Highly Efficient MoS2/CsxWO3 Nanocomposite Hydrogen Gas Sensors

Hydrogen gas sensors are important because of the significant use of hydrogen in industrial and commercial applications. In this study, we synthesized a novel CsxWO3/MoS2 nanocomposite using a solvothermal method. The samples were spin-coated on Si/SiO2 substrates, and the sensors were fabricated with interdigital electrodes. The hydrogen gas sensing properties of the sensor were investigated. CsxWO3/MoS2 exhibited an outstanding hydrogen gas sensing ability at room temperature. In particular, the nanocomposite comprising 15 wt.% MoS2 (15% CsxWO3/MoS2) showed a 51% response to hydrogen gas at room temperature. Further, it exhibited an excellent cyclic stability for hydrogen gas sensing, which is crucial for practical applications. Therefore, this study facilitates the development of effective and efficient hydrogen gas sensors operable at room temperature.


INTRODUCTION
A polluted atmosphere endangers the health of living organisms. It comprises various gases that exist in nature and those released from industries (Masteghin et al., 2019;Pisarkiewicz et al., 2020;Duc et al., 2020;Kim et al., 2021). These odorless, tasteless, colorless gases are toxic when they exceed the safe limits (Ha et al., 2018;Miglietta et al., 2020;Pisarkiewicz et al., 2020). Hydrogen (H 2 ), carbon dioxide (CO 2 ), carbon monoxide (CO), and ammonia (NH 3 ) present in the environment have adverse effects on human health when their concentrations exceed the permissible levels (Annanouch et al., 2021;Hübert et al., 2014;Saravanan et al., 2017). Therefore, the amount of these gases in the environment must be monitored, and the development of effective and efficient detection methods is essential.
Hydrogen is one of the most hazardous gas and regulating its concentration with adequate monitoring devices is crucial (Hübert et al., 2014). Currently it is extensively used as a major ecological energy source and is used in semiconductor processing, chemical industry, nuclear reactors, and petroleum extraction. Hydrogen is a potential candidate for next-generation energy requirements in power plants, automobile transportation, and aerospace industries. However, the storage and regulated supply of hydrogen are challenging owing to the potential dangers of leakage (Saravanan et al., 2017). Therefore, developing long-lasting and costeffective hydrogen sensing devices that are highly reliable for the accurate detection of the hazardous hydrogen gas is compelling (Hienuki et al., 2021;Liang et al., 2021;Sridhar et al., 2021).
In recent years, tungsten-based materials have gained a lot of interest owing to their nanostructures and unique chemical and physical properties (Chala et al., 2017;Motora and Wu, 2020;Wu et al., 2019). Because of their good selectivity and stability, they are the most suitable for fabricating highgrade sensors. In particular, tungsten trioxide has been extensively used in sensors for the detection of hazardous gases, such as hydrogen, ammonia, nitrous oxide, and hydrogen sulfide (Wang et al., 2000;Rydosz et al., 2014;Castillo et al., 2020;Dong et al., 2020). However, most of the WO 3 -based gas sensors function at high temperatures or have high response/recovery times, which hinder their practical application (Esfandiar et al., 2014;Chang et al., 2020). Therefore, the development of tungsten oxide-based gas sensor materials that can circumvent these limitations is important. In our previous study, we proposed a new tungsten bronze material-cesium tungsten oxide (Cs x WO 3 ) for hydrogen gas sensors, which exhibited significant hydrogen gas sensing properties at room temperature owing to its mixed-valence state and unique properties (Wu et al., 2021). However, its sensor response and response time need to be enhanced to detect hydrogen gas within a short duration, which are crucial for practical applications. Therefore, to circumvent this limitation, a suitable sensor material should be selected.
In contrast, molybdenum disulfide is a transition metal dichalcogenide (TMD), which is used in various applications, such as photocatalysis, sensing, disinfection, contaminant adsorption, and membrane-based separation (Barua et al., 2017;Li et al., 2018;Bello et al., 2020). It has been applied in the field of sensors as photochemical sensors, gas sensors, glucose sensors, photodetectors, electrochemical sensors, and DNA sensors (Zhang et al., 2015;Akbari et al., 2018). Among the different types of gases, MoS 2 nanostructures are usually selective toward NH 3 gas at room temperature, which hinders their applicability as gas sensors. Although MoS 2 is a good sensing material, it has limitations, such as a low structural strength and conductivity (Huaning et al., 2021). However, few studies have shown that its selective behavior can change while forming hybrids with different materials; this can be ascribed to the charge-transferbased modulation of the channel conductivity of the gas sensor mechanism (Gottam et al., 2020). Therefore, combining MoS 2 with unique material is important for achieving an enhanced sensing performance. For instance, WO 3 /MoS 2 composites have been developed, and the nanocomposite exhibits excellent ammonia and hydrogen sulfide sensing properties (Singh et al., 2020, Singh et al., 2021. However, these sensor devices function only at temperatures higher than 200°C. Besides, most of the previously developed hydrogen gas sensor exhibited low sensor response. It is very important to develop hydrogen gas sensor with high sensitivity, selectivity, and stability for practical applications. Therefore, the development of MoS 2 composites with excellent hydrogen sensing performance at room temperature is crucial.
Herein, we developed Cs x WO 3 @MoS 2 nanocomposites for application in hydrogen gas sensors through a solvothermal method by taking advantage of the low-temperature sensing properties of Cs x WO 3 and the high sensor response of MoS 2 . The hydrogen gas sensing properties of the developed Cs x WO 3 @ MoS 2 nanocomposite gas sensor at room temperature were systematically investigated. The proposed gas-sensing mechanism of the sensor was also explained.
All reagents and chemicals used in this study were of analytical grade and were used without further purification.

