The Development of a New Thermoplastic Elastomer (TPE)-Modiﬁed Asphalt

: The use of (recycled) plastics and (waste) vulcanized rubber powder is the main polymer of raw materials, and composite organic additives are selected to fully combine with asphalt components. The physical and chemical reactions between different components are completed in dynamic mixing, establishing a morphology structure similar to thermoplastic elastomers (TPEs), and a thermoplastic highly asphaltized alloy material. TPE-modiﬁed asphalt not only signiﬁcantly improves the high-temperature stability of the base asphalt, but also has the social and economic value of rational utilization of resources and turning waste into treasure. There are very few studies on the preparation of modiﬁed high-viscosity asphalt formulations using rubber and plastic as modiﬁers. In this study, rubber, plastic, and plasticizers were added to the base asphalt, and the TPE modiﬁer formulations were developed through the research of new TPE modiﬁer series and functional formulations, preparation process, and its modiﬁed asphalt properties. Meanwhile, the preparation method of the rubber–plastic alloy modiﬁer was determined. The performance of the TPE-modiﬁed asphalt was veriﬁed through performance veriﬁcation tests to evaluate the modiﬁcation effect of the modiﬁer on the base asphalt. The test results showed that the penetration, softening point, ductility, and viscosity indexes of the TPE-modiﬁed asphalt developed through the proposed formulation, and it met the speciﬁcation requirements for high-viscosity modiﬁed asphalt. Rubber and plastic modiﬁers signiﬁcantly improved the high-temperature stability of the base asphalt. In addition, the rubber–plastic modiﬁer had a signiﬁcant tackifying effect, with a dynamic viscosity of 60 ◦ C and a Brinell rotational viscosity much greater than asphalt and rubber asphalt. The microscopic mechanism of the newly developed TPE-modiﬁed asphalt was analyzed by ﬂuorescence microanalysis. The results showed that the rubber–plastic modiﬁer fully swelled in the asphalt and was uniformly dispersed in the asphalt as a ﬂoc. The network structure of activated waste rubber powder-modiﬁed asphalt was more uniform and dense, resulting in good performance of the modiﬁed asphalt, and stable storage of modiﬁed asphalt was obtained. Through appropriate formulation, the comprehensive performance of the TPE-modiﬁed asphalt obtained met the requirements of pavement application and construction, providing a good theoretical basis for promoting TPE-modiﬁed asphalt.


Introduction
Currently, various waste rubber products and waste plastic products (commonly known as waste rubber and plastic materials) and other materials are increasing in quantity. The amount of waste rubber and tires produced each year is conservatively estimated to be over 15 million tons. With a production of plastic goods that exceeds 21 million tons yearly and is growing at a rate of around 10% annually. China is another important plastics-producing nation in the world. A large amount of waste gradually intensifies "black pollution" and "white pollution", which inevitably result in more catastrophic social and environmental issues [1]. rubber tires through dynamic vulcanization process, whether pure or combined with original styrene butadiene copolymer, including different proportions of dicarboxylic peroxide and isophthalimide imide (BMI). This blend exhibited excellent ultimate tensile strength and elongation at break, comparable to other thermoplastic vulcanization systems, and also exhibited good reprocessing properties, which were useful for several potential applications [13]. Nizamuddin et al. studied how the use of innovative compatibilizers can help stabilize recycled rubber-plastic asphalt mixtures during high-temperature storage. At the same time, the storage stability, rheological properties, thermal properties, and physical properties of rubber and recycled low-density polyethylene composite-modified asphalt were studied in the presence and absence of compatibilizers [14].
While studying waste rubber-plastic alloy-modified asphalt, many scholars successfully borrowed the concept of "alloy" and proposed the proposition of preparing rubber-plastic alloy modifiers and rubber-plastic alloy-modified asphalt [15]. Wang et al. studied the technical performance of PE/waste rubber powder-modified asphalt and demonstrated that it is reasonable to analyze and evaluate the technical performance of composite-modified asphalt through the Strategic Highway Research Program (SHRP) binder specification [4]. Mulage prepared modified asphalt using rubber powder and waste plastics (polypropylene and polyethylene), and studied the reaction mechanism of composite modified asphalt [16]. Maw et al. compared and analyzed TPE-modified asphalt with SBS-modified asphalt, and found that some formulations of TPE-modified asphalt had better high-temperature performance than SBS-modified asphalt, but the addition of TPE would reduce the low-temperature performance of asphalt [17]. Reddy et al. further studied and added rubber powder, PE, rock asphalt, and SBR to the base asphalt for composite modification to obtain a high-viscosity modified asphalt. Through road performance verification, it was found that the performance of the OGFC mixture was excellent [18]. Xu et al. prepared three types of rubber-plastic modifiers and modified asphalt, and conducted road performance tests for three types of modified asphalt. Xu et al. mainly conducted research on the road performance of rubber and plastic alloy-modified asphalt, and its conclusions indicate that as a new modified material, rubber-plastic alloy-modified asphalt has no less high-temperature performance than SBS-modified asphalt, but also good low-temperature performance. Based on the component analysis of waste rubber powder and waste plastics, Ki et al. prepared waste rubber-plastic alloy modifiers with different rubber-plastic ratios, analyzed the modification mechanism of waste rubber-plastic alloy modifiers on base asphalt, and tested the technical performance and storage stability of waste rubber-plastic alloy-modified asphalt [19]. The results showed that when the rubber-plastic ratio was 7:3, the waste rubber powder and waste plastic had good compatibility; the blending process of waste rubber and waste plastics and the modification process of base asphalt by waste rubber-plastic alloy modifiers are mainly physical effects; The waste rubber-plastic alloy modifier has good compatibility with the base asphalt, significantly improving the road performance of the base asphalt [20]. Chen et al. studied the effect of raw material quality ratio on the performance of thermoplastic elastomermodified asphalt. The experimental results indicated that the mass ratio of water-based adhesive powder and SBS had a more important impact on the permeability, softening point and ductility, viscosity, high-temperature storage performance, elastic recovery rate, and dynamic rheological properties of TPE-modified asphalt [21].
In recent years, some scholars have conducted systematic research on waste rubber powder-modified asphalt. However, there is a gap between the performance of modified asphalt modified with rubber powder alone and that of SBS-modified asphalt [22]. For instance, as the subject of current research, the high-temperature softening point index of SBS-modified asphalt can reach about 80 • C, while rubber powder-modified asphalt usually only reaches about 60 • C; the low-temperature ductility index is also lower than that of SBS-modified asphalt [23]. Judging from the share of rubber powder-modified asphalt and SBS-modified asphalt used in the world, although rubber powder asphalt has many applications, it cannot fundamentally shake the mainstream position of modified asphalt prepared using thermoplastic elastomer SBS [24]. The rubber-plastic alloy TPE material studied in this paper is an extension of the modification of pure rubber powder. From the perspective of technical principles, rubber can impart elasticity to asphalt, while resin can impart rigidity to asphalt, enabling asphalt to have the characteristics of both rubber and resin, thereby enabling rubber-plastic alloy TPE materials to achieve the performance of SBS block copolymer TPE materials.
In this paper, the serialization and functionalization of novel rubber-plastic alloy (TPE) modifiers were studied, as well as the preparation process and properties; the mix ratio of new TPE modifier asphalt mixture was designed; rubber-plastic alloy modifier formulations were developed, the formulation design plans and processing technology plans were then proposed; subsequently, the preparation method of the rubber-plastic alloy modifier was determined. By analyzing the high-and low-temperature performance, temperature sensitivity, aging performance, and rheological properties of the new rubber-plastic alloy-modified asphalt, the theoretical basis for proposing technical standards related to road performance is improved.

