Mechanical Behavior of Low-Strength Hydraulic Lime Concrete Reinforced with Flexible Fibers under Quasi-Static and Dynamic Conditions

: We investigate the effect of flexible fiber reinforcement on low-strength hydraulic lime concrete. This type of concrete is occasionally necessary to ensure compatibility with the substrate, particularly in the conservation and rehabilitation of historical heritage. For this purpose, we designed a matrix of hydraulic lime concrete based on a mix design method we proposed previously and added different amounts of polyvinyl alcohol fiber (volumetric contents of 0.3%, 0.6%, 0.9%, and 1.2%). We then conducted three-point bending tests on prismatic specimens with a central notch under quasi-static (displacement rate of 4 × 10 − 4 mm/s) and dynamic (4 mm/s) conditions, using a servo-hydraulic machine. The results indicate that, in both quasi-static and dynamic regimes, the flexural strength, the residual flexural strengths for different crack openings, and the work of fracture increase as the fiber content increases. Furthermore, transitioning from one regime to another (by increasing the strain rate or velocity) leads to a significant increase in these mechanical parameters.


Introduction
There is a growing inclination towards promoting contemporary sustainable construction.Research explores materials like earth-based concrete [1,2], hemp concrete [3], etc., particularly suited for applications where high mechanical strength is not essential.For instance, hemp concrete demonstrates strengths ranging from 0.1 to 1.6 MPa after 28 days.Notably, a material gaining special relevance in this context is natural hydraulic lime, despite having mechanical properties below those of Portland cement.It offers distinct advantages, primarily cost-effectiveness and reduced environmental impact, as supported by recent studies [4].This trend extends to hydraulic lime concretes for similar reasons.
Furthermore, lime-based materials are especially suitable for the restoration of masonry buildings.In this sense, these mortars must fulfill compatibility and serviceability criteria, thus the importance of their detailed characterization [5].With this respect, several papers focus on searching for compatible mortars to restore various structures, such as the case of the work by Moropoulou et al. [5] centered on the earthquake protection of the Kaisarini Monastery in Greece; or the work by Maravelaki-Kalaitzaki et al. [6] focused on the characterization of original mortars from a Venetian Villa in Chania, Crete; or the case of Moropoulou et al. [7], who deal with the characterization of the crushed brick/lime mortars of Justinian's Hagia Sophia to resist earthquake stresses.Recently, in 2022, Groot et al. [8] wrote the RILEM TC 277-LHS report on lime-based mortars for restoration, where they define the theoretical background and experimental developments plus positive and negative practical experiences in lime-based binders and mortars.
Appl.Sci.2024, 14, 6364 2 of 16 These lime mortars, as also happens with lime concretes, present an inherent fragility common to most cementitious materials.To counterbalance this drawback, incorporating fibers becomes crucial to enhance energy absorption capacity and ductility under various quasi-static and dynamic solicitations.This requirement has generated considerable interest in research [9].
While there is abundant scientific literature addressing the influence of different fiber types on the mechanical behavior of Portland cement concrete, the same cannot be said for natural hydraulic lime concretes.Existing studies are exclusively focused on lime mortars.Let us delve into some of the most noteworthy studies.Angiolilli et al. [10] conducted a study on hydraulic lime mortars reinforced with varying amounts and lengths of fiberglass.They observed a significant increase in the mechanical properties of the composite in quasistatic conditions, proportional to the fiber content.Notably, there was a substantial increase in fracture energy, followed by flexural strength, tensile strength, and compressive strength, in that order.This study suggests that fiberglass-reinforced lime mortar could be a viable alternative for the restoration and strengthening of historical structures [10].
Asprone et al. [4] investigated hydraulic lime mortars reinforced with basalt fibers in both quasi-static and dynamic regimes.The inclusion of fibers led to an increase in porosity, resulting in lower quasi-static compressive and flexural strengths as the fiber content increased.However, the reinforced mortars exhibited a more ductile and tough behavior.In the dynamic regime, direct tensile strength increased, showing high sensitivity to deformation velocity.Fracture energy also increased with the loading rate [4].They concluded that basalt fiber-reinforced natural hydraulic lime mortars present good dynamic mechanical properties and may be a viable binder material for the recovery of cultural heritage.Santarelli et al. [11] studied hydraulic lime mortars reinforced with basalt fibers and different types of aggregates, showing improvements in post-cracking behavior and compressive strength, largely dependent on the matrix and basalt fiber type.They highlighted that the fibers could be surface-treated, and their content could be optimized to define a suitable material for restoration.