Synthesis of Cs x WO 3 Nanorods
Tungsten hexachloride (0.2976 g) was added to anhydrous ethanol (40 ml) under intense stirring, resulting in the formation of a yellowish solution. Thereafter, 0.065 g of CsOH·H 2 O was introduced into the yellowish solution.
After the resultant solution became homogeneous, 10 ml of acetic acid was added. Subsequently, the mixture was transferred into a 100 ml Teflon-lined autoclave, followed by hydrothermal treatment at 240°C for 20 h. Afterward, it was cooled to room temperature naturally, and the blue product was centrifuged, washed with ethanol several times, and finally dried in a vacuum oven at 60°C for 8 h (Wu et al., 2021).

Exfoliation of MoS 2 Nanosheets
The MoS 2 nanosheets were exfoliated by ultrasonication according to a previously reported method (Bera and sciences, 2017). Bulk MoS 2 (0.64 g) was added to DMF (20 ml) in a flatbottomed beaker (100 ml) and ultrasonicated for 60 min. The temperature of the sonication was controlled by a cooling system during ultrasonication. Afterward, the sample was centrifuged, washed, and dried at 60°C for 8 h.

Preparation of Cs x WO 3 /MoS 2 Nanocomposites
The Cs x WO 3 /MoS 2 nanocomposite was prepared using a hydrothermal method. The material required for the synthesis-0.1 M aqueous solution of MoS 2 (30 ml) was stirred for 1 h. Simultaneously, 0.2976 g of tungsten hexachloride was mixed with 40 ml of anhydrous ethanol under intense stirring, which resulted in the formation of a yellowish solution. Thereafter, 0.065 g of CsOH·H 2 O was added to the yellowish solution. Subsequently, 10 ml of acetic acid was added to the resultant solution when it became homogeneous. Afterward, different amounts of the prepared MoS 2 solution were added to form composites with different ratios. Subsequently, the mixture was transferred into a 100 ml Teflon-lined autoclave, followed by a hydrothermal process at 240°C for 20 h. The obtained dark blue product was centrifuged, washed with ethanol several times, and finally dried in a vacuum oven at 60°C. In this study, three different composites were prepared by changing the amount of MoS 2 and labeled as 5%, 15%, and 30%.

Characterization of Cs x WO 3 /MoS 2 Nanocomposites
Field emission scanning electron microscopy (FESEM, JSM6500F, JEOL, Tokyo, Japan), transmission electron microscopy (TEM), and high-resolution TEM (TEM, Philips-6500F) were used to study the surface morphologies of the samples. The crystal structures of the Cs x WO 3 , MoS 2 , and Cs x WO 3 /MoS 2 nanocomposites were obtained by X-ray diffraction (XRD; D2 Phaser X-ray diffractometer, Bruker, Karlsruhe, Germany) analysis. The chemical compositions of the prepared samples were determined by Raman spectroscopy using an HR800 instrument (Jobin Yvon, Taipei, Taiwan). The N 2 adsorption/desorption isotherm and Brunauer, Emmett, and Teller (BET) surface area analyses of the samples were conducted at 77 K using a Quanta chrome iQ-MP gas adsorption analyzer (BEL JAPAN, INC.).

