Reactivity of Rare-Earth Oxides in Anhydrous Imidazolium Acetate Ionic Liquids

: Rare-earth metal sesquioxides ( RE 2 O 3 ) are stable compounds that require high activation energies in solid-state reactions or strong acids for dissolution in aqueous media. Alternatively, dissolution and downstream chemistry of RE 2 O 3 have been achieved with ionic liquids (ILs), but typically with additional water. In contrast, the anhydrous IL 1-butyl-3-methylimidazolium acetate [BMIm][OAc] dissolves RE 2 O 3 for RE = La–Ho and forms homoleptic dinuclear metal complexes that crystallize as [BMIm] 2 [ RE 2 (OAc) 8 ] salts. Chloride ions promote the dissolution without being included in the compounds. Since the lattice energy of RE 2 O 3 increases with decreasing size of the RE 3+ cation, Ho 2 O 3 dissolves very slowly, while the sesquioxides with even smaller cations appear to be inert under the applied conditions. The Sm and Eu complex salts show blue and red photoluminescence and Van Vleck paramagnetism. The proton source for the dissolution is the imidazolium cation. Abstraction of the acidic proton at the C 2 -atom yields an N-heterocyclic carbene (imidazole-2-ylidene). The IL can be regenerated by subsequent reaction with acetic acid. In the overall process, RE 2 O 3 is dissolved by anhydrous acetic acid, a reaction that does not proceed directly.


Introduction
Rare earths, such as monazite, bastnasite, loparite and laterite clays, are the natural source of rare-earth elements and their compounds, which are essential, e.g., for luminophores, magnets, catalysts, superconductors, biomedical diagnosis, therapy, and environmental chemistry [1][2][3]. Although rare-earth elements are not as rare as their name suggests, their extraction is demanding, which has an impact on both price and environment. In the first production step, the phosphate mineral monazite is dissolved either in concentrated H 2 SO 4 at temperatures between 150 and 200 • C (acid process) or in 70% NaOH (basic process) at 140 to 150 • C using autoclaves. After this activation step, an elaborate procedure for the separation of the different metal species follows. Nowadays, the recycling of industrial and electronic waste has also become an important source of rare-earth metals. In many of these processes, rare-earth metal oxides occur as intermediate or final products. For any downstream chemistry, high temperatures or aggressive chemicals must again activate these stable oxides.
With the goal of establishing a more sustainable process, much research has been done in recent years on the chemistry of rare-earth compounds in ionic liquids (ILs) [4][5][6][7][8][9]. In most investigations, the focus lies on the development of new liquid extraction and separation techniques. Unfortunately, most ILs successfully tested for this purpose have severe weaknesses. First-generation ILs, such as [BMIm]Cl·nAlCl 3 ([BMIm] + = 1-n-butyl-3-methylimidazolium), are sensitive to air and moisture, which strongly limits their usefulness [10]. Super-acidic ILs combined with a stream of chlorine gas also dissolve rare-earth oxides [11]; however, using a highly toxic gas does not achieve the aim of green chemistry. Nevertheless, there are also some existing reports on the direct dissolution of rare-earth oxides in ILs [12][13][14][15][16][17]. Water-stable ILs containing Brønsted acidic groups, in particular the very effective IL [Hbet][NTf 2 ] ([Hbet] + = betainium, [NTf 2 ] − = bis(trifluoromethylsulfonyl)imide), are much more suitable. Its excellent dissolution power for metal oxides is based on the acidity of the [Hbet] + cation and the complexation capacity of the conjugate base (bet) [18]. The weakly coordinating anion [NTf 2 ] − , however, is expensive and ecologically questionable [19]. Moreover, these IL-based approaches typically involve water as a co-solvent. However, water narrows the electrochemical window and can have a detrimental effect on the subsequent chemistry.
In this work, we show that the anhydrous IL 1-butyl-3-methylimidazolium acetate [BMIm][OAc] can dissolve rare-earth oxides. Acetate, [OAc] − , is much cheaper than [NTf 2 ] − and ecologically harmless. Moreover, it has a complexing effect. Similarly, the nitrogen atoms in the positions 1 and 3 of the imidazole ring can form N-donor coordination complexes [20]. The proton at the C 2 -position of the ring is acidic and can be abstracted by a base. This generates an N-heterocyclic carbene (imidazole-2-ylidene), which can be functional in organo-catalytic reactions [21,22]. Imidazolium acetate ILs have been used to dissolve biomass, e.g., cellulose, and to store CO 2 [23][24][25][26].
It is known that traces of chloride, which is a strong nucleophile in most ILs, facilitate the dissolution of metal oxides [27,28] but also of covalently bonded substances such as red phosphorus [29][30][31]. We have also applied this here and succeeded in establishing an effective and inexpensive method for the chemical activation of RE 2 O 3 (RE = La-Ho, except the radioactive Pm) at moderate temperature, including the recycling of the IL. In addition, we crystallized anhydrous, homoleptic, dinuclear rare-earth metal complexes from these solutions and studied the magnetic and luminescence properties of the Eu and Sm complexes, which were previously synthesized from expensive anhydrous rare-earth metal trihalides [32].
[BDMIm] [OAc] was synthesized by mixing 20 mmol (3.75 g) of [BDMIm]Cl in 10 mL anhydrous ethanol with 50 mL of an ethanolic solution of 4.8 g potassium acetate under vigorous stirring at room temperature [33]. KCl 8 ] precipitate, the reacted IL contained a large portion of imidazole-2-ylidene, residuals of the dissolved complex as well as acetonitrile from the washing procedure. The IL was regenerated by mixing with a 2 mol L −1 solution of acetic acid in acetonitrile at room temperature under inert conditions. A white precipitate formed, which was centrifuged, and the supernatant liquid phase was pipetted off. Acetonitrile and excess acetic acid were evaporated off from the organic phase, first at 70 • C using a rotatory evaporator for 3 h and then at 100 • C on a Schlenk line under dynamic vacuum overnight.