Badagliacco et al. [9] investigated the flexural behavior of natural hydraulic lime mortars reinforced with natural cane fibers for brick manufacturing and use in sustainable construction.Results indicated improvements in post-cracking flexural strength compared to unreinforced mortars, along with increased ductility.
Chan et al. [12] examined quasi-static responses to compression, shear, and flexure of hydraulic lime mortars reinforced with polypropylene microfibers, noting improvements in flexural toughness but increased weakness in mode I fracture.The same authors [13] also analyzed the dynamic response to impact loading in flexure, finding higher sensitivity in the lime mortar reinforced with fibers compared to Portland cement mortar and concrete reinforced with fibers.The main application of said mortars was to repair stone masonry structures of historical importance in Canada subjected to varying degrees of seismicity.
Islam et al. [14] investigated the mechanical behavior in quasi-static and dynamic regimes of hydraulic lime mortars reinforced with polypropylene microfibers in various quantities.They explained the improvement in quasi-static flexural strength and toughness with increasing fiber content, highlighting the material's sensitivity to the deformation velocity in dynamic flexural testing.Recently, Mercuri et al. [15] studied lime mortars reinforced with polyvinyl alcohol (PVA) fibers, analyzing their behavior in flexure, compression, and indirect tensile strength.The findings showed that both flexural strength and fracture energy increased with fiber content, as did tensile and compressive strengths, but at different rates.They concluded that the newly proposed mortar presented appropriate properties for the strengthening of masonry structures, especially for intervention in cultural heritage buildings.
The research on lime concretes is limited, as stated above.A chapter called "Lime Concretes with Ad Hoc Performances" authored by Rosell and Bosch can be found in the book "Building Engineering Facing the Challenges of the 21st Century" [16].In this work, the authors use "limecrete" to refer to lime concretes and present several cases involving the design of mortars and concretes for restoration works and new buildings.Additionally, Rosell et al. [17] designed hydraulic lime concretes to restore the Roselló church in Lérida, Spain.Besides these works, there are several papers focused on adding lime to different concretes [18][19][20][21][22][23].However, these are not specifically designed for restoration purposes but rather for the benefits of using lime due to sustainability and economic reasons.The findings on fiber-reinforced lime concrete are extremely scant despite the potential advantages, such as increased ductility and toughness.
Furthermore, for specific applications related to both the conservation and rehabilitation of historical heritage, as well as its use in new construction, achieving compatibility requirements may not align with the desire for high compressive strength (typically defined as 6-7 MPa) [8].Consequently, it becomes necessary to analyze the dynamic fracture behavior of this type of low-strength concrete [24][25][26] as opposed to that of higher-strength natural hydraulic lime concretes, whose application field is not as focused on heritage restoration and conservation.Therefore, building upon this scientific literature, this paper aims to investigate the behavior of low-strength hydraulic lime concrete reinforced with polyvinyl alcohol fibers under various loading conditions.The hydraulic lime concrete matrix was designed using an innovative methodology recently developed by the authors of this work [27].A systematic experimental investigation was devised to examine the mode I fracture in prismatic notched beams, loaded in a three-point bending configuration at two loading velocities, covering a range of five orders of magnitude, encompassing quasi-static to dynamic regimes.
After this introduction, the paper is organized as follows.Section 2 describes the methods and materials; in Section 3, the results are presented along with a discussion.Finally, the main conclusions are provided in Section 4.

Mix Design Methodology
The methodology employed for formulating both the fiber-reinforced hydraulic lime concrete and its unreinforced matrix is the one presented by Garijo et al. [27].This methodology is based on rheological and mechanical principles, encompassing the assessment of deformability in the fresh state, compressive strength, and the optimal compactness of the granular skeleton.Key design parameters include consistency in the Abrams cone, water-to-lime (w/ℓ) and superplasticizer-to-lime (SP/ℓ) relationships, and the inherent characteristics of the granular skeleton.