Asphalt Binder
Regarding base asphalt, ESSO 70# is used, and its technical indicators satisfy the requirements of heavy-duty asphalt 70# in the current Chinese specification "Technical Specifications for Construction of Highway Asphalt Pavements" (JTG F40-2004), as shown in Table 1. The waste rubber powder used in the experimental study in this paper is the "MOZHU" brand fine waste rubber powder (80 mesh) produced by Tianjin Tianyuanheng Rubber Products Factory. Its physical indicators are shown in Table 2.  Waste plastic uses recycled plastic bottles to crush linear low-density polyethylene, and the specific technical indicators are shown in Table 3. Table 3. Physical properties of waste plastic.

Technical Indicators Measured Results
Density/(g/cm 3  The additive was a plasticizer, a white powdery substance that mainly served to increase solubility and reduce viscosity. The stabilizer used in this study was a composite stabilizer consisting of elemental sulfur and a commercial modified asphalt stabilizer, as well as a self-fabricated stabilizer. The stabilizer content in this study was 1.5‰ (percentage of asphalt content). The compatibility agent used was a rubber oil rich in aromatic compounds.

Test Scheme
This study is based on previous research on rubber powder and plastics-modified asphalts, and the TPE material fabricated from rubber-plastic alloys investigated in this study represents a breakthrough in the modification of asphalt using pure rubber powder or plastic. The so-called new type of rubber-plastic alloy is thermoplastic elastomer (TPE). It is based on the actual situation in China and relies on the abundant resources of waste rubber and plastic materials in the domestic industry. Through process and formulation exploration, a type of highly polymerized "alloy" asphalt material has been developed. Recycled plastics and (waste) vulcanized rubber powder are used as the main polymer raw materials, and recycled plastics and waste vulcanized rubber powder are the main polymer raw materials. During the thermodynamic process, under the action of selected composite organic additives, the components are fully mixed with the asphalt. The physical and chemical reactions between different components are completed in the dynamic mixing process, and different types of reactions should occur simultaneously in the mixture without mutual inhibition. This can establish a synergistic effect between various components or different phases, promoting mutual solubility. Establishing a structural morphology similar to that of thermoplastic elastomers (TPEs), this thermoplastic highly asphaltic alloy material can be extruded, granulated, cooled, and solidified. It is non-adhesive at room temperature and easy to be industrially packaged and transported.
This study selected materials such as waste vulcanized rubber powder (WRP), recycled low density polyethylene (RLDPE), viscosity reducer (compatibilizer), plasticizer (A), organic functional group graft copolymer, and other additives (organic composite additives (SBC)). Adopting the theory of molecular phase structure design technology, a new type of thermoplastic elastomer alloy material was designed, which uses rubber with deep dynamic desulfurization as the soft segment and polyolefin resin as the hard segment.
Firstly, the waste rubber powder was activated to prepare (waste) vulcanized rubber powder (A); then, the formulation was designed based on the analysis and requirements of the modified asphalt properties. A new type of rubber-plastic alloy similar to SBS was then prepared using a melting mixer and a double screw extruder, and the subsequent dry process TPE direct injection technology was studied.
By designing different composition formulas, the wet process serialization and functionalized formulations of modified asphalt systems were studied, as well as on the preparation process and performance of modified asphalt.