Single-Crystal Structure Determination. Single-crystal X-ray diffraction data were collected on a four-circle Kappa APEX II CCD diffractometer (Bruker, Madison, WI, USA) with a graphite(002)-monochromator and a CCD detector using Mo-K α radiation (λ = 0.71073 Å) under flowing nitrogen gas at T = 100 (2) K. The data were corrected for background, Lorentz factor, and polarization factor using the APEX III software. Empirical multi-scan absorption correction was applied [35,36]. The structures were solved using SHELXT in OLEX2 [37,38]. SHELXL was used for refinement against F 2 [39,40]. Anisotropic displacement parameters were refined for all non-hydrogen atoms. H atoms were refined without constraints. The structure was visualized with the Diamond software Version 4.6.8 (Klaus Brandenburg, Bonn, Germany) [41].
NMR Spectroscopy. The samples were dissolved in deuterated DMSO-d6 and filled in an NMR tube. Measurements were performed on a Bruker Avance (Leipzig, Germany) Neo WB 300 MHz NMR spectrometer at resonance frequencies of 300 MHz for 1 H and 75.5 MHz for 13 C spectra. The chemical shifts were referenced externally according to tetramethylsilane (TMS) and were calibrated with 10% ethylbenzene in CDCl 3 as external reference. The signals in the spectra were assigned with the NMR Predictor from ACD/Labs [42].
UV-Vis Spectroscopy. The sample was a powder consisting of 10 mg of the complex salt and 100 mg of BaSO 4 . The spectra were recorded with a solid-state UV-Vis spectrophotometer Varian-4000 (Varian BV, Middelburg, The Netherland).
Emission Spectroscopy. Photoluminescence of powder samples was measured on a spectrofluorometer Fluoro Max-4r (Horiba scientific, Piscataway, NJ, USA). The light source was a xenon arc lamp with photomultiplier R928P detector.
IR Spectroscopy. FTIR spectra of liquid samples soon after dissolution (no visible precipitates) as well as a crystal of [BMIm] 2 [Eu 2 (OAc) 8 ] were measured on a Bruker Vertex 70 FTIR spectrophotometer (Bruker Optics GmbH, Ettlingen, Germany) with attenuated total reflection (ATR) accessory in the range from 500 to 4000 cm −1 , with 32 scans per measurement. The data were analyzed using the OPUS 6.5 software (Bruker, Ettlingen, Germany) [43].
Thermogravimetric Analysis (TGA) and Differential Scanning Calorimeter (DSC). The thermal stability of several complex salts was investigated with TGA using an STA 409 Luxx (Netzsch, Selb, Germany). The TGA experiments were carried out in the temperature range from 25 to 500 • C, with a heating rate of 5 K min −1 in an argon stream. The thermal effects upon heating with 5 K min −1 in an argon stream were determined using a DSC1 (Mettler Toledo GmbH, Giessen, Germany).
Magnetic Measurement. The magnetic susceptibility of the Sm and Eu complex salts were measured with helium-cooled mini-CFMS (Cryogenic, The Vale London, UK) equipped with a vibrating-sample magnetometer (VSM, The Vale London, UK) in the temperature range from 300 K to 2 K.

Dissolution of RE 2 O 3
In orienting experiments, we tested the dissolution of the comparatively inexpensive La 2 O 3 in seven phosphonium-or imidazolium-based ILs at 175 • C in closed flasks under argon (Table S1). Only in the case of [BMIm] [OAc] was no solid residue found after 48 h. Droplets of water condensed in the upper, colder part of the flask. After cooling the solution to room temperature, the complex compound [BMIm] 2 [La 2 (OAc) 8 ] crystallized within some days (see below). The only hydrogen source for the formation of water in this system is the acidic proton at the C 2 atom of the imidazolium cation. In fact, La 2 O 3 did not dissolve in 1-butyl-2,3-dimethyl imidazolium acetate, [BDMIm][OAc], which is methylated at the C 2 -position and thus has no acidic proton. The reaction is summarized in Equation (1): The deprotonated [BMIm] + cation is a N-heterocyclic carbene (imidazole-2-ylidene). This is sensitive to air at the reaction temperature, which leads to decomposition when the reaction is performed in a system open to the atmosphere. However, at room temperature the reactivity of the carbene is strongly reduced, allowing handling of the solution and separation of the solid product in air.
It is known that the basic acetate ion can abstract the acidic proton from the [BMIm] + cation and form acetic acid [44,45]. Remarkably, La 2 O 3 did not dissolve in neat acetic acid (100%) at 175 • C under argon. However, when La 2 O 3 was mixed with [BDMIm][OAc] and acetic acid, a vigorous reaction occurred already at room temperature, resulting in a white microcrystalline precipitate of a lanthanum complex that was soluble in water, partially soluble in ethanol, and insoluble in acetone (for PXRD see Figure S1). Obviously, the cation of the IL is necessary for the dissolution; through this, there is enough free acetate in the solution for the formation of the acetate complex, and a stable salt can be precipitated.
