Performance of an Environmentally Friendly Alternative Fluid in a Loop Heat Pipe-Based Battery Thermal Management System
Abstract
:1. Introduction
2. Loop Heat Pipe Thermal Management Design
3. Experimental Set-Up
Novec™ 649 Selection Rationale
- It is non-toxic, so it will not harm passengers in case of leakage and presents advantages for production, as it does not require precautions for handling;
- It is non-flammable, as the TMS should not add any risk of incrementing a failure, not only in cases of leaks, but also in disruptive cases (such as accidents, crashes);
- It is inert and dielectric, so in case of leakage and contact with the battery cells, the working fluid will not cause a short-circuit;
- It has a global warming potential (GWP) value of 1 and ozone depletion potential (ODP) of 0, which are unparalleled values compared to other refrigerants and heat transfer fluids used in the automotive sector. Moreover, regulation No. 517/2014 of the European Parliament prevents the use of refrigerants with GWP higher than 150;
- It has a low freezing point of −108 °C, allowing it to be used in cold climates without the risk of damage to the LHP;
- Its boiling point of 49 °C is lower than other standard working fluids used in two-phase passive devices, which is makes it more suitable at keeping the cell temperature in the desired range.
4. Experimental Results and Discussion
4.1. Comparison between Novec™ 649 and Ethanol
4.2. Assessment of TMS with Novec™ 649 during Different C-Rates
5. Conclusions
- For the first time an LHP filled with Novec™ 649 as working fluid is utilized and thermally characterized.
- Comparing the results with the same LHP filled with ethanol over a bespoke driving cycle including 4C fast charge, the cell temperatures when using the two fluids, ethanol and Novec™ 649, in the TMS were very similar; in fact, the maximum temperatures at the end of fast charge differed by only 0.7 °C.
- Ethanol was slightly better in reducing the temperature in the final highway driving section, giving a final temperature 2.2 °C lower than Novec™ 649.
- Quicker start-up was achieved while using Novec™ 649, as the lower boiling point and latent heat of vaporisation compared to ethanol made the LHP start as soon as the fast charge was initiated;
- The proposed TMS running Novec™ 649 was tested for different fast charge cycles, 1C, 2C and 3C, where the maximum temperatures were 28.4 °C, 36.3 °C and 46.4 °C respectively; these results are below the safety threshold of 60 °C and very close to the 25−40 °C optimum window.
- The maximum temperature difference across the cells belonging to the module is 5 °C @3C fast charge, which in line with the thermal requirement at the module level; moreover, it was proven that graphite improves the cell temperature reduction by almost 21 °C.
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
Nomenclature
EV | Electric Vehicle |
GHG | GreenHouse Gases |
HFCH | Highway—Fast Charging—Highway |
HP | Heat Pipe |
LHP | Loop Heat Pipe |
PCM | Phase Change Materials |
TC | Thermocouple |
TMS | Thermal Management System |
SOC | State of Charge |
Capillary Pressure Gradient | |
Pore Size Medium Radius | |
Meniscus Contact Angle | |
Surface Tension |
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Parameter | Air | Liquid | PCM | Boiling | Heat Pipes |
---|---|---|---|---|---|
Power Consumption | High | Medium | Low | Low | Low |
Weight | Low | High | High | Medium | Medium |
Encumbrance | Medium | Medium | High | Medium | Medium |
Cost | Low | High | High | High | Medium |
Maintenance | Medium | Medium | Low | Low | Low |