Sensor Fabrication and Hydrogen Gas Sensing Measurements
To fabricate the gas sensor, the as-prepared Cs x WO 3 , MoS 2 , and Cs x WO 3 /MoS 2 nanocomposites were diluted with isopropanol (IPA) and spin-coated on Si/SiO 2 substrates, which were then sputtered with multi-finger Pt interdigitated electrodes ( Figure 1). The H 2 gas sensing properties of the prepared sensors were measured in a compact vacuum chamber with an H 2 flow of 99.9% (diluted with dry air) via a mass flow controller. The properties were measured systematically from the electrical output response recorded using a Keithley source meter unit (SMU, Keithley 2,400, Tektronix, Beaverton, OR, USA) connected to a computer.

Electrochemical Measurements of the Sensors
The electrochemical properties of the developed sensor materials were investigated by electrochemical impedance spectroscopy (EIS) using a 5,000 electrochemical workstation (Jiehan Technology Corp., Taiwan), wherein a conventional threeelectrode configuration was used. In this measurement, 0.1 M aqueous solution of KCl was used as the electrolyte and platinum and Ag/AgCl were used as the counter and reference electrodes, respectively; a titanium substrate was used as the working electrode (Phuruangrat et al., 2009). To prepare the working electrode for EIS measurements, 4 mg of Cs x WO 3 , MoS 2 , and 15% Cs x WO 3 /MoS 2 were added to 80 µL of Nafion solution and 920 µL of absolute ethanol, and the mixture was ultrasonicated for approximately 90 min to obtain a slurry. Thereafter, 40 µL of the slurry was drop-cast onto a 1 × 1 cm 2 titanium substrate electrode and dried at room temperature.