According to Equation (1), the molar ratio of RE 2 O 3 and [BMIm][OAc] must be at least 1:8. Since the IL is not only a reactant but also the solvent, an excess is advisable to avoid overly high viscosity. To still obtain fairly concentrated solutions, we kept the ratio of 1:10 for the subsequent experiments with RE 2 O 3 . In view of the catalytic effect of chloride on the dissolution of many metal oxides in ILs, we also repeated the dissolution experiments with admixtures of [BMIm]Cl in diverse molar ratios as the chloride source. A summary of the dissolution experiments performed can be found in Table S2.
Achieving complete dissolution below 150 • C proved difficult, as the viscosity increased with decreasing temperature, which affected the diffusion and wetting behavior of the IL. In addition, below 120 • C, abstraction of the proton from the substituted imidazolium cations was hindered [44].
The lighter RE 2 O 3 (RE = La-Nd) dissolved completely, also without the addition of chloride. However, chloride shortened the reaction time and the quality of the crystals was improved ( Figure S2), although chloride is not a component of the complex salt. For RE = Dy-Ho, the dissolution took much more time, especially without chloride. RE 2 O 3 with RE = Er-Lu, Sc, or Y did not react with [BMIm][OAc], even when the reaction time, the temperature, or the concentration of the IL was increased or chloride had been added ( Figure 1). Instead, decomposition of the IL was observed.
Such a dissolution behavior is well known and understood. In the series of RE 3+ cations, the effective ionic radius (for coordination number 9) decreases from 1.216 Å (La 3+ ) to 1.032 Å (Lu 3+ ) [46]. The smaller the RE 3+ cation, the shorter the cation-anion distance, the higher the lattice energy, and the poorer the solubility of the RE 2 O 3 . In the underlying case, the boundary is between 1.08 and 1.07 Å, with Ho (1.072 Å) showing poor solubility and Y (1.075 Å) and Er (1.062 Å) apparently none. CeO 2 , which has a much high lattice energy due to the higher cation charge, did not dissolve at all. Such a dissolution behavior is well known and understood. In the series of RE 3+ cations, the effective ionic radius (for coordination number 9) decreases from 1.216 Å (La 3+ ) to 1.032 Å (Lu 3+ ) [46]. The smaller the RE 3+ cation, the shorter the cation-anion distance, the higher the lattice energy, and the poorer the solubility of the RE2O3. In the underlying case, the boundary is between 1.08 and 1.07 Å, with Ho (1.072 Å) showing poor solubility and Y (1.075 Å) and Er (1.062 Å) apparently none. CeO2, which has a much high lattice energy due to the higher cation charge, did not dissolve at all. This behavior can be used for the separation of rare-earth elements. The four equimolar mixtures La2O3/Sc2O3, La2O3/Lu2O3, Eu2O3/Y2O3, and Eu2O3/CeO2 were treated at 175 °C in an IL consisting of [BMIm][OAc] and [BMIm]Cl (molar ratio of 10:1) for few hours. The unreacted solid was separated from the liquid, washed three times with acetonitrile, weighted, and analyzed with PXRD. In all cases, the diffraction patterns showed no evidence of the soluble oxide ( Figure S3), and the weight of the recovered insoluble oxide was within 1% of the original. From the separated solutions, the [BMIm]2[RE2(OAc)8] salts (RE = La, Eu) precipitated.

Regeneration of the Reacted Ionic Liquid
Under prolonged thermal stress, the dialkylimidazolium cations of the corresponding acetate ILs decompose into alkylated anions and imidazole derivatives [25,[47][48][49] (see also Section 3.4). The decomposition is the reverse reaction of the quaternization (reversed Menshutkin-like reaction). Further decomposition products result from the deprotonation of the C 2 -atom of the imidazolium ring by strong nucleophiles [50], as the resulting Nheterocyclic carbene reacts either with the IL or with other decomposition products [51]. However, the carbene formation is reversible, and the IL can be regenerated by the addition of acid. Irreversible decomposition of the IL can be largely avoided by heating at moderate temperature and for only short periods of time.
The regeneration of used [BMIm][OAc] ( Figure S4) was done by reaction with a solution of acetic acid in acetonitrile at room temperature under inert conditions. After evaporation of the acetonitrile and excess acetic acid, the recovered IL was analyzed spectroscopically. The FTIR spectra of neat and regenerated IL are almost identical ( Figure S5). In the 13 C and 1 H NMR spectra (Figure 2), no residual acetic acid and acetonitrile was found in the regenerated IL. Generally, the proton signal of acetic acid lies between 10 and 15 ppm, and that of acetonitrile near 2 ppm [52,53]. The decomposition products methyl acetate and 1-butylimidazole were also not detected. While the ester was likely cleaved in the treatment, the alkylimidazole likely precipitated as a coordination compound (white precipitate, see Materials and Methods).

Regeneration of the Reacted Ionic Liquid
Under prolonged thermal stress, the dialkylimidazolium cations of the corresponding acetate ILs decompose into alkylated anions and imidazole derivatives [25,[47][48][49] (see also Section 3.4). The decomposition is the reverse reaction of the quaternization (reversed Menshutkin-like reaction). Further decomposition products result from the deprotonation of the C 2 -atom of the imidazolium ring by strong nucleophiles [50], as the resulting N-heterocyclic carbene reacts either with the IL or with other decomposition products [51]. However, the carbene formation is reversible, and the IL can be regenerated by the addition of acid. Irreversible decomposition of the IL can be largely avoided by heating at moderate temperature and for only short periods of time.
