Effect of the Cu/Mg Ratio on Mechanical Properties and Corrosion Resistance of Wrought Al–Cu–Mg–Ag Alloy

: The present study aimed to investigate the inﬂuence of magnesium (Mg) on the mechanical properties and corrosion behavior of wrought Al–4Cu–xMg–0.6Ag alloys. The results from Optical Microscope, SEM, XRD analysis, and Thermo-Calc simulation were used to identify the microstructure formed after the aging process. Testing for hardness and tensile strength was conducted, in addition to corrosion testing. It was found that Mg signiﬁcantly impacts the hardness of the alloys, with a high Mg content (low Cu/Mg ratio) increasing the hardness but reducing the tensile strength and ductility. This study attributed this to the formation of the S phase, which is dependent on both the quantity in the bulk and the size of the phase. The grain size was found to be ﬁner with a higher Mg content, since the particle size inhibits grain growth during the artiﬁcial aging process. Counterintuitively, the corrosion activity was reduced in the high-Mg-content alloy due to its large particle size and the reduced galvanic cell effect. This study highlighted the importance of considering the effects of Mg on the mechanical properties and corrosion behavior of Al–Cu–Mg–Ag alloys.


Introduction
Aluminum alloys containing small amounts of copper and magnesium alloying elements (usually denoted as Al-Cu-Mg alloys) are widely used in many important transport applications including the aerospace and automobile industries. The high usage of this category of aluminum alloys is mainly related to their great properties, such as a light weight, high strength, high corrosion resistance, high ductility, and high strength-to-weight ratio. Further, the different types of possible pre-thermomechanical treatments can significantly improve the mechanical properties of these alloys (e.g., tensile strength improves from 190 to 430 MPa by aging), making them suitable for various applications [1]. In particular, the presence of a slight weight percentage of Cu (~4.0 wt.%) and Mg (~1.0 wt.%) in these alloys improves the precipitation hardening through aging heat treatment.
The precipitation hardening in Al-Cu-Mg alloys usually increases the hardness and strength of the material. The aging treatment facilitates the formation of various precipitates in these alloys depending on the composition, temperature, aging time, and other processing conditions [2,3]. In the aging treatment of an Al-Cu-Mg alloy, the process starts with the formation of a supersaturated solid solution (SSS) where all the small phases dissolve in the more abundant α-aluminum phase. This is performed by heating the Al-Cu-Mg alloy to approximately 520 • C to form a homogeneous solid solution, followed by rapid quenching in water. The alloy is then heated (artificial aging) to a moderate temperature, approximately 180 • C, to facilitate the formation of stable precipitates in the matrix (α) phase. In an Al-Cu-Mg alloy, the type of stable precipitates is strongly influenced by the atomic ratio of Cu to Mg. For alloys of low Cu/Mg ratios, with compositions in the (α + S) phase field at approximately 190 • C, the stable precipitate is the S (Al 2 CuMg) phase [4]. The value. This results in a reduction in the potential differences (from 190 to 110 mV) between the coarse Al 2 Cu particles and the Al matrix, as well as a weakening of the activity of the galvanic corrosion couple, where the pitting corrosion resistance increased [25]. As the Mg content increased, the corrosion current density also increased, indicating a corresponding increase in the corrosion rate of the Al-Cu-Mg-Ag alloy. This could potentially be linked to the greater potential difference between the PFZ and the matrix [26]. The self-corrosion potential of the Al-Cu-Mg-Ag alloy was evaluated using PFZ, and it was found that EPFZ < Eq < EMatrix. By adjusting the grain boundary microstructure, T614 temper can significantly enhance the exfoliation corrosion resistance of the alloy [27]. Intermetallic particles found in aluminum alloys have a significant impact on the breakdown of the passivity and pit morphology of these alloys when exposed to seawater.
The present study investigates the effects of increasing Mg concentration from 0.4 to 1.4 wt.% in Al-4%Cu-xMg-0.6%Ag alloy. The discussion of this study focuses on the mechanical properties, microstructure, and corrosion resistance.