Raw Materials
The raw materials used in the production of flexible fiber hydraulic lime concrete (FFLC) are outlined as follows.Table 1 includes the compositions of the mix designs.The mix design compositions of the hydraulic lime concrete (with and without PVA fibers) are presented in Table 1. Figure 1a plots the particle size distribution of aggregates and Figure 1b shows the morphology of the polyvinyl alcohol fibers.The use of a superplasticizer admixture is due to the interest in designing concretes (with and with-out fiber reinforcement) within a soft consistency typology S2 (Abram's cone slump of 50-90 mm ± 10 mm) suitable for good workability with the inclusion of flexible PVA fibers.Specifically, this poly-aryl-ether type-based superplasticizer was used based on rheological tests conducted on lime pastes to determine the compatibility of the lime-superplasticizer system and the appropriate dosage ranges to achieve the desired consistency [28].

Manufacturing Process
The laboratory-manufactured batches were processed using a vertical-axis planetary concrete mixer with a capacity of 100 liters, handling 63 liters per batch.The concrete mixing procedure involved sequential steps: initially, dry mixing of hydraulic lime and fine aggregate for one minute, subsequent addition of 90% water over one minute, followed by an additional minute of mortar phase mixing.The superplasticizer admixture and the remaining water were then introduced for one minute, with an additional minute of mortar mixing.Subsequently, the mixing operation was briefly halted to clear material adhering to the mixer's bottom and blades.Coarse aggregate inclusion followed, with an additional two minutes of concrete mixing.Finally, the introduction of PVA fibers (in concretes with fibers) took place over one minute.The entire mixing process continued for three more minutes, concluding with the fresh state characterization of the concrete.This mixing sequence adapts our established protocol for producing Portland cement concrete [27,29].In particular, the mixing times established in each phase have been determined and optimized based on initial tests and studies conducted in our laboratory.
Post-mixing, the concrete was poured into two types of steel molds: cylindrical specimens measuring 150 × 300 mm 2 (diameter × height) and prismatic specimens measuring 420 × 100 × 100 mm 3 (length × width × height).After casting, the specimens were stored in a room for 24 h.Subsequently, they were demolded and placed in a climatic chamber with constant temperature and humidity conditions (20 ºC ± 0.5 ºC, and 98% ± 0.5%, respectively) until the designated testing age.The testing age was 28 days for quasi-static characterization of compressive strength and elastic modulus, and 156 days for another quasi-static characterization of compressive strength concurrent with dynamic fracture tests.Please note that the improvement of mechanical properties over time in NHL 3.5 is slower than in higher classes.Therefore, we decided to conduct the tests at 156 days, approximately 5 months.This time frame represents a point at which the rate of strength development becomes significantly low [8].One week before testing, a notch, reaching a depth of 1/6 the height of the specimen, was created at the center of prismatic specimens for hydraulic lime concrete both with and without fiber reinforcement.

Fresh State Measurements and Quasi-Static Mechanical Characterization
In the fresh stage, a slump flow test using the Abrams cone was conducted to assess the slump characteristics of the fresh concrete batches [30].Concurrently, the density of the fresh concrete was determined according to the guidelines outlined in [31].
In the hardened state, mechanical characterization at 28 days was undertaken; the elastic modulus was measured in cylindrical specimens measuring 150 × 300 mm 2 (diameter × height) as per [32].Uniaxial compressive strength was determined in identical cylindrical specimens, controlling the load at a velocity of 0.3 MPa / s [33].These tests were executed on a Servosis servo-hydraulic machine with a load capacity of 300 kN.At the age of conducting dynamic fracture tests (156 days), quasi-static compression strength tests were also performed.
Additionally, prismatic specimens (420 × 100× 100 mm 3 , length × width × height) were manufactured for the assessment of flexural and residual flexural strengths through three-point bending tests following [34,35].A central notch, with a depth of 1/6 of the specimen's height, was pre-cut for subsequent testing.The value of this notch depth was chosen due to the low expected values of flexural strengths so that the specimen would not suffer damage during cutting and handling.Load-point displacements were recorded using two inductive extensometers of the LVDT type (Linear Variable Differential Transducer, HBM ± 50 mm), while CMOD (Crack Mouth Opening Displacement) was not measured due to the unavailability of a dynamic clip sensor.The testing was carried out on an Instron 8805 servo-hydraulic machine with a 1 MN capacity and a 25 kN load cell, utilizing displacement control at a velocity of 0.2 mm/min.Additionally, the work of fracture of concrete without fiber reinforcement was also determined [36][37][38][39].All these quasi-static three-point bending tests were conducted at the time of the dynamic fracture tests (156 days).