The regeneration of used [BMIm][OAc] ( Figure S4) was done by reaction with a solution of acetic acid in acetonitrile at room temperature under inert conditions. After evaporation of the acetonitrile and excess acetic acid, the recovered IL was analyzed spectroscopically. The FTIR spectra of neat and regenerated IL are almost identical ( Figure S5). In the 13 C and 1 H NMR spectra ( Figure 2), no residual acetic acid and acetonitrile was found in the regenerated IL. Generally, the proton signal of acetic acid lies between 10 and 15 ppm, and that of acetonitrile near 2 ppm [52,53]. The decomposition products methyl acetate and 1-butylimidazole were also not detected. While the ester was likely cleaved in the treatment, the alkylimidazole likely precipitated as a coordination compound (white precipitate, see Materials and Methods).
No solid residue remained after combustion of the regenerated IL in air. The 13 C NMR spectra of regenerated and neat IL showed no difference as long as the freshly regenerated IL was stored under inert conditions (sample A). After some time in air (sample B), the 1 H NMR spectrum of the regenerated IL showed a broad resonance signal at 5 ppm, which can be attributed to H 2 O, and also an up-field shift of the protons at C 2 , C 4 , and C 5 . The same effect was observed when water was added to the freshly regenerated IL ( Figure S6) as has been reported previously [54,55]. The new signals marked with asterisks in the spectra of (B) indicate a decomposition product. This is probably due to the small amount of carbene that is formed by the internal acid-base equilibrium between [BMIm] + and [OAc] − (Section 3.4). No solid residue remained after combustion of the regenerated IL in air. The 13 C NMR spectra of regenerated and neat IL showed no difference as long as the freshly regenerated IL was stored under inert conditions (sample A). After some time in air (sample B), the 1 H NMR spectrum of the regenerated IL showed a broad resonance signal at 5 ppm, which can be attributed to H2O, and also an up-field shift of the protons at C 2 , C 4 , and C 5 . The same effect was observed when water was added to the freshly regenerated IL ( Figure S6) as has been reported previously [54,55]. The new signals marked with asterisks in the spectra of (B) indicate a decomposition product. This is probably due to the small amount of carbene that is formed by the internal acid-base equilibrium between [BMIm] + and [OAc] − (Section 3.4).
The washed crystals of [BMIm]2[RE2(OAc)8] are air-stable (thick) platelets and appear colorless, except the light-green Pr salt. In the case of the Pr and Dy compounds, the platelet-shaped crystals transformed into thin needles within a day when stored in the reacted IL in air at 10 °C ( Figure S8). The powder diffractogram and the IR spectra of the platelets and the needles clearly differ (Figures S9 and S10). Subsequently, the needles turned into yellowish translucent flakes that decompose into dark brown microscale needles within several days.
The structure of plate-like crystals was determined with single-crystal X-ray diffraction (Table S3). As the sum formula suggests, the compounds consist of [BMIm] + cations and negatively charged [RE2(OAc)8] 2− complexes. Nine oxygen atoms of acetate anions coordinate each RE 3+ cation in the shape of a distorted tricapped trigonal prism (Figure 3).  [26]. M and C represent the methyl and carboxylic groups of acetate. The asterisk sign * indicates the decomposition product in regenerated IL in air (B). Deuterated DMSO-d6 was used for diluting all samples.
Unlike many other complexes obtained from RE 2 O 3 and ILs, these are anhydrous compounds. Up to now, such anhydrous complexes were made from anhydrous chlorides, nitrates, or acetates, i.e., starting materials that must be synthesized and are much more expensive than the oxides [56][57][58].
The washed crystals of [BMIm] 2 [RE 2 (OAc) 8 ] are air-stable (thick) platelets and appear colorless, except the light-green Pr salt. In the case of the Pr and Dy compounds, the plateletshaped crystals transformed into thin needles within a day when stored in the reacted IL in air at 10 • C ( Figure S8). The powder diffractogram and the IR spectra of the platelets and the needles clearly differ (Figures S9 and S10). Subsequently, the needles turned into yellowish translucent flakes that decompose into dark brown microscale needles within several days.
The structure of plate-like crystals was determined with single-crystal X-ray diffraction (Table S3). As the sum formula suggests, the compounds consist of [BMIm] + cations and negatively charged [RE 2 (OAc) 8 ] 2− complexes. Nine oxygen atoms of acetate anions coordinate each RE 3+ cation in the shape of a distorted tricapped trigonal prism ( Figure 3). The RE-O bond length develops according to the effective radii of the RE 3+ cations (Table S4). The carboxylate groups of the acetate anions coordinate in three different modes ( Figure 4). The two RE 3+ anions are connected through four carboxylate groups.
The salts [BMIm] 2 [RE 2 (OAc) 8 ] adopt two different types of crystal structure, depending on the size of the rare-earth (RE) cation. Both structure types have triclinic symmetry (space group type P − 1) and contain two formula units in the unit cell; however, their lattice translations are very different. Bond lengths (Table S5) and the basic arrangements of the molecules are similar in the two structure types, but they differ in translational and molecular point symmetry. Figure S11 shows analogous subcells of the two structure types, reduced to the RE 3+ cations. Their positions relative to the locations of the inversion centers differ in the two cases. Translational pseudosymmetry is observed (B-centering for RE = La-Pr and A-centering for RE = Nd-Ho). Yet, there are clear superstructure reflections that corroborate the primitive Bravais lattices.
Chemistry 2023, 5, FOR PEER REVIEW 7 S4). The carboxylate groups of the acetate anions coordinate in three different modes (Figure 4). The two RE 3+ anions are connected through four carboxylate groups.