Complexity/#parts | Low | High | Low | High | Medium |
Cooling Performance | Low | High | Low | High | High |
Parameter | Cell | Graphite | Units |
---|---|---|---|
Thickness | 10 | 0.8 | mm |
Height | 96 | 96 | mm |
Width | 280 | 240 | mm |
Thermal Conductivity planar | 46 | 350 | W/m∙K |
Thermal Conductivity normal | 0.7 | 10 | W/m∙K |
Density | 3720 | 1300–1500 | kg/m3 |
Mass Heat Capacity | 1726 | 810 | J/kg∙K |
Battery Capacity | 65 | - | Ah |
Part | Value | Units | |
---|---|---|---|
Condenser | ID/OD | 4.4/6 | mm |
HEX | ID/OD | 15/11 | mm |
Length | 580 | mm | |
Liquid Line | ID/OD | 4.4/6 | mm |
Length | 390 | mm | |
Vapour Line | ID/OD | 4.4/6 | mm |
Length | 400 | mm | |
Wick | Thickness | 8 | mm |
Width | 45 | mm | |
Length | 50.5 | mm | |
Porosity | 45% | ||
Pore Size | 7.3 | µm | |
Vapour Grooves | Radius | 1.5 | mm |
N | 9 | - | |
Length | 43 | mm | |
Evaporator Shell | Thickness | 1 | mm |
Width | 50 | mm | |
Length | 84 | mm | |
Compensation Chamber | Thickness | 8 | mm |
Width | 50.5 | mm | |
Length | 24 | mm |
Fluid | Boiling Point [°C] | Freezing Point [°C] | Application | Cons Compared to Novec™ 649 |
---|---|---|---|---|
Novec™ 649 | 49 | −108 | This work | |
Water | 100 | 0 | EV [30,31]; LHP [32] | Freezing at 0 °C with expansion that can break wick and piping of LHP; electrical conductor |
Ethanol | 78 | −114 | LHP [33] | Toxic and flammable |
Ammonia | −33 | −77 | LHP [34] | High Vapour Pressure (10 bar@25 °C); toxic and flammable |
Acetone | 56 | −95 | LHP [35] | Toxic and flammable |
R134a | −26 | −103 | EV [36] | High GWP of 1430; boiling point too low (<20 °C) |
Novec™ 7000 | 34 | −123 | EV [16,37] | High GWP of 420 |
Ethylene Glycol | 197 | −13 | EV [20,38] | Toxic and flammable |
R1234yf | −30 | −150 | EV [39] | Mildly flammable per ASTM E-681-04; boiling point too low (<20 °C) |
C-Rate | Duration (minutes) | Final SOC |
---|---|---|
−1 | 48 | 20% |
0 | 1 | - |
4 | 3 | 40% |
3.75 | 3 | 59% |
3.5 | 3 | 77% |
2.5 | 1 | 81% |
0 | 1 | - |
−1 | 48 | 20% |
Ethanol | Novec™ 649 | |
---|---|---|
Boiling Point [°C] | 78 | 49 |
Freezing Point [°C] | −114 | −108 |
Density [kg/m] | 804 | 1600 |
Viscosity [mPa·s] | 1.19 | 0.64 |
Thermal Conductivity [W/m·K] | 0.17 | 0.06 |
Latent Heat of Vaporisation [kJ/kg] | 945 | 88 |
Specific Heat [J/kg·K] | 3023 | 1103 |
Surface Tension [N/m] | 0.022 | 0.011 |
Saturation Pressure [bar] | 0.062 | 0.400 |
C-Rate | Charge Times 20–80% SOC | Heat Cell [W] | Heat 3Cell Module [W] |
---|---|---|---|
1C | 36 min | 3 | 9 |
2C | 18 min | 12 | 36 |
3C | 12 min | 27 | 81 |
C-Rate | Cell 1 [°C] | Cell 2 [°C] | Cell 3 [°C] | ∆ [°C] |
---|---|---|---|---|
1C | 28.4 ± 0.5 | 28.1 ± 0.5 | 27.5 ± 0.5 | 0.9 ± 0.7 |
2C | 36.3 ± 0.5 | 34.8 ± 0.5 | 33.3 ± 0.5 | 3.0 ± 0.7 |
3C | 46.4 ± 0.5 | 43.5 ± 0.5 | 41.0 ± 0.5 | 5.4 ± 0.7 |
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Bernagozzi, M.; Miché, N.; Georgoulas, A.; Rouaud, C.; Marengo, M. Performance of an Environmentally Friendly Alternative Fluid in a Loop Heat Pipe-Based Battery Thermal Management System. Energies 2021, 14, 7738. https://doi.org/10.3390/en14227738
Bernagozzi M, Miché N, Georgoulas A, Rouaud C, Marengo M. Performance of an Environmentally Friendly Alternative Fluid in a Loop Heat Pipe-Based Battery Thermal Management System. Energies. 2021; 14(22):7738. https://doi.org/10.3390/en14227738
Chicago/Turabian StyleBernagozzi, Marco, Nicolas Miché, Anastasios Georgoulas, Cedric Rouaud, and Marco Marengo. 2021. "Performance of an Environmentally Friendly Alternative Fluid in a Loop Heat Pipe-Based Battery Thermal Management System" Energies 14, no. 22: 7738. https://doi.org/10.3390/en14227738