Materials and Methods
The methodology for this study aims to examine the effects of Cu/Mg ratios on the mechanical properties and corrosion resistance of Al-Cu-Mg-Ag alloys. The materials were designed to present high and low Cu/Mg ratios, as shown in Figure 1. The change in Cu/Mg was controlled by increasing the Mg content while keeping the Cu and Ag fixed at the same percentage. The Mg concentration was raised from 0.4 to 1.4 wt.%, where the ratios were 10%, called high, and 3%, called low. This change in Mg content was based on the Al-Cu-Mg phase diagram, which predicts that a high Cu/Mg ratio could result in the presence of three phases (α + θ + S) with different percentages of phases [11].
Changing the Mg concentration in the composition led to the same change in co sion resistance, as mentioned in the following literature. By adding small amounts o and Mg to an Al-Cu alloy, the volta potential of the Al matrix was shifted to a hi positive value. This results in a reduction in the potential differences (from 190 to 110 between the coarse Al2Cu particles and the Al matrix, as well as a weakening of the a ity of the galvanic corrosion couple, where the pitting corrosion resistance increased As the Mg content increased, the corrosion current density also increased, indicati corresponding increase in the corrosion rate of the Al-Cu-Mg-Ag alloy. This could tentially be linked to the greater potential difference between the PFZ and the matrix The self-corrosion potential of the Al-Cu-Mg-Ag alloy was evaluated using PFZ, an was found that EPFZ < Eq < EMatrix. By adjusting the grain boundary microstruct T614 temper can significantly enhance the exfoliation corrosion resistance of the alloy Intermetallic particles found in aluminum alloys have a significant impact on the br down of the passivity and pit morphology of these alloys when exposed to seawater.
The present study investigates the effects of increasing Mg concentration from 0 1.4 wt.% in Al-4%Cu-xMg-0.6%Ag alloy. The discussion of this study focuses on the chanical properties, microstructure, and corrosion resistance.

Materials and Methods
The methodology for this study aims to examine the effects of Cu/Mg ratios on mechanical properties and corrosion resistance of Al-Cu-Mg-Ag alloys. The mate were designed to present high and low Cu/Mg ratios, as shown in Figure 1. The cha in Cu/Mg was controlled by increasing the Mg content while keeping the Cu and Ag f at the same percentage. The Mg concentration was raised from 0.4 to 1.4 wt.%, where ratios were 10%, called high, and 3%, called low. This change in Mg content was base the Al-Cu-Mg phase diagram, which predicts that a high Cu/Mg ratio could result in presence of three phases (α + θ + S) with different percentages of phases [11]. The alloys were prepared from pure bulk elements melted at 730 °C and cast heated mold of steel at 450 °C. The resulting ingots were then homogenized at 520 °C 24 h, followed by furnace cooling [28]. The chemical composition of the ingots was lyzed using SPECTRO MAXx Spectral analyzer, and the results are shown in Table 1  The alloys were prepared from pure bulk elements melted at 730 • C and cast into heated mold of steel at 450 • C. The resulting ingots were then homogenized at 520 • C for 24 h, followed by furnace cooling [28]. The chemical composition of the ingots was analyzed using SPECTRO MAXx Spectral analyzer, and the results are shown in Table 1. The casted ingots were then rolled from 16mm to 2.5 mm in thickness by hot rolling machine, which resulted in an 84% reduction, forming the alloy sheets. These sheets were then solution-treated at 520 • C and quenched in water at room temperature, inducing the formation of a supersaturated solid solution (SSS). Afterwards, the samples were aged in a salt bath at 180 • C to determine the aging peak point for hardness [28,29], as shown in Figure 2. A hardness test, Vickers hardness type, was performed on the scale of 10 KgF during the 15 s. The hardness was determined by taking an average of 5 indents at a random location on the sample. Tensile samples were then cut using an Electric Discharge Machine (EDM) from the SSS sheets, according to ASTM E 8/E 8M-08 standards. The tensile samples were then aged at the previously determined hardness peak point and were tested using an INSTRON universal testing machine at a strain rate of 10 −3 s −1 . To ensure accuracy, three samples were tested for each alloy to verify the outcomes.  