Morphological and Structural Properties of Cs x WO 3 /MoS 2 Nanocomposites
The surface morphologies of the prepared samples were studied by FESEM, and the FESEM image in Figure 2A shows that MoS 2 has a sheet-like morphology, mostly smaller than 2 µm in size. The FESEM image in Figure 2B depicts that the surface morphology of Cs x WO 3 comprises a nanorod-like structure with an average diameter of 40-50 nm. The FESEM image of the 15% Cs x WO 3 /MoS 2 nanocomposite in Figure 2C shows the coexistence of nanorods and nanosheets, owing to surface morphologies of Cs x WO 3 and MoS 2 , confirming the successful synthesis of the intended nanocomposites. Furthermore, the corresponding EDS spectrum confirmed the existence of Mo and S from MoS 2 ; Cs, O, and W from Cs x WO 3 . The actual elemental composition of the 15% Cs x WO 3 /MoS 2 nanocomposite was also investigated and the result as shown in the inset of Figure 2D. It can be seen from the actual mass percentage and theoretical mass percentage of each element in the nanocomposites that they are almost the same. These results reveal that the Cs x WO 3 /MoS 2 nanocomposite was successfully prepared. The FESEM image in Figure 3A and elemental mapping results of the 15% Cs x WO 3 /MoS 2 nanocomposites presented in Figures 3B-F show the homogeneous distribution of Mo, S, Cs, O, and W elements in the nanocomposite.
The surface morphology of the synthesized 15% Cs x WO 3 / MoS 2 nanocomposite was further studied by TEM and HRTEM. The TEM image of 15% Cs x WO 3 /MoS 2 nanocomposite shown in Figure 4A can be ascribed to Cs x WO 3 nanorods and MoS 2 nanosheets. The coexistence of the MoS 2 nanosheets and Cs x WO 3 nanorods can be seen in the HRTEM image of the nanocomposite, as shown in Figure 4B. The lattice spacing of 0.32 nm corresponds to the (002) crystal plane of Cs x WO 3 and that of 0.27 nm corresponds to the (100) crystal plane of MoS 2 . The corresponding selected area electron diffraction (SAED) pattern in Figure 4C confirms the combination of both Cs x WO 3 and MoS 2 , where the dots forming the hexagonal shape are attributed to the MoS 2 nanosheets and those forming the triangle are ascribed to Cs x WO 3 (Ahmadi et al., 2014). However, the SAED dots in Figure 4C form hexagonal and triangular shapes with minimal changes than those of individual Cs x WO 3 and MoS 2 . This can be attributed to the nanocomposite formation of Cs x WO 3 /MoS 2 . These results confirm that the nanocomposite was successfully prepared, and the Cs x WO 3 nanorods and MoS 2 nanosheets were in good contact, which would enhance the gas sensing property. Figure 5 shows the XRD patterns of the CxWO 3 nanorods, MoS 2 nanosheets, and their nanocomposites. The XRD pattern of the Cs x WO 3 nanorods can be ascribed to the hexagonal phase of Cs 0.33 WO 3 (JCPDS No. 83-1334) (Wu et al., 2021). The absence of additional diffraction peaks confirmed the successful synthesis of pure Cs 0.33 WO 3 . The XRD peaks of the MoS 2 nanosheets can be indexed to hexagonal phase of MoS 2 (JCPDS No. 65-1951) (Zhang et al., 2014). The XRD peaks of the Cs x WO 3 /MoS 2 nanocomposites comprise characteristic peaks of both Cs x WO 3 and MoS 2 , confirming the successful preparation of the nanocomposite. In addition, the peak intensity of Cs x WO 3 at (200) diffraction peak decreases as the MoS 2 content increases. The crystallite size of the Cs x WO 3 and MoS 2 in the synthesized 15% Cs x WO 3 /MoS 2 nanocomposite was determined by using the Scherrer equation as shown below: where λ is the wavelength of X-ray used (0.154 nm), β is the fullwidth at the half maximum of the respective diffraction peak, and θ is the angle at the maximum peak (Bekena et al., 2019). The Frontiers in Materials | www.frontiersin.org January 2022 | Volume 9 | Article 831725 finding shows that the crystallite size of Cs x WO 3 was 2 nm at diffraction peak of (200). While that of the MoS 2 nanocomposite is about 6 nm at (002) diffraction peak. The as-prepared samples were further characterized by Raman spectroscopy, and the Raman spectra are shown in Figure 6A. The spectra show that two major peaks were observed for the MoS 2 nanosheets, which be indexed to the 2H phase of MoS 2 and E 2g (308 cm −1 ) and A 1g (408 cm −1 ) activation modes (Vadivelmurugan et al., 2021). The E 2g mode corresponds to the plane vibration of S and Mo atoms, whereas the A 1g mode is attributed to the relative vibration of the S atom, which is in the plane direction (Yao et al., 2019). Further, the two weak peaks at 451 and 1599 cm −1 indicate E 1g and the longitudinal acoustic phonon modes, respectively. In the case of Cs x WO 3 , the Raman peak at 731 cm −1 corresponds to monoclinic Gama WO 3 and that at 935 cm −1 corresponds to nanocrystalline Cs x WO 3 (Okada et al., 2019). These peaks in Cs x WO 3 confirm the nanocrystalline formation of WO 3 with cesium. The characteristic peaks of both MoS 2 and Cs x WO 3 were observed for Cs x WO 3 /MoS 2 composite, indicating the successful preparation of the nanocomposites. In addition, there is a slight shift in the WO 3 peaks, at 872 and 993 cm −1 , which The BET specific surface areas of the materials were investigated by N 2 adsorption analysis, and the results in Figure 6B show that all the samples exhibited N 2 adsorption-desorption isotherms similar to type IV curves according to the Brunauer-Deming-Deming-Teller classification . The specific surface areas of the pure Cs x WO 3 , pure MoS 2 , and 15% Cs x WO 3 /MoS 2 nanocomposites were calculated from the linear region of the multipoint plot. The BET specific surface areas of Cs x WO 3 , MoS 2 , and 15% Cs x WO 3 / MoS 2 nanocomposites were 31.1, 3.3, and 15.0 m 2 g −1 , respectively. Herein, the surface area of 15% Cs x WO 3 /MoS 2 was lower than that of pure Cs x WO 3 because of the encompassing of the nanorods by the MoS 2 nanosheets. Compared to MoS 2 nanosheets, the 15% Cs x WO 3 /MoS 2 nanocomposites possessed a larger surface area, which is important for the adsorption of a higher amount of hydrogen gas, and would aid in enhancing the gas sensing properties of the sensor.