(a) (b)  The salts [BMIm]2[RE2(OAc)8] adopt two different types of crystal structure, depending on the size of the rare-earth (RE) cation. Both structure types have triclinic symmetry (space group type P1 ) and contain two formula units in the unit cell; however, their lattice translations are very different. Bond lengths (Table S5) and the basic arrangements of the molecules are similar in the two structure types, but they differ in translational and molecular point symmetry. Figure S11 shows analogous subcells of the two structure types, reduced to the RE 3+ cations. Their positions relative to the locations of the inversion centers differ in the two cases. Translational pseudosymmetry is observed (B-centering for RE = La-Pr and A-centering for RE = Nd-Ho). Yet, there are clear superstructure reflections that corroborate the primitive Bravais lattices.
For RE = La-Pr, the anionic [RE2(OAc)8] 2− complex is non-centrosymmetric, with two crystallographically independent RE atoms. However, it has a pseudo-center of inversion. The two crystallographically distinct [BMIm] + cations show a combined disorder. The majority position of one cation is connected to the minority position of the other cation by the pseudo-inversion. The fact that there are two positions for the [BMIm] + cation that can be alternatively occupied without significant impact on the position of the anions suggests that the complexes form a packing that includes larger cavities than needed for the organic cations.
In the second structure type, which is adopted by the compounds RE = Nd-Ho, the [RE2(OAc)8] 2− complexes are truly centrosymmetric. The packing is slightly different, and    (Table S5) and the b molecules are similar in the two structure types, but they differ lecular point symmetry. Figure S11   For RE = La-Pr, the anionic [RE 2 (OAc) 8 ] 2− complex is non-centrosymmetric, with two crystallographically independent RE atoms. However, it has a pseudo-center of inversion. The two crystallographically distinct [BMIm] + cations show a combined disorder. The majority position of one cation is connected to the minority position of the other cation by the pseudo-inversion. The fact that there are two positions for the [BMIm] + cation that can be alternatively occupied without significant impact on the position of the anions suggests that the complexes form a packing that includes larger cavities than needed for the organic cations.
In the second structure type, which is adopted by the compounds RE = Nd-Ho, the [RE 2 (OAc) 8 ] 2− complexes are truly centrosymmetric. The packing is slightly different, and the [BMIm] + cations are ordered. Thus, it could be argued that this packing is more efficient than the first; however, there is no unusual reduction in the volume of the unit cell when changing the structure type from the Pr to the Nd compound.

(H 2 O) 2 ] 6+
can dissociate into mononuclear units in ILs [59]. It could therefore be argued that, also in the underlying case, the dissolved species might be mononuclear. Acetates have been studied extensively with vibrational spectroscopy. Among the 15 active infrared frequencies in acetate ions, the symmetric and asymmetric stretching frequencies of the carboxylic group were analyzed using FTIR spectroscopy. The spectra of various RE 2 O 3 dissolved in the IL as well as of crystalline [BMIm] 2 [Eu 2 (OAc) 8 ] show additional bands along with shifted and split bands of the neat IL ( Figure 5).
[RE2(bet)8(H2O)2] 6+ can dissociate into mononuclear units in ILs [59 argued that, also in the underlying case, the dissolved species migh etates have been studied extensively with vibrational spectroscopy infrared frequencies in acetate ions, the symmetric and asymmetric of the carboxylic group were analyzed using FTIR spectroscopy. T RE2O3 dissolved in the IL as well as of crystalline [BMIm]2[Eu2(O bands along with shifted and split bands of the neat IL ( Figure 5). The C-H stretching frequencies of the organic cation in nea about 3000 cm −1 , e.g., νas(CH2) = 2952, νas(CH3) = 2932, and νs(CH3) an The asymmetric νas and symmetric νs stretching frequencies of the found at 1575 and 1385 cm −1 [60]. For the solutions and the complex carboxylic group are slightly shifted and split or broadened accord ordination modes of the acetate ion. Nakamoto et al. showed that th coordination is related to the difference of νas-νs [61]. Since the div reliably assigned to the different coordination modes, further eval Nonetheless, the differences in the FTIR spectra suggest that the can differ from the crystallized one [62]. The broad bands at about 3 of the solutions indicate the water formed during the dissolution o system was kept open during the reaction, this led to the decom shown by the FTIR spectrum in Figure S12.
Using 13 C and 1 H NMR spectroscopy (Figure 6), we compared S4): the unreacted IL, a freshly prepared solution of La2O3 in [BMIm precipitation had occurred, and the supernatant of a solution from w had precipitated and which had been stored in air for several mont solution containing decomposition products of [BMIm][OAc] after for 4 days at 175 °C was investigated ( Figure S13). The asymmetric ν as and symmetric ν s stretching frequencies of the carboxylic group are found at 1575 and 1385 cm −1 [60]. For the solutions and the complex salt, the signals of the carboxylic group are slightly shifted and split or broadened according to the diverse coordination modes of the acetate ion. Nakamoto et al. showed that the nature of the acetate coordination is related to the difference of ν as -ν s [61]. Since the diverse signals cannot be reliably assigned to the different coordination modes, further evaluation is not possible. Nonetheless, the differences in the FTIR spectra suggest that the complexes in solution can differ from the crystallized one [62]. The broad bands at about 3400 cm −1 in the spectra of the solutions indicate the water formed during the dissolution of the oxides. When the system was kept open during the reaction, this led to the decomposition of the IL, as shown by the FTIR spectrum in Figure S12.
Using 13 C and 1 H NMR spectroscopy (Figure 6), we compared three samples ( Figure S4): the unreacted IL, a freshly prepared solution of La 2 O 3 in [BMIm][OAc] from which no precipitation had occurred, and the supernatant of a solution from which the complex salt had precipitated and which had been stored in air for several months. In addition, a dark solution containing decomposition products of [BMIm][OAc] after heating La 2 O 3 in the IL for 4 days at 175 • C was investigated ( Figure S13).