Raw Material Activation Treatment
Given that the highly crosslinked network structure of waste rubber powder contains three-dimensional crosslinking structures with S-S chemical bonds, it neither melts nor dissolves and is difficult to dissolve and disperse in asphalt. To enhance the compatibility between the various components (including waste rubber powder) in TPE and asphalt, the rubber powder was subjected to a deep desulfurization and activation treatment before processing.
Four types of activators were selected to activate waste rubber powder, namely, petroleum-based (L-A), coal tar-based (L-B), de-link-based (L-C), and vegetable oil-based (S-1) activators. The activation process is the following: the waste rubber powder and activator were mixed in a high-speed mixer first, and then rolled and cooled in a two-roller mixing mill for crushing into fine powder.

Preparation of TPE Modifier
The equipment used for processing the TPE modifier in this paper is the SHJ-20 double screw extruder produced by Nanjing Hanyi Machinery limited company. A specific proportion of activated waste rubber powder, waste plastic, and additives were mixed in a high-speed mixer, and then a double screw extruder was used for reactive blending. The overall mix was extruded and pelletized to make TPE modifier particles. The double screw extruder and TPE modifier particles are shown in Figures 1 and 2. organic functional group graft copolymer, and other additives (organic compos tives (SBC)). Adopting the theory of molecular phase structure design technolog type of thermoplastic elastomer alloy material was designed, which uses rubber w dynamic desulfurization as the soft segment and polyolefin resin as the hard seg Firstly, the waste rubber powder was activated to prepare (waste) vulcanized powder (A); then, the formulation was designed based on the analysis and requi of the modified asphalt properties. A new type of rubber-plastic alloy similar to then prepared using a melting mixer and a double screw extruder, and the sub dry process TPE direct injection technology was studied.
By designing different composition formulas, the wet process serialization a tionalized formulations of modified asphalt systems were studied, as well as on t aration process and performance of modified asphalt.

Raw Material Activation Treatment
Given that the highly crosslinked network structure of waste rubber powder three-dimensional crosslinking structures with S-S chemical bonds, it neither m dissolves and is difficult to dissolve and disperse in asphalt. To enhance the comp between the various components (including waste rubber powder) in TPE and the rubber powder was subjected to a deep desulfurization and activation treatm fore processing.
Four types of activators were selected to activate waste rubber powder, nam troleum-based (L-A), coal tar-based (L-B), de-link-based (L-C), and vegetable oil-b 1) activators. The activation process is the following: the waste rubber powder a vator were mixed in a high-speed mixer first, and then rolled and cooled in a tw mixing mill for crushing into fine powder.

Preparation of TPE Modifier
The equipment used for processing the TPE modifier in this paper is the SHJ ble screw extruder produced by Nanjing Hanyi Machinery limited company. A proportion of activated waste rubber powder, waste plastic, and additives were m a high-speed mixer, and then a double screw extruder was used for reactive blend overall mix was extruded and pelletized to make TPE modifier particles. The screw extruder and TPE modifier particles are shown in Figures 1 and 2.

Preparation of TPE-Modified Asphalt
The equipment used for preparing TPE-modified asphalt in this article are speed shear and a blender. Firstly, the TPE modifier was stirred and swelled in the then a certain amount of stabilizer was added after being sheared in a high-spe mixer, and finally developed in an oven to complete the process. The process of pr TPE-modified asphalt is shown in Figure 3.

Research on the Performance of TPE-Modified Asphalt
According to the requirements of "Standard Test Methods of Bitumen and mous Mixtures for Highway Engineering" (JTG E20-2011), routine tests such as tion test, softening point test, ductility test, Brinell viscosity test, and elastic recov were conducted on the prepared TPE-modified asphalt. The improvement of m asphalt in terms of high and low performance was analyzed and compared. In a by changing the dosage of the additive, the influence of additive dosage on the tional performance of TPE-modified asphalt was analyzed. This paper used d shear rheometer and bending beam rheometer to measure relevant indicators to the rheological properties of TPE-modified asphalt.
The storage stability of the modified asphalt was mainly characterized by t ration test, and evaluated by ∆ts, the difference of the softening point between the bottom. According to the domestic technical standards for modified asphalt, wh

Preparation of TPE-Modified Asphalt
The equipment used for preparing TPE-modified asphalt in this article are a highspeed shear and a blender. Firstly, the TPE modifier was stirred and swelled in the asphalt, then a certain amount of stabilizer was added after being sheared in a high-speed shear mixer, and finally developed in an oven to complete the process. The process of preparing TPE-modified asphalt is shown in Figure 3.

Preparation of TPE-Modified Asphalt
The equipment used for preparing TPE-modified asphalt in this article are a highspeed shear and a blender. Firstly, the TPE modifier was stirred and swelled in the asphalt, then a certain amount of stabilizer was added after being sheared in a high-speed shear mixer, and finally developed in an oven to complete the process. The process of preparing TPE-modified asphalt is shown in Figure 3.

Research on the Performance of TPE-Modified Asphalt
According to the requirements of "Standard Test Methods of Bitumen and Bitunimous Mixtures for Highway Engineering" (JTG E20-2011), routine tests such as penetration test, softening point test, ductility test, Brinell viscosity test, and elastic recovery test were conducted on the prepared TPE-modified asphalt. The improvement of modified asphalt in terms of high and low performance was analyzed and compared. In addition, by changing the dosage of the additive, the influence of additive dosage on the conventional performance of TPE-modified asphalt was analyzed. This paper used dynamic shear rheometer and bending beam rheometer to measure relevant indicators to evaluate the rheological properties of TPE-modified asphalt.
The storage stability of the modified asphalt was mainly characterized by the separation test, and evaluated by ∆ts, the difference of the softening point between the top and bottom. According to the domestic technical standards for modified asphalt, when ∆ts ≤ 2.5 °C, the stability of the modified asphalt is qualified. On this basis, an optical microscope was also used to analyze the morphology of TPE-modified asphalt at a high temperature by transmission electron microscopy.