Hydrogen Gas Sensing Properties of Cs x WO 3 /MoS 2 Composites-Based Gas Sensors
The sensing properties of metal oxide-based gas sensors are usually measured in terms of their sensitivity and repeatability by varying the resistance values of gas and vacuum/air vs. time. The H 2 gas detection properties of the Cs x WO 3 /MoS 2 nanocomposites were tested at a gas concentration of 10-500 ppm at 25°C (~35 RH %). The sensor response of the samples is calculated using Equation 2 for oxidizing gases and vice versa for reducing gases.
where R is the resistance; a is the air atmosphere, and g is the gas atmosphere of the samples. The gas-sensing performance of a sensor can be determined using the current-voltage (I-V) curve recorded before and after the adsorption of the gas. Herein, we also evaluated the H 2 gas sensing performance of 15% Cs x WO 3 /MoS 2 nanocomposites using I-V characteristics before and after the adsorption of hydrogen gas, and the results in Figure 7A show the change in the electrical performance in the presence of H 2 when compared with that of no hydrogen gas. Figure 7B shows the sensor response of the developed 15% Cs x WO 3 /MoS 2 nanocomposite gas sensor at different concentrations (500, 250, 100, and 10 ppm) of hydrogen gas. The developed sensor exhibited outstanding H 2 gas sensing properties with a 50.6% sensor response toward 500 ppm of H 2 gas with 60 and 120 s response and recovery time, respectively. These recovery time and Frontiers in Materials | www.frontiersin.org January 2022 | Volume 9 | Article 831725 6 response time are better than that of reported Pd/CNT/Ni H 2 gas sensor that has 312 s response time and 173 s recovery and Ni/Pdgraphene H 2 gas, which has 180 s response time and 720 s recover time. Phan and Chung, 2014). This sensor response is superior to that of the H 2 gas sensor of pure Cs x WO 3 (31.3%) (Wu et al., 2021), which indicates that nanocomposite formation has enhanced the sensitivity. Figure 7C presents the sensor response vs. concentration curve, which shows a linear increase in the sensor response with an increase in concentration, revealing that the developed sensor can be applied to detect a wide range of concentrations of H 2 gas. Figure 7D shows that the fabricated 15% Cs x WO 3 /MoS 2 nanocomposite H 2 gas sensor demonstrates excellent cyclic stability for the five consecutive cycles that are important for practical applications. These findings reveal the potential applicability of the developed 15% Cs x WO 3 /MoS 2 nanocomposite sensor for the detection of H 2 gas.
Long-term stability of sensor is very important for practical application. Herein, the long-term stability of the developed sensor was investigated. The result as shown in Figure 8A shows that it has excellent long-term stability during the 11days evaluation period. Moreover, selectivity of the fabricated 15% Cs x WO 3 /MoS 2 nanocomposite hydrogen gas sensor was also studied. The finding in Figure 8B indicates that the 15% Cs x WO 3 /MoS 2 nanocomposite sensor presented excellent selectivity towards hydrogen gas by showing only 4 and 5% sensor response toward ammonia and carbon dioxide, respectively. The sensor response of the developed sensor toward CO 2 and NH 3 is neglible when compared with that of H 2 (50.6%). These findings confirm that developed sensor has potential applicability for real application for H 2 gas sensing. The sensing property of the developed sensor with respect to current versus time was also investigated. As it can be seen in Supplementary Figure S1, the current response of the fabricated sensor increases with increasing H 2 gas concentration, which proves the behavior of the n-type semiconductor sensor (Wisitsoraat et al., 2009;Mohamad et al., 2010). Moreover, the pure Cs x WO 3 and MoS 2 also have the same properties (Saravanan et al., 2019;Wu et al., 2021). Figure 9 shows the sensor response of Cs x WO 3 /MoS 2 nanocomposites against different amount of MoS 2 (5%, 15%, and 30%) added to Cs x WO 3 . The sensor response of the nanocomposite initially increased with an increase in the amount of MoS 2 up to 15% MoS 2 addition and then decreased  Frontiers in Materials | www.frontiersin.org January 2022 | Volume 9 | Article 831725 7 till 30% MoS 2 addition. This could be because of the encompassing of CsxWO 3 nanorods by MoS 2 nanosheets with low surface areas, which influences the adsorption of H 2 gas and consequently the sensor response (Supplementary Figure S2).
The photograph of the prepared samples dispersed in IPA shown in Supplementary Figure S3 also confirms that the intensity of the dark color of the nanocomposite increases with an increase in the concentration of MoS 2 nanosheets, which confirms the FIGURE 7 | (A) I-V curves, (B) sensor response with respect to the H 2 gas concentration of 15% Cs x WO 3 /MoS 2 -based hydrogen gas sensor, (C) variation of the sensing response of Cs x WO 3 and 15% Cs x WO 3 /MoS 2 -based hydrogen gas sensor at room temperature when exposed to different ppm hydrogen, and (D) repeatability of 15% Cs x WO 3 /MoS 2 -based hydrogen gas sensor at 500 ppm. Frontiers in Materials | www.frontiersin.org January 2022 | Volume 9 | Article 831725 8 presence of the high amount of MoS 2 in 30% MoS 2 . Therefore, 15% Cs x WO 3 /MoS 2 nanocomposite was selected for further studies.