The casted ingots were then rolled from 16mm to 2.5 mm in thickness by hot rolling machine, which resulted in an 84% reduction, forming the alloy sheets. These sheets were then solution-treated at 520 °C and quenched in water at room temperature, inducing the formation of a supersaturated solid solution (SSS). Afterwards, the samples were aged in a salt bath at 180 °C to determine the aging peak point for hardness [28,29], as shown in Figure 2. A hardness test, Vickers hardness type, was performed on the scale of 10 KgF during the 15s. The hardness was determined by taking an average of 5 indents at a random location on the sample. Tensile samples were then cut using an Electric Discharge Machine (EDM) from the SSS sheets, according to ASTM E 8/E 8M-08 standards. The tensile samples were then aged at the previously determined hardness peak point and were tested using an INSTRON universal testing machine at a strain rate of 10 −3 s −1 . To ensure accuracy, three samples were tested for each alloy to verify the outcomes. The microstructure of the samples was analyzed using optical microscopy (OM) and scanning electron microscopy (SEM), equipped with electron probe microanalysis (JEOL, Tokyo, Japan). X-ray diffraction (XRD) analysis was also conducted using a MAXima XRD-7000 machine equipped with Cu Kα radiation on both H-0.4Mg alloy and L-1.4Mg alloy to investigate the effects of Mg concentration on the alloys [28]. The XRD analysis was performed on polished samples and the fixed direction for both samples. Thermo-Calc simulation software equipped with the TCAL8 database was used to calculate the possible amount of each phase that may have developed between 150 and 250 °C [30].
Cyclic polarization tests were conducted to evaluate the corrosion behavior of the alloys in Arabian Gulf seawater. The tests were performed in a three-electrode electrochemical cell using a potentiostat/galvanostat instrument. The working electrode was a polished disc of each alloy with an exposed surface area of 1 cm 2 . A reference electrode made of Ag/AgCl and a counter electrode made of platinum wire were employed in the experiment. Prior to the test, the working electrode surface was cleaned using a series of standard metallographic techniques. The electrochemical cell was filled with Arabian Gulf seawater and maintained at a temperature of 25 °C for 30 min to allow the system to equilibrate. The cyclic polarization test was performed by applying a potential sweep from −0.5 V to +0.5 V vs. Ag/AgCl at a scan rate of 1 mV/s. The potential sweep was first conducted in the positive direction (anodic scan), until a current density of 10 μA/cm 2 was reached, and then in the negative direction (cathodic scan), until the current density returned to the initial value. The potential difference between the working electrode and the reference electrode was recorded throughout the test, and the resulting current-potential curve was used to determine the corrosion behavior of the alloys. The microstructure of the samples was analyzed using optical microscopy (OM) and scanning electron microscopy (SEM), equipped with electron probe microanalysis (JEOL, Tokyo, Japan). X-ray diffraction (XRD) analysis was also conducted using a MAXima XRD-7000 machine equipped with Cu Kα radiation on both H-0.4Mg alloy and L-1.4Mg alloy to investigate the effects of Mg concentration on the alloys [28]. The XRD analysis was performed on polished samples and the fixed direction for both samples. Thermo-Calc simulation software equipped with the TCAL8 database was used to calculate the possible amount of each phase that may have developed between 150 and 250 • C [30].
