Journal of the Magnetics Society of Japan
Online ISSN : 1880-4004
Print ISSN : 0285-0192
ISSN-L : 0285-0192
THEORY OF MAGNETISM
CURIE TEMPERATURE AND BAND STRUCTURE OF METALLIC FERROMAGNETS
R. SKOMSKIX.-L. RAOQ.-N. QIJ.M.D. COEY
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JOURNAL OPEN ACCESS

1995 Volume 19 Issue S_1_MORIS_94 Pages S1_193-196

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Abstract

  A soft-spin Heisenberg model is used to investigate the Curie temperature of elementary iron and iron-rich intermetallics such as Sm2Fe17. In the localized limit the mean-field solution of the classical Heisenberg model is reproduced, while quasi-localized perturbation theory accounts for band-structure effects. An extrapolation of this quasi-localized approach yields physically reasonable results, which makes it possible to interpolate between the delocalized band-structure and localized Heisenberg limits. Using Stoner-type magnetic energies derived from paramagnetic band-structure calculations it is argued that the comparatively low Curie temperature of iron-rich rare-earth intermetallics such as R2Fe17 originates from their quasi-weak ferromagnetism. Upon interstitial modification, these materials leave the quasi-weak limit and become nearly strong ferromagnets with enhanced Curie temperature.

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© 1995 by The Magnetics Society of Japan
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