Research on the Performance of TPE-Modified Asphalt
According to the requirements of "Standard Test Methods of Bitumen and Bitunimous Mixtures for Highway Engineering" (JTG E20-2011), routine tests such as penetration test, softening point test, ductility test, Brinell viscosity test, and elastic recovery test were conducted on the prepared TPE-modified asphalt. The improvement of modified asphalt in terms of high and low performance was analyzed and compared. In addition, by changing the dosage of the additive, the influence of additive dosage on the conventional performance of TPE-modified asphalt was analyzed. This paper used dynamic shear rheometer and bending beam rheometer to measure relevant indicators to evaluate the rheological properties of TPE-modified asphalt.
The storage stability of the modified asphalt was mainly characterized by the separation test, and evaluated by ∆ts, the difference of the softening point between the top and bottom. According to the domestic technical standards for modified asphalt, when ∆ts ≤ 2.5 • C, the stability of the modified asphalt is qualified. On this basis, an optical microscope was also used to analyze the morphology of TPE-modified asphalt at a high temperature by transmission electron microscopy.

Activated Crumb Rubber-Modified Asphalt with Mono Activation Agent
Activated crumb rubber-modified asphalt (CRM) is prepared by adding different activators. Its formulation and sample preparation process conditions are shown in Tables 4 and 5.
Total 100.00 100.00 100.00 100.00 100.00 100.00 100.00 An electrically heated twin-roll mill Φ160 is used, the front and rear rollers are preheated to the required temperature, then the already weighed materials are added, the sample is then thin-passed, plasticized, and turned over evenly (the total time of plasticizing is about 15 min). After being sliced and cooled, it is crushed into fine powder.
The obtained activated waste rubber powder is added to the asphalt for modification according to specific process requirements. The performance test results of activated waste rubber powder-modified asphalt are presented in Table 6. (1) Effect of WRP activated by various activation agents on asphalt properties The effect of activator L-A and activator S on the performance of modified asphalt was compared by Scheme S1 and Scheme S4, and the results are shown in Figure 4. (1) Effect of WRP activated by various activation agents on asphalt properties The effect of activator L-A and activator S on the performance of modified asphalt was compared by Scheme S1 and Scheme S4, and the results are shown in Figure 4. The comparison in Figure 4 shows that there are not much differences between the modification effects of WRP added with L-A and S on asphalt; however, when the difference between the upper and lower softening points of 48 h is compared, the S-modified asphalt has a lower softening point than that of the L-A-modified asphalt, indicating that the stability of L-A on asphalt is better than that of oil. The effective component of S is a new chemical polymer fabricated from accelerator M and zinc dimethyldithiocarbamate (accelerator ZDMC) dispersed in binary alcohol and in the presence of stearic acid, zinc oxide, and sulfur. S is an effective regenerant for WRP, which can react with the S-S bond in WRP without destroying the C-C bond and breaking the vulcanization network. WRPmodified by S is added to asphalt as a modifier, which has an obvious modification effect on asphalt.
Scheme S3 and Scheme S5 compare the influence of S and L-B on the performance of modified asphalt, and the results are shown in Figure 5. The experimental results show that the difference of the softening point of L-B-modified asphalt is smaller than that of Smodified asphalt, indicating that the stability of L-B-modified asphalt is better than that of S, and the elastic recovery is also larger (nearly 70%). L-B is a black viscous liquid with a special odor. During the experiment, middling coal tar also emits a pungent odor, which has a certain impact on the experimenter's body and is not conducive to the operation of the experiment.
Scheme S2 and Scheme S6 compare the influence of L-B and L-C on asphalt performance, and the results are shown in Figure 5. The comparison in Figure 4 shows that there are not much differences between the modification effects of WRP added with L-A and S on asphalt; however, when the difference between the upper and lower softening points of 48 h is compared, the S-modified asphalt has a lower softening point than that of the L-A-modified asphalt, indicating that the stability of L-A on asphalt is better than that of oil. The effective component of S is a new chemical polymer fabricated from accelerator M and zinc dimethyldithiocarbamate (accelerator ZDMC) dispersed in binary alcohol and in the presence of stearic acid, zinc oxide, and sulfur. S is an effective regenerant for WRP, which can react with the S-S bond in WRP without destroying the C-C bond and breaking the vulcanization network. WRPmodified by S is added to asphalt as a modifier, which has an obvious modification effect on asphalt.
Scheme S3 and Scheme S5 compare the influence of S and L-B on the performance of modified asphalt, and the results are shown in Figure 5. The experimental results show that the difference of the softening point of L-B-modified asphalt is smaller than that of S-modified asphalt, indicating that the stability of L-B-modified asphalt is better than that of S, and the elastic recovery is also larger (nearly 70%). L-B is a black viscous liquid with a special odor. During the experiment, middling coal tar also emits a pungent odor, which has a certain impact on the experimenter's body and is not conducive to the operation of the experiment.
Scheme S2 and Scheme S6 compare the influence of L-B and L-C on asphalt performance, and the results are shown in Figure 5.
L-C is a colorless and odorless mixture obtained from crude oil fractionation. It is a colorless and transparent oily liquid, and its main components are C16~C20 normal alkanes. It can be seen from Figure 6 that the modification effect of L-C is not as good as that of L-B on the whole, and L-B performs much better than L-C in terms of the difference between the ductility and softening point. L-C is a colorless and odorless mixture obtained from crude oil fractionation. It is a colorless and transparent oily liquid, and its main components are C16~C20 normal alkanes. It can be seen from Figure 6 that the modification effect of L-C is not as good as that of L-B on the whole, and L-B performs much better than L-C in terms of the difference between the ductility and softening point. In conclusion, L-B and L-C have better effects on asphalt modification. The modification effect of L-A is not ideal. Finally, it is necessary to conduct more research on S's impact on asphalt ductility.