Cyclic polarization tests were conducted to evaluate the corrosion behavior of the alloys in Arabian Gulf seawater. The tests were performed in a three-electrode electrochemical cell using a potentiostat/galvanostat instrument. The working electrode was a polished disc of each alloy with an exposed surface area of 1 cm 2 . A reference electrode made of Ag/AgCl and a counter electrode made of platinum wire were employed in the experiment. Prior to the test, the working electrode surface was cleaned using a series of standard metallographic techniques. The electrochemical cell was filled with Arabian Gulf seawater and maintained at a temperature of 25 • C for 30 min to allow the system to equilibrate. The cyclic polarization test was performed by applying a potential sweep from −0.5 V to +0.5 V vs. Ag/AgCl at a scan rate of 1 mV/s. The potential sweep was first conducted in the positive direction (anodic scan), until a current density of 10 µA/cm 2 was reached, and then in the negative direction (cathodic scan), until the current density returned to the initial value. The potential difference between the working electrode and the reference electrode was recorded throughout the test, and the resulting current-potential curve was used to determine the corrosion behavior of the alloys. Finally, this methodology is designed to provide comprehensive insights into the mechanical properties and corrosion resistance of the Al-Cu-Mg-Ag alloy as a function of Cu/Mg ratios. The results of this study contribute to the understanding of the behavior of Al-Cu-Mg-Ag alloys in various environments and have practical implications for the selection and use of these alloys in various industrial applications.

Results
The hardness comparison of the investigated alloys is presented in Figure 3, which shows that the low Cu/Mg ratio alloy (L-1.4Mg) presents a higher hardness directly after the supersaturated solid solution (SSS) at the onset of the aging process, with a value of 122 Hv. In contrast, the high Cu/Mg ratio alloy (H-0.4Mg) only reached 102 Hv. The explanation for this difference lies in the high concentration of Mg in the low Cu/Mg ratio alloy, leading to the supersaturation of Mg atoms in the aluminum matrix, as indicated by the supersaturated solid solution theory [28]. This results in improved hardness, which continues to improve through the precipitate hardening theory, characterized by the accumulation of alloy elements to form different precipitates. This is due to the diffusion of elements within the alloys, leading to larger precipitates until they reach a uniform size and distribution. The peak hardness values of the L-1.4Mg alloy and H-0.4Mg alloy were 149 Hv and 138 Hv, respectively. Despite initially increasing, the hardness of both alloys eventually started to decrease. However, the hardness of L-1.4Mg was less than the SSS stage after 48 h, which can be attributed to an increment in the size of the θ precipitate relative to the S precipitate. The larger size of precipitates negatively affected the hardness due to an increased mismatch between the aluminum matrix and precipitates [11].
Finally, this methodology is designed to provide comprehensive insights into chanical properties and corrosion resistance of the Al-Cu-Mg-Ag alloy as a fun Cu/Mg ratios. The results of this study contribute to the understanding of the beh Al-Cu-Mg-Ag alloys in various environments and have practical implications fo lection and use of these alloys in various industrial applications.

Results
The hardness comparison of the investigated alloys is presented in Figure  shows that the low Cu/Mg ratio alloy (L-1.4Mg) presents a higher hardness direc the supersaturated solid solution (SSS) at the onset of the aging process, with a 122 Hv. In contrast, the high Cu/Mg ratio alloy (H-0.4Mg) only reached 102 Hv. planation for this difference lies in the high concentration of Mg in the low Cu/M alloy, leading to the supersaturation of Mg atoms in the aluminum matrix, as in by the supersaturated solid solution theory [28]. This results in improved hardnes continues to improve through the precipitate hardening theory, characterized by cumulation of alloy elements to form different precipitates. This is due to the diff elements within the alloys, leading to larger precipitates until they reach a unifo and distribution. The peak hardness values of the L-1.4Mg alloy and H-0.4Mg all 149 Hv and 138 Hv, respectively. Despite initially increasing, the hardness of bo eventually started to decrease. However, the hardness of L-1.4Mg was less than stage after 48 h, which can be attributed to an increment in the