Dynamic Fracture Mechanics Tests
At 156 days (≈ 5 months), mode I dynamic fracture tests were conducted using the servo-hydraulic machine Instron 8805, previously employed for quasi-static mechanical characterization (Figure 2).Four prismatic specimens measuring 420 × 100 × 100 mm 3 , each featuring a centrally sawn notch with a depth equal to 1/6 of the specimen's height, were tested for each type of hydraulic lime concrete (with and without PVA fiber reinforcement) and at two different loading rates.The selected velocities, aiming to encompass the spectrum from quasi-static to low dynamic regimes, were denoted as v 1 = 4 × 10 −4 mm/s and v 2 = 4 mm/s, respectively.

Fresh State Characterization
The presentation of the characterization results for the fresh state of both hydraulic lime concretes (with and without PVA fibers) can be found in Table 2.The density could not be measured for the mix without fibers.In all cases, with and without fiber reinforcement, a soft consistency is obtained in the Abrams cone test (S2 class, meaning a slump within the range 50-90 mm ± 10 mm) [40], aligning with the initial mix design goal for the fresh state.The measured fresh state density values are relatively low, possibly due to a high entrapped air content, despite vibrating the concrete in all cases.

Quasi-Static Mechanical Characterization
Tables 3 and 4 include the quasi-static mechanical characterization carried out for both hydraulic lime concretes (with and without PVA fibers) at 28 and 156 days.The data is also depicted in three bar plots in Figure 3.By the initially established w/ℓ ratio during the design of the base or matrix concrete, the expected compressive strength value is achieved in all cases.Table 3 reflects how the compressive strength increases as the fiber content rises (at 28 and 156 days).While the primary effect of fiber inclusion in concrete pertains to increased ductility and toughness [41], in these cases, high fiber quantities generate a confinement effect that substantially enhances compressive strength in this type of low-strength concrete.Furthermore, Table 3 and Figure 3 show that at 156 days of age, the compressive strength of the concretes approximately matches that of 28 days, confirming that the material no longer evolves in terms of its mechanical behavior.Regarding the modulus of elasticity, Table 3 and Figure 3 indicate variability in terms of its reduction as fiber is added, except for a fiber quantity of ϕ f = 0.9%, where an increase is observed.This could result from the greater or lesser degree of matrix disintegration due to fiber addition, as well as a potential limit or optimum value beyond which the modulus undergoes a drastic reduction.In this research, we have drawn an analogy with flexural and residual flexural strengths since, instead of being defined for crack opening values, we refer to vertical displacement values here.In other words, σ R1 will denote the residual flexural strength value for 0.5 mm of vertical displacement of the load application point instead of 0.5 mm of crack opening.The same procedure is followed for the remaining flexural and residual flexural strengths.Figure 4a compares the calculated values of σ N under quasi-static and dynamic conditions, with loading rates v 1 = 4 × 10 −4 mm/s and v 2 = 4 mm/s, respectively.In the quasi-static regime, as ϕ f increases, so does σ N , reaching its maximum value at ϕ f = 0.009.In the dynamic regime, there is likewise an increasing trend for σ N as ϕ f is augmented, except at ϕ f = 0.006, where it decreases relatively.Additionally, values of W F have been measured at both loading rates for fiber-unreinforced concretes up to 0.5 mm of vertical displacement under the loading point (Figure 4b).As anticipated, in the dynamic regime, the W F value is higher than in the quasi-static regime, except for ϕ f = 0.006 of fiber content.Given that the average W F values are quite similar, and the standard deviation is relatively high at both speeds, the most likely explanation for this atypical trend is the lack of uniformity in the distribution and quantity of fibers crossing the fracture section.
Figure 5 compares the obtained values of σ L and σ R1 for both regimes.In the quasistatic regime, as ϕ f increases, so does σ L , reaching the optimum value at ϕ f = 0.009.Meanwhile, in the dynamic regime, σ L remains constant as ϕ f increases (Figure 5a).Regarding residual flexural strength, only the evolution of σ R1 can be compared since it is the only measurable parameter in both regimes (Figure 5b).In the quasi-static regime, a similar trend to σ L is observed; as ϕ f increases, so does σ R1 , reaching the optimal value again at ϕ f = 0.009.In the dynamic regime, the value of σ R1 increases with the increase in ϕ f .Figure 6 illustrates the dynamic regime evolution of residual flexural strength values for 1.5 mm and 2.5 mm of vertical displacement, σ R2 and σ R3 , respectively.Both strength parameters are enhanced as ϕ f is increased.
Figure 7a compares the evolution of flexural strength parameters measured in the quasi-static regime (v 1 = 4 × 10 −4 mm/s).Except for the unreinforced matrix, σ N and σ L coincide for different fiber quantities.It is also observed that the values of σ R1 follow a similar trend to σ N and σ L for various ϕ f values, reaching their maximum values at ϕ f = 0.009.This indicates that, for the studied hydraulic lime concrete matrix design, there exists an optimal fiber volume fraction (ϕ f = 0.009) in the quasi-static regime, beyond which distortion occurs, leading to reduced flexural strengths.
Figure 7b compares the evolution of residual flexural strength (σ R1 , σ R2 , σ R3 , and σ R4 ) measured in the dynamic regime (v 2 = 4 mm/s).All parameters show an increase as the fiber volume fraction is augmented.Additionally, their growth rates remain approximately constant across the entire ϕ f range.
Figures 8a,b depict the stress-displacement curves, σ-δ, for three-point bending tests under quasi-static and dynamic conditions, respectively.In the quasi-static regime (Figure 8a), specimen failure occurs at displacements, δ, around 0.5 mm for fiber-unreinforced concretes and approximately 1 mm for fiber-reinforced concretes.An increase in flexural energy absorption capacity is also evident as ϕ f is augmented.In the dynamic regime (Figure 8b), all fiber-reinforced concretes exhibit residual flexural strength values for displacements of at least 3.5 mm.Furthermore, the flexural energy absorption capacity not only increases with fiber content but is significantly higher than that calculated in the quasi-static regime for all cases, including fiber-unreinforced concretes, as previously explained (Figure 4b).As depicted in Figures 7 and 8, the evolution of residual flexural strengths for different vertical displacement values is noteworthy in the dynamic regime as fiber is added to hydraulic lime concrete.This highlights the effective interaction at the fiber-matrix interface, confirmed through post-mortem analysis of specimens where the predominant fiber failure is pullout.This interaction allows the composite material to develop energy absorption capacity and ductility in the post-peak load range.This translates into the suitability of discontinuous reinforcement with this fiber type in lime concretes susceptible to specific ranges of dynamic loading.