(2) Effect of activator dosage on asphalt performance  L-C is a colorless and odorless mixture obtained from crude oil fractionation. It is a colorless and transparent oily liquid, and its main components are C16~C20 normal alkanes. It can be seen from Figure 6 that the modification effect of L-C is not as good as that of L-B on the whole, and L-B performs much better than L-C in terms of the difference between the ductility and softening point. In conclusion, L-B and L-C have better effects on asphalt modification. The modification effect of L-A is not ideal. Finally, it is necessary to conduct more research on S's impact on asphalt ductility.
(2) Effect of activator dosage on asphalt performance Scheme S6 investigated the effect of L-C on asphalt performance, but the effect is not ideal. In order to further investigate the effect of L-C and increase the amount of L-C, In conclusion, L-B and L-C have better effects on asphalt modification. The modification effect of L-A is not ideal. Finally, it is necessary to conduct more research on S's impact on asphalt ductility.
(2) Effect of activator dosage on asphalt performance Scheme S6 investigated the effect of L-C on asphalt performance, but the effect is not ideal. In order to further investigate the effect of L-C and increase the amount of L-C, Scheme S7 was designed and compared with Scheme S6. The results are shown in Figure 7.
viscosity of asphalt increase, and the difference between the upper and lower softening points decreases, indicating that the stability of asphalt is enhanced, and that the indicators of Scheme 7 met the technical requirements of the specification.
The additive selected in both Scheme S2 and Scheme S3 is L-B; however, the dosage and process for each scheme are different. The two results are compared and illustrated in Figure 8.  It can be seen from Figure 8 that in terms of overall performance, the modified asphalt produced by Scheme S2 outperforms that produced by Scheme S3; with the exception of stability, which is not better than that of Scheme 3, all other indicators are better than those in Scheme 3. In Scheme 3, the amount of L-B is more than that in Scheme 2, and the shear As illustrated in Figure 7, with the increase in L-C dosage, the ductility and the Brinell viscosity of asphalt increase, and the difference between the upper and lower softening points decreases, indicating that the stability of asphalt is enhanced, and that the indicators of Scheme 7 met the technical requirements of the specification.
The additive selected in both Scheme S2 and Scheme S3 is L-B; however, the dosage and process for each scheme are different. The two results are compared and illustrated in Figure 8.
Scheme S7 was designed and compared with Scheme S6. The results are shown in Figure  7.
As illustrated in Figure 7, with the increase in L-C dosage, the ductility and the Brinell viscosity of asphalt increase, and the difference between the upper and lower softening points decreases, indicating that the stability of asphalt is enhanced, and that the indicators of Scheme 7 met the technical requirements of the specification.
The additive selected in both Scheme S2 and Scheme S3 is L-B; however, the dosage and process for each scheme are different. The two results are compared and illustrated in Figure 8.  It can be seen from Figure 8 that in terms of overall performance, the modified asphalt produced by Scheme S2 outperforms that produced by Scheme S3; with the exception of stability, which is not better than that of Scheme 3, all other indicators are better than those in Scheme 3. In Scheme 3, the amount of L-B is more than that in Scheme 2, and the shear It can be seen from Figure 8 that in terms of overall performance, the modified asphalt produced by Scheme S2 outperforms that produced by Scheme S3; with the exception of stability, which is not better than that of Scheme 3, all other indicators are better than those in Scheme 3. In Scheme 3, the amount of L-B is more than that in Scheme 2, and the shear time is longer than that in Scheme 2; the shear time mainly reflects on the stability of asphalt, therefore deducing that the more coal tar is not better, and it (the amount of L-B in Scheme S3) reached the requirements of asphalt modification at 3.68 phr.
Scheme S4 is compared with Scheme S5. The additive used in both schemes is S, and the results obtained are shown in Figure 9.
time is longer than that in Scheme 2; the shear time mainly reflects on the stability of asphalt, therefore deducing that the more coal tar is not better, and it (the amount of L-B in Scheme S3) reached the requirements of asphalt modification at 3.68 phr.
Scheme S4 is compared with Scheme S5. The additive used in both schemes is S, and the results obtained are shown in Figure 9.
As indicated in Figure 10, the difference in performance between the modified asphalt obtained from Scheme S4 and Scheme S5 are not significant. Ignoring the influence of shear time, when the amount of S is 4.5 phr, the modification effect can be achieved very well, and more is not better.

Properties of Activated Waste Rubber Powder and Modified Asphalt with Complex Activator
The above-mentioned activators were compounded to study the performance index of the modified asphalt. The test formulation is shown in Table 7, and the sample preparation process is established in Table 8. The rubber powder activated by the composite system is used to prepare the modified asphalt, and its performance indicators are shown in Table 9.  As indicated in Figure 10, the difference in performance between the modified asphalt obtained from Scheme S4 and Scheme S5 are not significant. Ignoring the influence of shear time, when the amount of S is 4.5 phr, the modification effect can be achieved very well, and more is not better.  The purpose of adding an activator is to reduce the crosslinking of sulfur and modify the surface of waste rubber powder. This can change the surface layer of waste rubber powder from elastic to viscous, and increase its surface reactivity.
XLDS-15 rubber crosslinking density NMR analyzer produced by IIC Innovative Im-agingCorp. KG (Germany) was used to determine the crosslinking density of rubber powder. Figure 11 shows the NMR analysis of the crosslinking density of the inactive and activated rubber powder (see Table 10 for the NMR analysis data of the crosslinking density of the activated rubber powder tablet).