size of the θ pr relative to the S precipitate. The larger size of precipitates negatively affected the h due to an increased mismatch between the aluminum matrix and precipitates [11 The effect of the high and low Cu/Mg ratios on the tensile test is demonst Figure 4. The results show that a decrease in Mg content leads to an increase in t stress from 362 to 381 MPa, or 5%, as well as an increase in the tensile stress from 426 MPa. However, the low Cu/Mg ratio alloy was found to be brittle, with a pe ductility of 2 compared to 10 for the high Cu/Mg ratio alloy. This reduction in yiel tensile stress, and ductility percentage may be due to the increased size of the pre as the Mg content increases, leading to a mismatch between the aluminum ma precipitates' clusters. In addition, Figure 5 compared the amounts of the S phas 1.4Mg at 180 °C at the aging temperature, and the Thermo-Calc simulation softw supports these observations. In particular, the L-1.4Mg alloy had an average size o for the S phase, which is three times larger than the critical size of the S phase [31]. The effect of the high and low Cu/Mg ratios on the tensile test is demonstrated in Figure 4. The results show that a decrease in Mg content leads to an increase in the yield stress from 362 to 381 MPa, or 5%, as well as an increase in the tensile stress from 391 to 426 MPa. However, the low Cu/Mg ratio alloy was found to be brittle, with a percentage ductility of 2 compared to 10 for the high Cu/Mg ratio alloy. This reduction in yield stress, tensile stress, and ductility percentage may be due to the increased size of the precipitates as the Mg content increases, leading to a mismatch between the aluminum matrix and precipitates' clusters. In addition, Figure 5 compared the amounts of the S phase and L-1.4 Mg at 180 • C at the aging temperature, and the Thermo-Calc simulation software [30] supports these observations. In particular, the L-1.4Mg alloy had an average size of 18 µm for the S phase, which is three times larger than the critical size of the S phase (4.5 µm) [31].   The optical micrograph of Al-Cu-Mg-Ag alloys with high and low Cu/Mg ratios provides valuable insight into the microstructure of the alloys. As shown in Figure 6A, the high Cu/Mg ratio exhibits an average grain size of approximately 205 μm, while the low Cu/Mg ratio, as depicted in Figure 6B, displays an average grain size of 139 μm. According to the findings, the alloys' incorporation of Mg prevents recrystallization from occurring throughout the artificial aging process. The large size of the precipitates in the L-1.4Mg alloy may be responsible for the limited recrystallization size, as indicated by Figure 7. This leads to an increase in the mismatch between the lattice parameters of the alloy matrix and the S phase. In addition, this might affect the tensile result by increasing the average size of the S phase from 3 μm to 18 μm in the high Cu/Mg ratio alloy when the Mg concentration rose from 0.4 to 1.4. This observation is further supported by the Xray diffraction (XRD) results, which show the presence of large-sized S phases separated at several planes, as shown in Figure 8. XRD results support the increase in Mg content in the L-1.4Mg alloy enhanced the formation of the S phase, as evidenced by the peak XRD at 2θ angles of 24° and 35°. As well, the XRD results show multiple peaks with a high intensity of the S phase in L-1.4Mg compared to H-0.4Mg. The limited recrystallization size can be explained in other ways as well though. Another that might be important is the L-1.4Mg alloy's abundance of Ω phases, which are composed of Al-Cu-Mg-Ag. This, however, is outside the purview of this investigation. Our previous work showed that the mechanical properties of alloys with a high Mg content can be improved by increasing the   The optical micrograph of Al-Cu-Mg-Ag alloys with high and low Cu/Mg ratios provides valuable insight into the microstructure of the alloys. As shown in Figure 6A, the high Cu/Mg ratio exhibits an average grain size of approximately 205 μm, while the low Cu/Mg ratio, as depicted in Figure 6B, displays an average grain size of 139 μm. According to the findings, the alloys' incorporation of Mg prevents recrystallization from occurring throughout the artificial aging process. The large size of the precipitates in the L-1.4Mg alloy may be responsible for the limited recrystallization size, as indicated by Figure 7. This leads to an increase in the mismatch between the lattice parameters of the alloy matrix and the S phase. In addition, this might affect the tensile result by increasing the average size of the