Discussion
Fiber-reinforced concrete proves highly suitable for withstanding dynamic forces owing to its heightened ductility and increased ability to dissipate energy during fractures.Over the past few decades, research has extensively addressed the initiation and progression of mode I fracture cracks in plain Portland cement concrete, employing both experimental and numerical approaches.As concrete is inherently prone to damage and fracture, the loading rate plays a pivotal role in influencing its strength, failure mode, and ultimate crack patterns [42][43][44][45].This response may be attributed to various factors, including the growth of micro-cracks associated with loading rate, the viscous behavior influenced by water content, or the Steffan effect [46], and the impact of structural inertia forces.These forces, stemming from crack propagation, inertia activated by material hardening or softening, and inertia due to crack bifurcation, can alter the stress-strain state.
The first two factors dominate at lower loading rates, while the third becomes more significant at higher loading rates.Concrete properties, such as bending [47][48][49], have been demonstrated to be rate-dependent.Consequently, applying quasi-static mechanical properties to structures becomes inappropriate when dynamic effects are significant.The introduction of fibers enhances the material's toughness by improving the stitching capacity of fibers for developed cracks through the pullout mechanism [50,51].Simultaneously, the dynamic fracture of fiber-reinforced concrete in mode I becomes more intricate.Zhang et al. [45,52] conducted a study on the dynamic fracture of fiber-reinforced concrete, shedding light on these complexities.
Therefore, characterizing these properties under dynamic loading conditions becomes imperative.In particular, the findings from this study are consistent with the existing scientific literature on Portland cement concrete.However, this work represents a relevant and novel contribution to fiber-reinforced lime concrete knowledge.Indeed, restoration and repair elements in heritage structures may need to sustain wind loads, earthquakes, cyclic loads, impacts, etc.Therefore, the reinforcement of natural hydraulic lime concrete with flexible fibers (in this case, PVA) is beneficial from multiple perspectives for use in heritage restoration and repair elements regarding strength, durability, and sustainability (economic, social, and environmental).It is noteworthy that one of the limitations identified in this study will be addressed in a subsequent article, where the results under impact loads will be analyzed.Therefore, for a proper interpretation of the findings in this study, it is crucial to bear in mind this important consideration.
Figure 9 depicts the typical cracking pattern in a three-point bending test under mode I fracture on a specimen with a central notch.Upon dynamic loading, the initial observation is the development of the primary crack extending from the notch tip towards the loading point (Figure 10).In the dynamic regime, failure occurs along the intergranular regions of the fractured surface (Figure 11).Additionally, it is noted that the fibers predominantly fail through pullout, occasionally experiencing breakage (Figure 11).These characteristics of inter-granular fracture mode and predominant fiber pullout are similar to those observed in the quasi-static regime.