Properties of Activated Waste Rubber Powder and Modified Asphalt with Complex Activator
The above-mentioned activators were compounded to study the performance index of the modified asphalt. The test formulation is shown in Table 7, and the sample preparation process is established in Table 8. The rubber powder activated by the composite system is used to prepare the modified asphalt, and its performance indicators are shown in Table 9.  It can be seen from Table 8 that the composite activation system outperforms the single/mono system, especially regarding the stability of modified asphalt. Other performance changes are not particularly obvious. The following conclusions can be drawn: (1) Similar to the modified asphalt with single activator system, the modified asphalt with L-B in the composite system has the best stability; (2) The addition of plant softener S-1 can improve the softening point of modified asphalt; (3) In the composite system, the change in the content of L-A and S has little effect on the performance of modified asphalt, and the performance index basically does not change with the change in its content; (4) Compared with other composite systems, the softening point of the modified asphalt system added with L-B is slightly lower.

Study on Activation Effect of Waste Rubber Powder
The waste rubber powder is a highly crosslinked, three-dimensional network structure created from crushed vulcanized rubber that neither melts nor dissolves. The three-dimensional network structure is shown in Figure 10. This crosslinked three-dimensional structure is also difficult to dissolve and disperse in asphalt. However, the traditional regeneration methods, such as the hot oil method and acid method, cause the oxidation and partial thermal cracking of the rubber main chain bond while cutting off the sulfur bond crosslinking mesh, resulting in the decline of its physical properties. Cutting the sulfur-sulfur bond without cutting the carbon-carbon bond maintains the main chain structure of rubber macromolecules to maximize the performance of the original rubber.
The purpose of adding an activator is to reduce the crosslinking of sulfur and modify the surface of waste rubber powder. This can change the surface layer of waste rubber powder from elastic to viscous, and increase its surface reactivity.
XLDS-15 rubber crosslinking density NMR analyzer produced by IIC Innovative ImagingCorp. KG (Germany) was used to determine the crosslinking density of rubber powder. Figure 11 shows the NMR analysis of the crosslinking density of the inactive and activated rubber powder (see Table 10 for the NMR analysis data of the crosslinking density of the activated rubber powder tablet). The purpose of adding an activator is to reduce the crosslinking of sulfur and modify the surface of waste rubber powder. This can change the surface layer of waste rubber powder from elastic to viscous, and increase its surface reactivity.
XLDS-15 rubber crosslinking density NMR analyzer produced by IIC Innovative ImagingCorp. KG (Germany) was used to determine the crosslinking density of rubber powder. Figure 11 shows the NMR analysis of the crosslinking density of the inactive and activated rubber powder (see Table 10 for the NMR analysis data of the crosslinking density of the activated rubber powder tablet). Figure 11. Crosslink density NMR analysis graph. Figure 11. Crosslink density NMR analysis graph. Table 10. NMR analysis of crosslinking density of activated rubber powder tablet. The NMR crosslinking density analysis of activated waste rubber powder showed that the crosslinking density decreased and the area of crosslinking point decreased, indicating that the number of crosslinking points in the waste rubber powder decreased. The number of crosslinking points of activated waste rubber powder decreases, the restriction of network structure on the movement of molecular chain decreases, the small molecular chain segment increases, the movement ability of small active units increases, and the number increases, in other words, T2 increases. Due to the reaction between the activator and the macromolecule of the waste rubber powder, a part of the crosslinking bond of the rubber powder was interrupted, and the network structure was destroyed, resulting in a relatively large number of small movement units, meaning that some free molecular chain segments appeared, corresponding to the increase in A (T2). The above analysis shows that the activation of waste rubber powder effectively breaks the sulfur-sulfur bonds in the three-dimensional network structure of waste rubber powder, increases its reactivity, and the fracture of the molecular chain is also conducive to the dispersion of waste rubber powder in asphalt.

Activated Waste Rubber Powder-Modified Asphalt Microstructure Analysis
In the waste rubber powder-modified asphalt system, there is only partial adsorption and phase dissolution between the waste rubber powder and asphalt, rather than a complete melting. This kind of system belongs to the thermodynamic unstable system, which is prone to separation between two phases, thus causing segregation as shown in Figure 12. The fluorescence microscope of waste rubber powder-modified asphalt shows that the waste rubber powder is black, and the field of vision is dark.
that the crosslinking density decreased and the area of crosslinking point decreased, in cating that the number of crosslinking points in the waste rubber powder decreased. number of crosslinking points of activated waste rubber powder decreases, the restric of network structure on the movement of molecular chain decreases, the small molecu chain segment increases, the movement ability of small active units increases, and number increases, in other words, T2 increases. Due to the reaction between the activa and the macromolecule of the waste rubber powder, a part of the crosslinking bond of rubber powder was interrupted, and the network structure was destroyed, resulting relatively large number of small movement units, meaning that some free molecular ch segments appeared, corresponding to the increase in A (T2). The above analysis sho that the activation of waste rubber powder effectively breaks the sulfur-sulfur bond the three-dimensional network structure of waste rubber powder, increases its reactiv and the fracture of the molecular chain is also conducive to the dispersion of waste rub powder in asphalt.