S phase from 3 μm to 18 μm in the high Cu/Mg ratio alloy when the Mg concentration rose from 0.4 to 1.4. This observation is further supported by the Xray diffraction (XRD) results, which show the presence of large-sized S phases separated at several planes, as shown in Figure 8. XRD results support the increase in Mg content in the L-1.4Mg alloy enhanced the formation of the S phase, as evidenced by the peak XRD at 2θ angles of 24° and 35°. As well, the XRD results show multiple peaks with a high intensity of the S phase in L-1.4Mg compared to H-0.4Mg. The limited recrystallization size can be explained in other ways as well though. Another that might be important is the L-1.4Mg alloy's abundance of Ω phases, which are composed of Al-Cu-Mg-Ag. This, however, is outside the purview of this investigation. Our previous work showed that the mechanical properties of alloys with a high Mg content can be improved by increasing the The optical micrograph of Al-Cu-Mg-Ag alloys with high and low Cu/Mg ratios provides valuable insight into the microstructure of the alloys. As shown in Figure 6A, the high Cu/Mg ratio exhibits an average grain size of approximately 205 µm, while the low Cu/Mg ratio, as depicted in Figure 6B, displays an average grain size of 139 µm. According to the findings, the alloys' incorporation of Mg prevents recrystallization from occurring throughout the artificial aging process. The large size of the precipitates in the L-1.4Mg alloy may be responsible for the limited recrystallization size, as indicated by Figure 7. This leads to an increase in the mismatch between the lattice parameters of the alloy matrix and the S phase. In addition, this might affect the tensile result by increasing the average size of the S phase from 3 µm to 18 µm in the high Cu/Mg ratio alloy when the Mg concentration rose from 0.4 to 1.4. This observation is further supported by the X-ray diffraction (XRD) results, which show the presence of large-sized S phases separated at several planes, as shown in Figure 8. XRD results support the increase in Mg content in the L-1.4Mg alloy enhanced the formation of the S phase, as evidenced by the peak XRD at 2θ angles of 24 • and 35 • . As well, the XRD results show multiple peaks with a high intensity of the S phase in L-1.4Mg compared to H-0.4Mg. The limited recrystallization size can be explained in other ways as well though. Another that might be important is the L-1.4Mg alloy's abundance of Ω phases, which are composed of Al-Cu-Mg-Ag. This, however, is outside the purview of this investigation. Our previous work showed that the mechanical properties of alloys with a high Mg content can be improved by increasing the Ag content, which suggests that the Ω phase may have a negative impact on the recrystallization process [29]. Ag content, which suggests that the Ω phase may have a negative impact on the recry tallization process [29].  The samples were immersed in seawater for 120 h to investigate the corrosion activi on the particles, as shown in Figure 9. The impact of corrosion is dependent on the utiliz composition, leading to varying reactions to the corrosion. Based on the image, it appea that corrosion may have begun in the area surrounding the particles, where the mismat between the Al-matrix and the particles might have a chance. This result is supported the cycle polarization test, as shown in Figure 10, which shows that the H-0.4Mg has t higher corrosion potential, while the L-1.4Mg has the lower corrosion potential. Howev the particle size might be involved in the corrosion rate, where the L1.4Mg alloy has t bigger particle size, which enhances the corrosion rate compared to the small particle si in the H-0.4Mg alloy. Ag content, which suggests that the Ω phase may have a negative impact on the recrys tallization process [29].  The samples were immersed in seawater for 120 h to investigate the corrosion activity on the particles, as shown in Figure 9. The impact of corrosion is dependent on the utilized composition, leading to varying reactions to the corrosion. Based on the image, it appear that corrosion may have begun in the area surrounding the particles, where the mismatch between the Al-matrix and the particles might have a chance. This result is supported b the cycle polarization test, as shown in Figure 10, which shows that the H-0.4Mg has th higher corrosion potential, while the L-1.4Mg has the lower corrosion potential. However the particle size might be involved in the corrosion rate, where the L1.4Mg alloy has th bigger particle size, which enhances the corrosion rate compared to the small particle siz in the H-0.4Mg alloy. Ag content, which suggests that the Ω phase may have a negative impact on the recry tallization process [29].  