Possible Hydrogen Gas Sensing Mechanisms of Cs x WO 3 /MoS 2 Nanocomposites
Metal oxide-based gas sensors, which sense hydrogen gas, are usually explained based on the variation of the electron depletion layer (EDL) and oxygen adsorption (Sun et al., 2011;Park et al., 2015;Wang et al., 2018). Herein, we propose a sensing mechanism for the developed sensor based on EDL. Cs x WO 3 has oxygen defects in its structure, and MoS 2 is tuned to have a high bandgap after the exfoliation of bulk MoS 2 . Therefore, the Cs x WO 3 nanorods in the nanocomposite can adsorb oxygen from the air because of its oxygen vacancies, and the adsorbed oxygen extracts electrons from the conduction band and generates oxygen species and increases the width of the EDL ( Figure 10A). In contrast, when the sensor is exposed to H 2 gas, the adsorbed oxygen species react with H 2 gas and produce extra electrons in the conduction band of CsxWO 3 , which increase the electrical performance of the material and consequently the sensing property ( Figure 10B).
Further, the electrochemical properties of the samples were investigated, and the results in Figure 11 show that the EIS semicircle radius of the 15% Cs x WO 3 /MoS 2 nanocomposite is lower than those of pure Cs x WO 3 and pure MoS 2 , confirming that the nanocomposite has a higher electrical conductivity than those of pure materials, which contributed to the enhancement in the hydrogen gas sensor response.
The hydrogen gas sensing response of the developed 15% Cs x WO 3 /MoS 2 nanocomposite was also compared with those of reported hydrogen gas sensors, and the results in Table 1 indicate   Frontiers in Materials | www.frontiersin.org January 2022 | Volume 9 | Article 831725 9 that the 15% Cs x WO 3 /MoS 2 nanocomposite exhibited a higher sensor response than those of other sensors (Esfandiar et al., 2012;Huang and Lin, 2012;Anand et al., 2014;Liu et al., 2015;Yang et al., 2015;Zhang et al., 2018;Sharma and Kim, 2018;Xiao et al., 2018;Wu et al., 2021). Further, some of the reported sensors can only operate at high temperatures. Therefore, the developed 15% Cs x WO 3 /MoS 2 nanocomposite H 2 gas sensor is a promising candidate for practical application in the detection of hydrogen gas.

CONCLUSION
In this study, Cs x WO 3 /MoS 2 nanocomposites were successfully prepared using the solvothermal method. The developed Cs x WO 3 /MoS 2 nanocomposite-based sensor exhibited outstanding hydrogen gas sensing properties with 51% response to 500 ppm H 2 gas. It also exhibits excellent cyclic stability. Further, the developed 15% Cs x WO 3 /MoS 2 nanocomposite demonstrated a superior H 2 gas sensing response at room temperature compared to reported H 2 gas sensors. The enhanced sensing response could be because of the improved electrical properties of the 15% Cs x WO 3 /MoS 2 nanocomposite. Therefore, this study facilitates the development of an effective and efficient H 2 gas sensor at room temperature, which will play a crucial role in the detection of hydrogen gas in the environment.

DATA AVAILABILITY STATEMENT
The original contributions presented in the study are included in the article/Supplementary Material, further inquiries can be directed to the corresponding author.

AUTHOR CONTRIBUTIONS
C-MW: Supervision, conceptualization and reviewing and editing. Shrisha: Methodology, data curation and writing. KM: Review and editing. G-YC: Methodology and data curation. D-HK: Resources. NG: Methodology.