Activated Waste Rubber Powder-Modified Asphalt Microstructure Analysis
In the waste rubber powder-modified asphalt system, there is only partial adsorpt and phase dissolution between the waste rubber powder and asphalt, rather than a co plete melting. This kind of system belongs to the thermodynamic unstable system, wh is prone to separation between two phases, thus causing segregation as shown in Fig  12. The fluorescence microscope of waste rubber powder-modified asphalt shows that waste rubber powder is black, and the field of vision is dark. The activated waste rubber powder is dispersed in the asphalt by physical meth such as shear machine high-speed mixing and shearing. The activated waste rubber p der has a strong interaction with the asphalt, which limits the cohesion and flexibilit the asphalt and reduces its sensitivity to temperature. Figure 13 shows the fluorescence micrograph of activated waste rubber powd modified asphalt. Compared with Figure 12, it can be seen that in the activated w rubber powder-modified asphalt system, the surface of waste rubber powder is swe The activated waste rubber powder is dispersed in the asphalt by physical methods such as shear machine high-speed mixing and shearing. The activated waste rubber powder has a strong interaction with the asphalt, which limits the cohesion and flexibility of the asphalt and reduces its sensitivity to temperature. Figure 13 shows the fluorescence micrograph of activated waste rubber powdermodified asphalt. Compared with Figure 12, it can be seen that in the activated waste rubber powder-modified asphalt system, the surface of waste rubber powder is swelled by the light components of asphalt, and the waste rubber powder particles are evenly dispersed. The activated waste rubber powder-modified asphalt prepared by activated waste rubber powder is shown in Figure 13a. The surface of the rubber powder swells, but it penetrates less into the interior. With the addition of the activator, asphalt penetrates the rubber powder, and the rubber powder particles are smaller. In the interface area between asphalt and rubber powder, the rubber powder is translucent.
by the light components of asphalt, and the waste rubber powder particles are evenly dispersed. The activated waste rubber powder-modified asphalt prepared by activated waste rubber powder is shown in Figure 13a. The surface of the rubber powder swells, but it penetrates less into the interior. With the addition of the activator, asphalt penetrates the rubber powder, and the rubber powder particles are smaller. In the interface area between asphalt and rubber powder, the rubber powder is translucent.

Selection and Determination of Organic Functional Group Graft Copolymer
In waste rubber-based thermoplastic elastomer (polymer alloy), some organic composite additives are often selected to establish the physical and chemical interaction between different components (rubber and plastic). Therefore, based on the activation of waste rubber powder, the selection of organic chemical additives and the effect of modified asphalt properties were studied.
The organic functional group graft copolymers selected three kinds of P grafts and one kind of styrene block thermoplastic elastomer styrene butadiene block copolymer (SBC). The formulation is shown in Table 11 below. The preparation process is as follows: a Φ 160 electrically heated twin-roll plasticizing machine, the front and rear rollers are preheated to the suitable temperature, the weighed materials are added, thin-passed, plasticized, and turned over evenly (the total plasticizing time is controlled at about 15 min). After cutting and cooling, crushing and grinding into fine powder, they are then passed through 80 sieves for use. The sample preparation process is listed in Table 12.

Selection and Determination of Organic Functional Group Graft Copolymer
In waste rubber-based thermoplastic elastomer (polymer alloy), some organic composite additives are often selected to establish the physical and chemical interaction between different components (rubber and plastic). Therefore, based on the activation of waste rubber powder, the selection of organic chemical additives and the effect of modified asphalt properties were studied.
The organic functional group graft copolymers selected three kinds of P grafts and one kind of styrene block thermoplastic elastomer styrene butadiene block copolymer (SBC). The formulation is shown in Table 11 below. The preparation process is as follows: a Φ 160 electrically heated twin-roll plasticizing machine, the front and rear rollers are preheated to the suitable temperature, the weighed materials are added, thin-passed, plasticized, and turned over evenly (the total plasticizing time is controlled at about 15 min). After cutting and cooling, crushing and grinding into fine powder, they are then passed through 80 sieves for use. The sample preparation process is listed in Table 12.

Effect of Organic Functional Group Graft Copolymer on the Properties of Modified Asphalt
The function of organic functional group graft copolymer is to closely combine waste rubber, waste plastics, and additives in the alloy as an intermediary, improve the compatibility of rubber and plastic alloy and base asphalt, and improve the interfacial properties of rubber and plastic alloy particles and base asphalt. Three kinds of organic functional group graft copolymers were selected and their modification effects were compared. The experimental scheme and comparison results are shown in Tables 13 and 14. It can be seen that the difference between the softening points of the three modified asphalts above and below 48 h is large, the ductility is also too low, and the indexes of penetration, softening point, and Brinell viscosity meet the technical requirements of the specification. In the optics of improving the ductility of modified asphalt, reducing the proportion of RLDPE is one method.   It can be seen from Table 15 that when the plastic content is reduced, the difference of softening point of modified asphalt is significantly reduced, and the stability is greatly improved. The rubber and plastic alloy used in Scheme T4 and Scheme T5 accounts for 15% of the asphalt, and the rubber powder content is much higher than that in Scheme 8-10. The ductility of the modified asphalt is also significantly improved; however, the Brinell viscosity is higher.