In the 13 C and 1 H NMR spectra of the freshly reacted solution, methyl acetate and 1-butylimidazole are identified as decomposition products known from the literature [25,63,64]. 13 C NMR-DEPT-135 spectroscopy (DEPT = Distortionless Enhancement by Polarization Transfer; Figure S14) supports the assignment of the signals. The 13 C NMR signal of the carboxylic group at 175 ppm is broadened and drastically reduced. Since the signal of the methyl group of acetate is still intense, we attribute this effect to the interaction with the La 3+ cations. A closer look into the 1 H NMR spectrum shows also the presence of water at 5.7 ppm. However, no sign of the formation of BMIm-2-ylidene or its reaction products could be found, although it must have formed at least intermediately. Although dimerization according to the Wanzlick equilibrium is not expected for this type of N-heterocyclic carbene [65,66], it cannot be excluded that the high reaction temperature allows for it. In the 13 C and 1 H NMR spectra of the freshly reacted solution, methyl acetate and 1butylimidazole are identified as decomposition products known from the literature [25,63,64]. 13 C NMR-DEPT-135 spectroscopy (DEPT = Distortionless Enhancement by Polarization Transfer; Figure S14) supports the assignment of the signals. The 13 C NMR signal of the carboxylic group at 175 ppm is broadened and drastically reduced. Since the signal of the methyl group of acetate is still intense, we attribute this effect to the interaction with the La 3+ cations. A closer look into the 1 H NMR spectrum shows also the presence of water at 5.7 ppm. However, no sign of the formation of BMIm-2-ylidene or its reaction products could be found, although it must have formed at least intermediately. Although dimerization according to the Wanzlick equilibrium is not expected for this type of N-heterocyclic carbene [65,66], it cannot be excluded that the high reaction temperature allows for it.
The 1 H NMR spectrum of the aged supernatant shows only weak and broadened resonances, while the 13 C NMR signals are still sharp. We attribute this to a higher water content that has accumulated in the hygroscopic IL during the long period of exposure to the air. With a higher water content, the water signals shift to 4.7 ppm. The influence of the water concentration on the NMR signal is shown in Figure S6. Remarkably, the 13 C NMR signals of the [BMIm] + cation are still visible, but no corresponding (carbon-based) anion can be identified.

Stability of the Complex Salts
The [BMIm]2[RE2(OAc)8] complexes were obtained as single-phase products, allowing their further chemical and physical characterization. Since no decomposition was observed by visual inspections over a period of ten months, the washed crystals can be con- The 1 H NMR spectrum of the aged supernatant shows only weak and broadened resonances, while the 13 C NMR signals are still sharp. We attribute this to a higher water content that has accumulated in the hygroscopic IL during the long period of exposure to the air. With a higher water content, the water signals shift to 4.7 ppm. The influence of the water concentration on the NMR signal is shown in Figure S6. Remarkably, the 13 C NMR signals of the [BMIm] + cation are still visible, but no corresponding (carbon-based) anion can be identified.

Stability of the Complex Salts
The [BMIm] 2 [RE 2 (OAc) 8 ] complexes were obtained as single-phase products, allowing their further chemical and physical characterization. Since no decomposition was observed by visual inspections over a period of ten months, the washed crystals can be considered stable under ambient conditions. In contrast, unwashed samples are degraded to an unknown product ( Figure S15).
The thermal stability in argon atmosphere of washed [BMIm] 2 [RE 2 (OAc) 8 ] crystals (RE = Pr, Sm, Eu, Dy) was investigated with a differential scanning calorimeter (DSC) and thermogravimetric analysis (TGA) in the temperature range from 25 to 500 • C. All samples showed a two-step decomposition (Figure 7a), with a uniform onset temperature of 250 • C for first weight loss of 54.3%. Remarkably, the decomposition of imidazolium-based ILs was reported to start at 216 • C in argon atmosphere, resulting in complete evaporation of all fragments at 300 • C [67]. In a second step starting at about 330 • C and up to the maximum temperature of 500 • C, the mass was reduced further by 8% of the initial mass. The residual of 37.7% of the initial mass matches the calculated mass of Eu 2 O 2 CO 3 (37.5%), whose formation under similar conditions has been described previously [62]. The PXRD patterns of the solid residual shows a poorly crystalline material, which could be Eu 2 O 2 CO 3 ( Figure S16). The DSC thermograms of the [BMIm] 2 [Eu 2 (OAc) 8 complex salt shows a sharp endothermic transition at 167 • C, which indicates melting of the compound, and a broad endothermic effect starting above 220 • C, which is associated with its decomposition (Figure 7b).
showed a two-step decomposition (Figure 7a), with a uniform onset temperature of 250 °C for first weight loss of 54.3%. Remarkably, the decomposition of imidazolium-based ILs was reported to start at 216 °C in argon atmosphere, resulting in complete evaporation of all fragments at 300 °C [67]. In a second step starting at about 330° C and up to the maximum temperature of 500 °C, the mass was reduced further by 8% of the initial mass. The residual of 37.7% of the initial mass matches the calculated mass of Eu2O2CO3 (37.5%), whose formation under similar conditions has been described previously [62]. The PXRD patterns of the solid residual shows a poorly crystalline material, which could be Eu2O2CO3 ( Figure S16). The DSC thermograms of the [BMIm]2[Eu2(OAc)8 complex salt shows a sharp endothermic transition at 167 °C, which indicates melting of the compound, and a broad endothermic effect starting above 220 °C, which is associated with its decomposition (Figure 7b).