The samples were immersed in seawater for 120 h to investigate the corrosion activi on the particles, as shown in Figure 9. The impact of corrosion is dependent on the utilize composition, leading to varying reactions to the corrosion. Based on the image, it appea that corrosion may have begun in the area surrounding the particles, where the mismatc between the Al-matrix and the particles might have a chance. This result is supported b the cycle polarization test, as shown in Figure 10, which shows that the H-0.4Mg has th higher corrosion potential, while the L-1.4Mg has the lower corrosion potential. Howeve the particle size might be involved in the corrosion rate, where the L1.4Mg alloy has th bigger particle size, which enhances the corrosion rate compared to the small particle si in the H-0.4Mg alloy. The samples were immersed in seawater for 120 h to investigate the corrosion activity on the particles, as shown in Figure 9. The impact of corrosion is dependent on the utilized composition, leading to varying reactions to the corrosion. Based on the image, it appears that corrosion may have begun in the area surrounding the particles, where the mismatch between the Al-matrix and the particles might have a chance. This result is supported by the cycle polarization test, as shown in Figure 10, which shows that the H-0.4Mg has the higher corrosion potential, while the L-1.4Mg has the lower corrosion potential. However, the particle size might be involved in the corrosion rate, where the L1.4Mg alloy has the bigger particle size, which enhances the corrosion rate compared to the small particle size in the H-0.4Mg alloy.

Discussion
The results section illustrates that Mg concentration has a significant influence on Al Cu-Mg-Ag alloys, as summarized in Table 2. Despite increasing the material's hardness Mg reduces yield stress and ductility. The XRD results and Thermo-Calc simulation wer used to identify the phases that formed on the alloys during the aging process. It is eviden that the S phase played a crucial role. It was dependent not only on the S phase quantity in the bulk but also on the phase size. The hardness result indicates that a high Mg conten increases the hardness of the alloy, while decreasing the yield stress and ductility. This i due to the increased size of the S phase, which increased the mismatch between the phase and the Al matrix. The result of the ductility can confirm this. Compared to a lowe Mg content, a higher Mg content produced finer grains. In general, a high Mg content i expected to produce a higher yield stress, contingent upon the Hall-Petch strengthening theory. However, this resulted in a comparison of the grain size to the particle size. Th argument is supported by the proportion of the grain size to the particle size. The percent age of high Mg content was approximately 8%, while the percentage of low Mg conten was 68%. This huge disparity in the grain-to-particle ratio justifies the effect of the particl size on the strength of the alloy. Nonetheless, the particle size inhibited recrystallization during the artificially aged process, even when the Mg content was doubled. This was du to the effect of the particle size on the process of recrystallisation. Based on the Mg corro sion ability, it was anticipated that a higher Mg content would increase the corrosion ac tivity, as shown in Figure 10. The corrosion activity was reduced due to the large particl size in the high Mg content alloy, which decreased the contact surface with the medium Furthermore, the S phase particle-strengthening contribution was analyzed for both alloy by using the Orowan strengthening model, as follows:

Discussion
The results section illustrates that Mg concentration has a significant influence on Al Cu-Mg-Ag alloys, as summarized in Table 2. Despite increasing the material's hardness Mg reduces yield stress and ductility. The XRD results and Thermo-Calc simulation wer used to identify the phases that formed on the alloys during the aging process. It is eviden that the S phase played a crucial role. It was dependent not only on the S phase quantity in the bulk but also on the phase size. The hardness result indicates that a high Mg conten increases the hardness of the alloy, while decreasing the yield stress and ductility. This i due to the increased size of the S phase, which increased the mismatch between the phase and the Al matrix. The result of the ductility can confirm this. Compared to a lowe Mg content, a higher Mg content