Effect of Additive SBC
In order to further improve the effect of rubber-plastic alloy-modified asphalt, 13.6% content of SBC (based on 100% content of total WRP and RLDPE) is added on the basis of Scheme T4 and Scheme T5, and Scheme T6 and Scheme T7 are designed respectively. Other conditions remain unchanged (see Table 17 for the formulation).  Figures 14 and 15 show the performance comparison between SBC added and SBC unadded. The two figures show that the addition of SBC significantly improves the stability of the system, reduces the difference between the softening point above and below 48 h, and increases the softening point, ductility, and elastic recovery. This suggests that the addition of SBC improved the blending of RLDPE and the system as well as the low-temperature performance of asphalt. However, it can also be seen that the Brinell viscosity of the system increases, which has a great impact on the construction conditions of asphalt.

Viscosity-Reducing Effect of Plasticizer A on Asphalt
In order to solve the problem of excessive Brinell viscosity of rubber-plastic al modified asphalt, plasticizer A (plasticizer A is a mixture of cracked polyethylene long-chain alkyl acid in a certain proportion) was selected, and the design scheme inv tigated the viscosity reduction effect of plasticizer A.
With plasticizer A as the variable, the modified system prepared by Scheme T7 w selected, and 1 fen (T8) and 1.5 fen (T9) of plasticizer A were added in the shear proc of modified asphalt. The specific formulation and results are shown in Tables 18 and

Viscosity-Reducing Effect of Plasticizer A on Asphalt
In order to solve the problem of excessive Brinell viscosity of rubber-plastic alloymodified asphalt, plasticizer A (plasticizer A is a mixture of cracked polyethylene and longchain alkyl acid in a certain proportion) was selected, and the design scheme investigated the viscosity reduction effect of plasticizer A.
With plasticizer A as the variable, the modified system prepared by Scheme T7 was selected, and 1 fen (T8) and 1.5 fen (T9) of plasticizer A were added in the shear process of modified asphalt. The specific formulation and results are shown in Tables 18 and 19. It can be seen from Figure 16 that the viscosity reduction in modified asphalt is obvious when adding 1 fen of plasticizer A, but with the increase in the proportion of A, the viscosity reduction is no longer obvious. The long-chain alkyl acid in plasticizer A can soften the combination of S segment in SBC and RLDPE in modified asphalt, so the viscosity of modified asphalt is reduced, but the softening point is also reduced, resulting in the weakening of the high-temperature performance of modified asphalt. The cracked polyethylene in plasticizer A can not only further reduce the viscosity of the system, but also improve the high-temperature performance of modified asphalt raw materials. The combination of the two can reduce the viscosity of modified asphalt while maintaining the original performance of asphalt.
It can be seen from Figure 16 that the viscosity reduction in modified asphalt is ob ous when adding 1 fen of plasticizer A, but with the increase in the proportion of A, viscosity reduction is no longer obvious. The long-chain alkyl acid in plasticizer A c soften the combination of S segment in SBC and RLDPE in modified asphalt, so the v cosity of modified asphalt is reduced, but the softening point is also reduced, resulting the weakening of the high-temperature performance of modified asphalt. The crack polyethylene in plasticizer A can not only further reduce the viscosity of the system, also improve the high-temperature performance of modified asphalt raw materials. T combination of the two can reduce the viscosity of modified asphalt while maintain the original performance of asphalt.

Conclusions
In conclusion, the analysis of GPC data for crumb rubber-modified asphalt and tracted asphalt leads to the following conclusions: (1) Investigation and analysis were carried out on the infrared and thermal analysis ch acteristics of crumb rubber and waste plastic, and based on this, a design method rubber-plastic alloys used in modified asphalt was proposed. The theory of mole lar phase structure design technology was used to design an SBS-like waste rubb

Conclusions
In conclusion, the analysis of GPC data for crumb rubber-modified asphalt and extracted asphalt leads to the following conclusions: (1) Investigation and analysis were carried out on the infrared and thermal analysis characteristics of crumb rubber and waste plastic, and based on this, a design method for rubber-plastic alloys used in modified asphalt was proposed. The theory of molecular phase structure design technology was used to design an SBS-like waste rubber-plastic alloy material structure based on the extracted infrared and thermal analysis data of waste rubber-plastic materials. A new thermoplastic elastomer alloy material was invented, which uses rubber with deep dynamic desulfurization as the soft segment region and polyolefin as the hard segment region; (2) The formulation and preparation processes of the rubber-plastic alloy were studied indoors, and the technical scheme adopted included graft modification of the rubber-plastic alloy with activated waste rubber powder and organic functional group graft copolymer. In the experiment, a mono activator and a composite activator were used to activate the waste rubber powder, and a comparative study of their properties was carried out. The results showed that after adding the activator, the waste rubber powder expanded significantly in the asphalt, with smaller and more uniformly dispersed particles. The network structure of the modified asphalt with activated waste rubber powder was more uniform and dense, resulting in improved performance and storage stability of the modified asphalt; (3) This study made a reasonable formulation of waste rubber powder, waste plastic, organic functional group graft copolymer, desulfurization and activation agents, and viscosity-reducing agents, and adjusted the processing technology. A new type of thermoplastic elastomer rubber-plastic alloy material was obtained through reactive blending technology. By formulating and adjusting the ratio of waste rubber pow-der and waste plastic, rubber-plastic alloy materials suitable for different practical engineering requirements can be obtained; (4) The optimal process conditions for modifying asphalt with a rubber-plastic alloy were obtained through exploration of the process conditions: shear temperature of 160-170 • C, rotating speed of 3000 r/min, and shear time of 30 min. Through this research, it was discovered that the prolongation of shearing time has the greatest impact on the performance of modified asphalt, and the method of prolonging shearing time can be used to prepare modified asphalt with more stable storage.

Data Availability Statement:
The relevant data has been reflected in the paper, and there is no additional data available for sharing.

Conflicts of Interest:
The authors declare no conflict of interest.