Photoluminescence of the Eu and Sm Salts
Isolation of the homoleptic dinuclear rare-earth complexes as single-phase materials allowed us to characterize their optical properties. The UV-Vis spectra of

Photoluminescence of the Eu and Sm Salts
Isolation of the homoleptic dinuclear rare-earth complexes as single-phase materials allowed us to characterize their optical properties. The UV-Vis spectra of [BMIm] 2 [Eu 2 (OAc) 8 ] and [BMIm] 2 [Sm 2 (OAc) 8 ] showed broad absorption bands at 214 and 261 nm (Figure 8). This absorptions correspond to π→π* transitions of the IL cation [68]. The absorption bands observed above 350 nm were assigned to the absorption bands of the respective rare-earth metal cations.
°C for first weight loss of 54.3%. Remarkably, the decomposition of imidazolium-based ILs was reported to start at 216 °C in argon atmosphere, resulting in complete evaporation of all fragments at 300 °C [67]. In a second step starting at about 330° C and up to the maximum temperature of 500 °C, the mass was reduced further by 8% of the initial mass. The residual of 37.7% of the initial mass matches the calculated mass of Eu2O2CO3 (37.5%), whose formation under similar conditions has been described previously [62]. The PXRD patterns of the solid residual shows a poorly crystalline material, which could be Eu2O2CO3 ( Figure S16). The DSC thermograms of the [BMIm]2[Eu2(OAc)8 complex salt shows a sharp endothermic transition at 167 °C, which indicates melting of the compound, and a broad endothermic effect starting above 220 °C, which is associated with its decomposition (Figure 7b).

Photoluminescence of the Eu and Sm Salts
Isolation of the homoleptic dinuclear rare-earth complexes as single-phase materials allowed us to characterize their optical properties. The UV-Vis spectra of   (Figure 9). Rare-earth metal ions can show strong luminescence due to transitions involving their 4f orbitals. A narrow emission band is characteristic of metalorganic complexes [69], in which the organic ligand absorbs energy and the intramolecular transfer of this energy from π* or n* to the next closest 4f level occurs (antenna effect). The intensity of the photoluminescence depends on the energy gap between the singlet S1 and the triplet state of the ligand, and the band gap between the triplet T1 and the 4f resonance states of the metal cation. Geometry and electronic features of the rare-earth metal complex influence the emission of spectra [7,70]. The coordination of polar molecules reduces the lifetime of the luminescence and the quantum yields. The depopulation of excited states takes place through the vibronic coupling of X-H oscillators (X = N, C, O) [71].
ing their 4f orbitals. A narrow emission band is characteristic of metalorga [69], in which the organic ligand absorbs energy and the intramolecular energy from π* or n* to the next closest 4f level occurs (antenna effect). T the photoluminescence depends on the energy gap between the singlet S1 state of the ligand, and the band gap between the triplet T1 and the 4f reso the metal cation. Geometry and electronic features of the rare-earth metal ence the emission of spectra [7,70]. The coordination of polar molecules r time of the luminescence and the quantum yields. The depopulation of exci place through the vibronic coupling of X-H oscillators (X = N, C, O) [71].
( Figure 9). Rare-earth metal ions can show strong luminescence due to transitions involving their 4f orbitals. A narrow emission band is characteristic of metalorganic complexes [69], in which the organic ligand absorbs energy and the intramolecular transfer of this energy from π* or n* to the next closest 4f level occurs (antenna effect). The intensity of the photoluminescence depends on the energy gap between the singlet S1 and the triplet state of the ligand, and the band gap between the triplet T1 and the 4f resonance states of the metal cation. Geometry and electronic features of the rare-earth metal complex influence the emission of spectra [7,70]. The coordination of polar molecules reduces the lifetime of the luminescence and the quantum yields. The depopulation of excited states takes place through the vibronic coupling of X-H oscillators (X = N, C, O) [71].   (Figure 10). The excitation spectrum of the Eu compound was monitored at 615 nm, that is, the emission of Eu 3+ ( 5 D0 → 7 F2). A series of intense and narrow lines was observed (in nm): 361, 367 ( 7 F0 → 5 D4), 374 ( 7 F0/1 → 5 Gj), 381, 385 ( 7 F0/1 → 5 L7, 5 Gj), 396 ( 7 F0 → 5 L6), 416 ( 7 F0 → 5 D3), and 465 ( 7 F0 → 5 D2). The most prominent excitations are at 396 and 465 nm, which is similar to the excitation spectrum of Eu(DCA)3 [5]. Using the excitation at 396 nm, the emission spectrum showed lines at (in nm): 580 ( 5 D0 → 7 F0), 592 ( 5 D0 → 7 F1), 615 ( 5 D0 → 7 F2), and 651 ( 5 D0 → 7 F3), while the ( 5 D0 → 7 F4) transition band composed of two stark sublevels at 687 nm and 697 nm under the electric field (crystal field) were observed [72][73][74]. The very sharp 5 D0 → 7 F2 transition is more intense than 5 D0 → 7 F1. This correlates with a Eu 3+ cation in a distorted tricapped trigonal prism [5].  In the case of the Sm complex salt, the excitation spectra were measured at 455 nm. The entire excitation spectrum is composed of multiple broad bands, ranging from 270 to 420 nm, most likely due to inefficient energy transfer from the ligand to the Sm 3+ cation. The maximum excitation was observed at 396 nm. The emission lines are also broad, with overlapping bands ranging from 400 to 700 nm. Commonly, Sm 3+ emits orange-red light, but in [BMIm] 2 [Sm 2 (OAc) 8 ], the emission band is in the blue region, which cannot be explained without further investigations. Energy transfer from the imidazolium cation, which shows fluorescence between 250 and 400 nm [68], may be involved.

