日本応用磁気学会誌
Online ISSN : 1880-4004
Print ISSN : 0285-0192
ISSN-L : 0285-0192
磁性体物理
ペロブスカイト関連酸化物Sr3(Ga1-xMnx)2O6 (0≦x≦0.2)の結晶構造と磁性
長沼 順子的場 正憲
著者情報
ジャーナル オープンアクセス

2001 年 25 巻 4_2 号 p. 719-722

詳細
抄録

Perovskite-related Ga oxide, Sr3(Ga1-xMnx)2O6 (0≤x≤0.2) was synthesized and characterized in order to design new diluted magnetic perovskites for spin electronics. The crystal structure of Sr3(Ga1-xMnx)2O6 (SGMO) was investigated by powder X-ray diffraction and Rietveld analysis. Knowledge of the SGMO was refined using the Rietveld program, RIETAN. Strontium gallate Sr3Ga2O6 (SGO) is a novel cubic structure with GaO4 tetrahedral unit, space group P3a, and a=b=c=16.095 Å. The crystal structure of SGMO is similar to that of SGO, and Mn-doping does not affect the crystal structure of the mother compound SGO. The electronic nature of Ga and Mn ions in SGMO was investigated by X-ray photoemission spectroscopic measurement, suggesting that the ions of Ga and Mn are +3 and +4 states, respectively. Magnetic properties of SGMO were measured on a SQUID magnetometer. SGMO exhibits non-paramagnetic behavior at 10 K, but it is paramagnetic with θP<0 at 300 K.

著者関連情報
© 2001 (社)日本応用磁気学会
前の記事 次の記事
feedback
Top