imitation basalt compounds with desired properties is an effective method for the preparation of high-performance imitation basalt compounds.

Conclusions
(1) The as-prepared imitation basalt compounds exhibited excellent high-temperature melting performance and low crystallization ability, indicating that red mud, fly ash, and coal gangue with different chemical compositions and phase components can be used to produce imitation basalt fiber.
(2) Using thermodynamic calculations to obtain the chemical composition of imitation basalt compounds with desired properties is an effective method for the preparation of high-performance imitation basalt compounds.
(3) The high-temperature melting performance and crystallization ability of the imitation basalt compounds are strongly dependent on their chemical compositions.