Magnetism of the Eu and Sm Salts
The rare-earth metal ions show magnetism mainly due to the interelectron repulsion and spin-orbit coupling. Strong spin-orbit coupling can also affect the degenerate state of the lanthanides and split them into 2S+1 L J multiplets that further split into Stark levels through the crystal field. The magnetic property of the rare-earth ions thus depends on the splitting and thermal population of the resulting states.  8 ], an increase of the magnetic susceptibility with decreasing temperature to a plateau below 100 K was observed. This behavior is consistent with Van Vleck paramagnetism [75], commonly observed for Eu 3+ -containing compounds. The increase in χ m below 15 K could be explained by traces of Eu 2+ ions, as has been observed in dinuclear europium complexes before [76].
In the case of the Sm complex salt, the excitation spectra were measu The entire excitation spectrum is composed of multiple broad bands, rangi 420 nm, most likely due to inefficient energy transfer from the ligand to th The maximum excitation was observed at 396 nm. The emission lines are al overlapping bands ranging from 400 to 700 nm. Commonly, Sm 3+ emits ora but in [BMIm]2[Sm2(OAc)8], the emission band is in the blue region, which plained without further investigations. Energy transfer from the imidaz which shows fluorescence between 250 and 400 nm [68], may be involved.

Magnetism of the Eu and Sm Salts
The rare-earth metal ions show magnetism mainly due to the interelec and spin-orbit coupling. Strong spin-orbit coupling can also affect the dege the lanthanides and split them into 2S+1 LJ multiplets that further split int through the crystal field. The magnetic property of the rare-earth ions thu the splitting and thermal population of the resulting states.  8], an increase of the magnetic susceptibility w temperature to a plateau below 100 K was observed. This behavior is consi Vleck paramagnetism [75], commonly observed for Eu 3+ -containing compo crease in χm below 15 K could be explained by traces of Eu 2+ ions, as has bee dinuclear europium complexes before [76]. Generally, only the electronic ground states are occupied at low and r tures in the free rare-earth metal ions due to the larger-than-kBT energy spl the multiplets [77]. However, the Eu 3+ (4f 6 ) and Sm 3+ (4f 5 ) complexes are exce show temperature-independent van Vleck contributions to the susceptibili tive sign for this behavior is a significant curvature in the inverse susceptibil is observed for both samples (Figures S18 and S19). Due to a small energ between the ground and the first excited state, the latter is substantially higher temperatures [79,80]  Generally, only the electronic ground states are occupied at low and room temperatures in the free rare-earth metal ions due to the larger-than-k B T energy splitting between the multiplets [77]. However, the Eu 3+ (4f 6 ) and Sm 3+ (4f 5 ) complexes are exceptions, as they show temperature-independent van Vleck contributions to the susceptibility. The indicative sign for this behavior is a significant curvature in the inverse susceptibility [78], which is observed for both samples (Figures S18 and S19). Due to a small energetic difference between the ground and the first excited state, the latter is substantially populated at higher temperatures [79,80]. At 300 K, χ m T is 2.37 emu K mol − 8 ]. χ m T decreases continuously with decreasing temperature, which is caused by the depopulation of excited states. At low temperatures, a rigid linear change is still observed, where the product χ m T remains nonzero due to the thermal population of the first excited state [79]. The effective magnetic moment per Eu 3+ ion of 3.02 µ B at 0.1 T in the high-temperature region decreases to 0.15 µ B without a field using the molar susceptibility at 300 K. The effective magnetic moment per Sm 3+ ion is 2.40 µ B at 0.1 T. Similar values were found in the literature [58,79,81].

Conclusions
A straightforward approach was used for the study of anhydrous dissolution of RE 2 O 3 in an imidazolium acetate ionic liquid. The fact that the use of water can be avoided opens up new possibilities for downstream chemistry. The proton source for the dissolution is the imidazolium cation. Abstraction of the acidic proton at the C 2 -atom yields an N-heterocyclic carbene (imidazole-2-ylidene). The used IL can be regenerated by reaction with acetic acid. Chloride promotes the dissolution, especially for the heavier RE 2 O 3 (RE = Gd-Ho), although it is not included in the precipitating salts [BMIm] 2 [RE 2 (OAc) 8 ] (RE = La-Ho). The latter contain anhydrous, homoleptic, dinuclear complexes. The samarium and europium complex salts show blue and red photoluminescence, respectively. They are paramagnetic, with substantial van Vleck contributions.
Supplementary Materials: The following supporting information can be downloaded at: https: //www.mdpi.com/article/10.3390/chemistry5020094/s1, Table S1. Results of reactions of 1 mmol La 2 O 3 with 10 mmol of various imidazolium or phosphonium-based ILs. Table S2. Reaction parameters of RE 2 O 3 used in this work. Figure S1. PXRD pattern of the white microcrystalline precipitate formed by the reaction of La 2 O 3 with [BDMIm] [OAc] and acetic acid at room temperature together with the patterns of some reference compounds. Figure Figure S9. PXRD diffractogram measured at 100 K of [BMIm] 2 [Dy 2 (OAc) 8 ] crystals grown at room temperature or at 5 • C. Figure S10. FTIR spectra of the IL and [BMIm] 2 [Dy 2 (OAc) 8 ] crystals grown at room temperature or at 5 • C. Table S3. Crystallographic data for [BMIm] 2 [RE 2 (OAc) 8 ] salts at 100(2) K. Table S4. Metal-metal and metal-oxygen bond distances of all complexes studied in this work. Table S5. Selected interatomic distances in the Eu and La compounds, which belong to different structure types. Figure