produced finer grains. In general, a high Mg content i expected to produce a higher yield stress, contingent upon the Hall-Petch strengthening theory. However, this resulted in a comparison of the grain size to the particle size. Th argument is supported by the proportion of the grain size to the particle size. The percent age of high Mg content was approximately 8%, while the percentage of low Mg conten was 68%. This huge disparity in the grain-to-particle ratio justifies the effect of the particl size on the strength of the alloy. Nonetheless, the particle size inhibited recrystallization during the artificially aged process, even when the Mg content was doubled. This was du to the effect of the particle size on the process of recrystallisation. Based on the Mg corro sion ability, it was anticipated that a higher Mg content would increase the corrosion ac tivity, as shown in Figure 10. The corrosion activity was reduced due to the large particl size in the high Mg content alloy, which decreased the contact surface with the medium Furthermore, the S phase particle-strengthening contribution was analyzed for both alloy by using the Orowan strengthening model, as follows:

Discussion
The results section illustrates that Mg concentration has a significant influence on Al-Cu-Mg-Ag alloys, as summarized in Table 2. Despite increasing the material's hardness, Mg reduces yield stress and ductility. The XRD results and Thermo-Calc simulation were used to identify the phases that formed on the alloys during the aging process. It is evident that the S phase played a crucial role. It was dependent not only on the S phase quantity in the bulk but also on the phase size. The hardness result indicates that a high Mg content increases the hardness of the alloy, while decreasing the yield stress and ductility. This is due to the increased size of the S phase, which increased the mismatch between the S phase and the Al matrix. The result of the ductility can confirm this. Compared to a lower Mg content, a higher Mg content produced finer grains. In general, a high Mg content is expected to produce a higher yield stress, contingent upon the Hall-Petch strengthening theory. However, this resulted in a comparison of the grain size to the particle size. The argument is supported by the proportion of the grain size to the particle size. The percentage of high Mg content was approximately 8%, while the percentage of low Mg content was 68%. This huge disparity in the grain-to-particle ratio justifies the effect of the particle size on the strength of the alloy. Nonetheless, the particle size inhibited recrystallization during the artificially aged process, even when the Mg content was doubled. This was due to the effect of the particle size on the process of recrystallisation. Based on the Mg corrosion ability, it was anticipated that a higher Mg content would increase the corrosion activity, as shown in Figure 10. The corrosion activity was reduced due to the large particle size in the high Mg content alloy, which decreased the contact surface with the medium. Furthermore,

1.
The results showed that magnesium (Mg) has a significant impact on Al-Cu alloys, with increasing Mg content leading to increased hardness but reduced yield stress and ductility.

2.
The results indicated that a high Mg content resulted in finer grains and a larger S phase size, which caused a mismatch between the S phase and the aluminum matrix, leading to reduced yield stress and ductility. 3.
The grain-to-particle size ratio was found to be crucial in determining the strength of the alloy, with a high Mg content having a smaller ratio compared to a low Mg content. 4.
The particle size was found to inhibit grain growth during the artificial aging process, even when the Mg content was doubled.

5.
Despite being known for its corrosion ability, a high Mg content reduced corrosion activity due to the large particle size in the high Mg content alloy. 6.
As for future work, reducing the S phase size in the high Mg content might be useful in improving the properties of the Al-Cu-Ag alloys and the coherency of the S phase.
Overall, this study provides valuable insights into the impact of Mg on Al-Cu-Ag alloys and highlights the importance of further ways to explore reducing the S phase size in the high Mg content to improve the material's properties. In addition, a deep study of an Ag effect on the alloy might be useful in future work. Data Availability Statement: If needed, the corresponding author can provide access to the datasets generated and/or analyzed during the current study upon request that is deemed reasonable.