Conclusions
In this study, we examine the effects of flexible PVA fiber reinforcement on low-strength hydraulic lime concrete under both quasi-static and dynamic conditions.The research involves prismatic specimens with varying polyvinyl alcohol fiber contents, subjected to three-point bending tests.In both hydraulic lime concretes (with and without PVA fibers), the fresh state characterization revealed a soft consistency in the Abrams cone test, aligning with the design goal.Relatively low fresh state density values were observed, possibly attributed to a high content of entrapped air.
Concerning the quasi-static mechanical characterization, the expected compressive strength value was achieved in all cases, aligned with the initially established w/ℓ ratio in the mix design.The compressive strength increased with the rise in fiber content, showcasing a substantial enhancement in low-strength concrete.The modulus of elasticity exhibited variability, generally decreasing with fiber inclusion, except for ϕ f = 0.9%.An optimal fiber volume fraction (ϕ f = 0.9%) was identified for maximum flexural strengths in the quasi-static regime, beyond which a reduction occurred.
Dynamic fracture tests demonstrated increased flexural strength parameters as fiber volume fraction increased.Residual flexural strengths (σ R1 , σ R2 , σ R3 , σ R4 ) in the dynamic regime consistently grew with augmented ϕ f , with constant growth rates.The stress-crack opening curves in three-point bending tests revealed enhanced energy absorption capacity and ductility in the dynamic regime, emphasizing the effectiveness of fiber-matrix interaction.
An increase in flexural strength, residual flexural strengths, and work of fracture is observed with higher fiber content in both regimes.Transitioning between regimes significantly enhances these mechanical properties.Post-mortem analysis confirmed intergranular fracture and effective fiber-matrix interaction, primarily through fiber pullout failure.This interaction facilitated the development of energy absorption capacity and ductility in the post-peak load range.
The study highlights the suitability of discontinuous PVA fiber reinforcement in lime concretes under specific dynamic loading conditions.The results offer valuable insights for optimizing fiber content to improve mechanical properties and fracture strength in lime concretes.The composite material exhibits significant ductility and energy absorption capacity, rendering it a promising alternative for various applications including restoration, rehabilitation, and new construction projects.

Figure 2 .
Figure 2. Configuration for a three-point bending test setup.

Figure 3 .
Figure 3. (a) f c at 28 days, (b) f c at 156 days, and (c) E c at 28 days, in a quasi-static regime.

Table 1 .
Mix design composition of FFLC (kg of raw materials in a cubic meter of hydrauliclime concrete).

Table 2 .
Slump in the Abrams cone test and density values.

Table 3 .
Quasi-static mechanical tests characterization results: f c , compressive strength; E, elastic modulus (mean values, standard deviation in parentheses).

Table 4 .
Three point bending quasi-static tests results at a displacement rate of 0.4 µm/s (v 1 ): σ N , flexural strength; σ L , flexural strength for 0.05 mm of vertical displacement; σ R1 , residual flexural strength for 0.5 mm of vertical displacement; W F , work of fracture up to 0.5 mm of vertical displacement (mean values, standard deviation in parentheses).

Table 5
presents a summary of mode I dynamic fracture tests conducted on hydraulic lime concretes, with and without PVA fibers, at 156 days.Additionally, graphical representations in Figures4-7offer a more accessible visualization of the comparative analysis and trends of various parameters.

Table 5 .
Mode I fracture dynamic test results at a displacement rate of 4 mm/s (v 2 ): σ N , flexural strength; σ L , flexural strength for 0.05 mm of vertical displacement; σ R1 , residual flexural strength for 0.5 mm of vertical displacement; σ R2 , residual flexural strength for 1.5 mm of vertical displacement; σ R3 , residual flexural strength for 2.5 mm of vertical displacement; σ R4 , residual flexural strength for 3.5 mm of vertical displacement; W F , work of fracture up to 0.5 mm of vertical displacement (mean values, standard deviation in parentheses).